Contents Vol. 68b (2013)
Authors Index
Headings and Complete Articles in PDF
The underlined page numbers lead to the headings and the phrases Full Text behind them to the complete articles.
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Graphical Abstracts: No 1, No 2, No 3, No 4, No 5 / 6, No 7, No 8, No 9, No 10, No 11, No 12
Jump to:  No 2 ,  No 3 ,  No 4 ,  No 5 / 6 ,  No 7 ,  No 8 ,  No 9 ,  No 10 ,  No 11 ,  No 12 
N u m b e r  1 (Graphical Abstracts)
To Professor Alfred Klemm on the Occasion of his 100th Birthday
Thomas Lindel, Gerhard Maas, Norbert Mitzel, Gerhard Müller, Rainer Pöttgen, Annette Schier, and Hubert Schmidbaur
1 Open Access
Original Communications
[BMIm][Fe(OTf)3], [BMIm][Mn(OTf)3], [BMIm][Li(OTf)2] – Three One-dimensional Infinite Coordination Polymers
Key words: Coordination Polymer, Infinite Chain, Triflate, Ionic Liquid, Crystal Structure, Manganese, Iron, Lithium
Silke Wolf, Yanhua Lan, Annie Powell, and Claus Feldmann
3  Full Text
The Stannides RE2Ni2Sn (RE = Pr, Ho, Er, Tm) – Structural Transition from the W2B2Co to the Mo2B2Fe Type as a Function of the Rare Earth Size
Key words: Stannides, Crystal Structure, Lanthanoid Contraction
Birgit Heying, Ute Ch. Rodewald, Bernard Chevalier, and Rainer Pöttgen
10  Full Text
SrCo2Sn8 and BaCo2Sn8: Tin-rich Stannides with Distorted SnSn6 Octahedra within Three-dimensional [Co2Sn8] Networks
Key words: Stannide, Crystal Structure, Pauli Paramagnetism, Cobalt, Strontium, Barium
Christian Schwickert and Rainer Pöttgen
17  Full Text
Electronic Structure and Bonding in YTi2Ga4 – A Gallide with Linear Titanium Chains and Four-bonded Gallium Atoms
Key words: Gallide, Intermetallic Compound, Electronic Structure, Yttrium, Titanium
Samir F. Matar and Rainer Pöttgen
23  Full Text
High-pressure Syntheses and Characterization of the Rare Earth Borates RE5(BO3)2F9 (RE = Dy, Ho)
Key words: High Pressure, Fluoride, Borate, Crystal Structure, DFT
Ernst Hinteregger, Gerhard Böhler, Thomas S. Hofer, and Hubert Huppertz
29 Open Access
Synthesis, Raman Spectrum and Single-Crystal Structure of CaBa8[CN2]6O2(N0.5H0.5)
Key words: Barium, Calcium, Carbodiimide, Cyanamide, Hydride, Nitride, Oxide, Raman Spectroscopy
Olaf Reckeweg, Armin Schulz and Francis J. DiSalvo
39  Full Text
Hydrogen Insertion Effects on the Electronic Structure of Equiatomic MgNi Traced by ab initio Calculations
Key words: Hydrogen, Equiatomic MgNi, Iono-covalent Character, Bader Charge, Chemical Bonding
Samir F. Matar, Adel F. Al Alam and Naim Ouaini
44  Full Text
Study of the Synthesis of Some Biginelli-type Products Catalyzed by Nano-ZrO2
Key words: Nanoparticles Zirconium (IV) Oxide, 3,4-Dihydropyrimidinones, Biginelli Compounds, Catalyst, Mild Conditions
Asadollah Farhadi, Mohammad Ali Takassi and Leila Hejazi
51  Full Text
Synthesis of Stable Acyclic Aminals Derived from l-(+)-Aspartic Acid and Their Application in Asymmetric Henry Reactions
Key words: Acyclic Aminals, l-(+)-Aspartic Acid, Enantioselective Henry Reaction
Gamze Koz, Demet Astley and Stephen T. Astley
57  Full Text
Electronic and Molecular Structures of Heteroradialenes: A Combined Synthetic, Computational, Spectroscopic, and Structural Study Identifying IR Spectroscopy as a Simple but Powerful Experimental Probe
Key words: Density Functional Calculations, IR Spectroscopy, Electronic Structure, Aromaticity
Carl-Georg Freiherr von Richthofen, Bastian Feldscher, Kai-Alexander Lippert, Anja Stammler, Hartmut Bögge, and Thorsten Glaser
64  Full Text
Formation and Structure of [(CO)4Mo(Et4Sb2)]2
Key words: Antimony, Chromium, Molybdenum
Hans Joachim Breunig, Enno Lork, Ovidiu Moldovan, and Ciprian Ionuţ Raţ
87  Full Text
Synthesis and Structural Characterization of a Gallium(III) Bis(selenoureato) Complex
Key words: Acylselenourea, Chelate Ligands, Gallium(III), X-Ray Structure, Ligand Exchange
Anja Molter and Fabian Mohr
91  Full Text
Ca2Pd2Cd with W2B2Co-type Structure
Key words: Cadmium, Intermetallics, Crystal Chemistry, Palladium, Calcium
Michael Johnscher and Rainer Pöttgen
95  Full Text
Formation and Fragmentation of 4-Diazo-1,2-diphenyl-3-oxo-butyl Acetate
Key words: Hydroxy-diazoketones, Ester Cleavage, Dehydration, Fragmentation
Deniz Özbilen, Bernhard Beile and Herbert Meier
99  Full Text
N u m b e r  2 (Graphical Abstracts)
Original Communications
The Effect of Centrifugal Force on the Assembly and Crystallization of Binary Colloidal Systems: Towards Structural Gradients
Key words: Binary Colloidal Crystal, Ultracentrifugation, Structural Gradient, Self Organization
Mengdi Chen, Helmut Cölfen and Sebastian Polarz
103  Full Text
CaTMg2 and CaTCd2 (T = Rh, Pd, Pt) with YPd2Si-type Structure
Key words: Magnesium, Cadmium, Cementite Phases, Electronic Structure
Michael Johnscher, Marcel Kersting, Samir F. Matar, and Rainer Pöttgen
111  Full Text
Preparation and Crystal Structure of a New Lithium Vanadium Fluoride Li2VF6 with Trirutile-type Structure
Key words: Lithium Metal Fluoride, Synthesis, Crystal Structure
Suliman Nakhal, Dominik Weber and Martin Lerch
121  Full Text
Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-Organic Cd(II) Coordination Polymer Based on Helical Units
Key words: 4-Methylphthalic Acid, Cd(II) Coordination Polymer, Double-helical Chain, Fluorescence
Hai-Hua Li, Peng Zhang, Jia-Yi Pu, Yu-Ying Zhao, and Chong-Zhen Mei
127  Full Text
Solvothermal Syntheses and Characterization of Three Lanthanide Thioantimonates(V) with Mixed Ethylene Polyamines
Key words: Lanthanide, Thioantimonates, Complex, Solvothermal Syntheses, Crystal Structure
Jian Zhou, Xing Liu and Feilong Hu
133  Full Text
Syntheses, Structures and Electrochemical Properties of Two New Copper(II) Complexes Based on Isomeric Bis(pyridylformyl)piperazine Ligands and Rigid/Flexible Organic Dicarboxylates
Key words: Bis(pyridylformyl)piperazine Ligand, Organic Dicarboxylate, Copper(II) Complex, Crystal Structure, Electrochemical Properties
Hong-Yan Lin, Peng Liu, Xiu-Li Wang, Chuang Xu, and Guo-Cheng Liu
138  Full Text
Cu(II) and Zn(II) Complexes with an N- and O-Donor Ligand: Structural Characterization, Jahn-Teller Effect and Fluorescence
Key words: Cu(II) and Zn(II), Jahn-Teller Effect, Fluorescence Properties
Hai-Wei Kuai, Xiao-Chun Cheng and Xiao-Hong Zhu
147  Full Text
A Novel 2D Mn(II) Coordination Polymer Based on the New Flexible 3-Carboxy-1-(4′-(2″-carboxy)biphenylmethyl)-2-oxidopyridinium and the Pyrazino[2,3-f][1,10]phenanthroline Ligands
Key words: Crystal Structure, Coordination Polymer, 3-Carboxy-1-(4′-(2″-carboxy)biphenylmethyl)-2-oxidopyridinium, Pyrazino[2,3-f][1,10]phenanthroline
Qian Qiao, Xiao-Min Yu, Yuan-Rui Wang, and Zhen-Yu Li
155  Full Text
A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and π-π Interactions, {[Zn(phen)2(H2O){Ag(CN)2}][Ag(CN)2]·MeOH}n (phen = 1,10-Phenanthroline)
Key words: Zinc(II), Silver Cyanide, 1,10-Phenanthroline, Coordination Polymer
Muhammad Monim-ul-Mehboob, Muhammad Ramzan, Tobias Rüffer, Heinrich Lang, Shafqat Naddem, Muhammad Akhtar, and Saeed Ahmad
161  Full Text
New Crystalline Forms of Piroxicam
Key words: Piroxicam, X-Ray Crystal Structure, Crystal Forms, Cocrystals
Anatoly Mishnev and Glebs Kiselovs
168  Full Text
Studies with Enamines: Route to Aminoazolopyrimidines and Arylazoazolopyrimidines
Key words: Azolopyrimidines, Enamines, Azoloazines, Microwave Irradiation
Abdellatif M. Salaheldin and Khalid S. Khairou
175  Full Text
Regio- and Chemoselective Synthesis of 5-Aroyl-NH-1,3-oxazolidine-2-thiones
Key words: NH-Oxazolidine-2-thiones, Chemoselective Reaction, Regioselective Reactions, One-pot Synthesis, Ionic Liquid
Soroor Sadegh-Malvajerd, Zeinab Arzehgar and Farzad Nikpour
182  Full Text
Heterocycles [h]-Fused onto 4-Oxoquinoline-3-carboxylic Acid. Part X. Synthesis and X-Ray Structure of a Model 4-Oxo[1,4]benzoxazepino[2,3-h]quinoline-3-carboxylic Ester
Key words: Salicylaldehyde Oxyanion in SN(Ar) Reaction, 7-(2-Formylphenoxy)-8-nitro-4-oxoquinoline-3-carboxylic Ester, Reductive Cyclization, 4-Oxo[1,4]benzoxazepino-[2,3-h]quinoline-3-carboxylic Ester
Batool A. Farrayeh, Mustafa M. El-Abadelah, Jalal A. Zahra, Salim F. Haddad, and Wolfgang Voelter
187  Full Text
Study of the Catalytic Activity of Zr(HPO4)2 in the Synthesis of Hexahydroquinoline Derivatives under Solvent-free Conditions
Key words: Acidic Salts, Green Method, Hexahydroquinoline-3-carbonitrile, Solvent-free, Zr(HPO4)2
Shahrzad Abdolmohammadi
195  Full Text
Synthesis and Cytotoxic Activity of Ursolic Acid Derivatives
Key words: Ursolic Acid Derivatives, Cytotoxic Activity
Dao Duc Thien, Nguyen Thanh Tam, Dinh Gia Thien, Nguyen Thi Hoang Anh, and Tran Van Sung
201  Full Text
N u m b e r  3 (Graphical Abstracts)
Original Communications
Derivatives of the Triaminoguanidinium Ion, 2. Prototropic Tautomerism, Crystal and Molecular Structure of N,N′,N″-Tris(propan-2-iminyl)guanidine
Key words: Triaminoguanidine, Triaminoguanidinium Salt, Variable-temperature 1H NMR Spectra, Layered Crystal Structure
Jan Szabo and Gerhard Maas
207  Full Text
Synthesis and Structural Characterisation of New Bifunctional o-Hydroxyacetophenones – Potential Linker Molecules for Coordinative Framework Construction
Key words: o-Hydroxyacetophenone, Synthesis, Crystal Structure, X-Ray Photoemission, X-Ray Diffraction
Jörg Hübscher, Michael Günthel, Robert Rosin, Wilhelm Seichter, Florian Mertens, and Edwin Weber
214  Full Text
Unexpected Formation of Thiophene-annulated Tetrahydro-3-benzazepines by Alkylation of Thiolactams with Ethyl Bromoacetate
Key words: Tetrahydro-3-benzazepines, Enantiomerically Pure Compounds, Thiophene Annulation, Thiolactams, Lawesson's Reagent, Eschenmoser Sulfide Contraction, X-Ray Crystal Structure Analysis
Soumya Sarkar, Roland Fröhlich and Bernhard Wünsch
223  Full Text
Synthesis and anti-HIV Activity of New Fused Chromene Derivatives Derived from 2-Amino-4-(1-naphthyl)-5-oxo-4H,5H-pyrano[3,2-c]chromene-3-carbonitrile
Key words: Anti-HIV Activity, Chromenes, Pyrano-chromenes, Reverse Transcriptase Inhibitors (NNRTIs)
Najim A. Al-Masoudi, Hamid H. Mohammed, Aws M. Hamdy, Omer A. Akrawi, Nadi Eleya, Anke Spannenberg, Christophe Pannecouque, and Peter Langer
229  Full Text
Synthesis, Crystal Structure and Fluorescence Behavior of 2,6-Di(thiophen-2-yl)-benzo[1,2-d:4,5-d′]bisoxazole
Key words: 4-Methoxy-TEMPO Free Radical, 2,6-Dithiophene Disubstituted Benzobisoxazole, Synthesis, Crystal Structure, Fluorescence Behavior
Lan-Qin Chai, Yu-Li Zhang, Jun-Feng Tong, and Gang Liu
239  Full Text
Synthesis and Structure of 1-Ethyl-2,4,5-triphenyl-1H-imidazole (Ethyl-Lophine)
Key words: Ionic Liquid, Imidazole, X-Ray Structure, Synthesis
Tim Peppel and Martin Köckerling
245  Full Text
Synthesis, Crystal Structures and Fluorescence Properties of Two d10 Metal Coordination Polymers with Flexible Bis(benzimidazolyl)alkane Ligands
Key words: Bis-benzimidazole, Crystal Structure, Fluorescence Properties, Supramolecular Network
Jun-Wen Wang, Guang-Hua Cui, Li Qin, and Shu-Lin Xiao
250  Full Text
Synthesis, Crystal Structure, DNA-binding Properties and Antioxidant Activities of a Lutetium(III) Complex with the Bis(N-salicylidene)-3-oxapentane-1,5-diamine Ligand
Key words: Lutetium(III) Complex, Crystal Structure, DNA-Binding Properties, Antioxidant Activities, Bis(N-salicylidene)-3-oxapentane-1,5-diamine
Guolong Pan, Yuchen Bai, Hua Wang, Jin Kong, Furong Shi, Yanhui Zhang, Xiaoli Wang, and Huilu Wu
257  Full Text
Complexation to Cadmium(II) of a Tetradentate Ligand Resulting from the Condensation of 2-Pyridinecarbaldehyde with N-(2-Aminoethyl)propane-1,3-diamine
Key words: Hydropyrimidine, Cadmium Complex, Spectroscopic Characterization, X-Ray Crystal Structure, Microwave Irradiation
Mohammad Hakimi, Zahra Mardani, Keyvan Moeini, Esther Schuh, and Fabian Mohr
267  Full Text
A Spectral and Structural Study of the New Cadmium Salt [(H2L)2][Cd2I6][(NO3)2]
Key words: Cadmium Complex, Iodide Bridge, Piperazine Moiety, Amino Alcohol, X-Ray Crystal Structure
Mohammad Hakimi, Zahra Mardani, Keyvan Moeini, Esther Schuh, and Fabian Mohr
272  Full Text
Syntheses, Crystal Structures and Properties of Two New Manganese(II) Coordination Polymers with Tetrafluorophthalate Ligands
Key words: Coordination Polymer, Solvent-induced Synthesis, MnII Tetrafluorophthalate, Crystal Structure, Luminescence Properties
Sheng-Chun Chen, Jing Qin, Zhi-Hui Zhang, Xiao-Xiao Cai, Jian Gao, Li Liu, Ming-Yang He, and Qun Chen
277  Full Text
A Silver(I) Coordination Polymer Based on a Schiff Base Ligand: Synthesis, Crystal Structure and Luminescence Properties
Key words: Silver(I), Coordination Polymer, Schiff Base, Luminescence
Lin Yu Jin, Meng Meng Li, Dong Bin Dang, Yan Bai, and Yan Ning Zheng
284  Full Text
A Polyketide Metabolite from an Endophytic Fusarium equiseti in a Medicinal Plant
Key words: Endophyte, Fusarium equiseti, Antimicrobial Activity
Yoshihito Shiono, Fumiaki Shibuya, Tetsuya Murayama, Takuya Koseki, Herve Martial Poumale Poumale, and Bonaventure Tchaleu Ngadjui
289  Full Text
Antifungal Activity of a Polyacetylene against the Fungal Pathogen of Japanese Oak from the Liquid Culture of the Edible Mushroom, Hypsizygus marmoreus
Key words: Japanese Oak Wilt, Hypsizygus marmoreus, Raffaelea quercivora, Polyacetylene
Yoshihito Shiono, Masatomo Haga, Hiromasa Koyama, Testuya Murayama, and Takuya Koseki
293  Full Text
Synthesis, Single-crystal Structure and Raman Spectrum of Cu[N(CN)2]2 · 2 NH3
Key words: Copper(II), [N(CN)2]2 Anion, Ammonia, Dicyanamide, Raman Spectrum
O. Reckeweg, A. Schulz and F. J. DiSalvo
296  Full Text
Synthesis of Ce2Rh3Ge5 Crystals from a Bismuth Flux
Key words: Cerium, Intermetallics, Crystal Chemistry, Crystal Growth
Daniel Voßwinkel and Rainer Pöttgen
301  Full Text
N u m b e r  4 (Graphical Abstracts)
Original Communications
Barium Triel Mercurides BaMxHg4−x and Ba3MxHg11−x (M = Ga, In, Cd) (In German)
Key words: Mercurides, Barium, Trieles, Crystal Structure, Electronic Structure
Marco Wendorff and Caroline Röhr
307  Full Text
Crystal Structures of the Alkali Thiosulfates A2S2O3 · nH2O (A/n = K/0, K/1/3, Rb/1) (In German)
Key words: Thiosulfate, Hydrates, Potassium, Rubidium, Crystal Structure
Anna J. Lehner, Lisa V. Schindler and Caroline Röhr
323  Full Text
Single-crystal Structure Determination and Spectroscopic Characterization of KSr4(BO3)3
Key words: High Pressure, Borate, Crystal Structure, Raman Spectroscopy, IR Spectroscopy
Gerhard Sohr, Doris Clara and Hubert Huppertz
338  Full Text
Hydrothermal Synthesis and Crystal Structure of a Meso-Helical Chain Based on Lindqvist Polyoxometalates
Key words: Polyoxometalate, Lindqvist, Helical Structure, Hydrothermal Synthesis
Chun-Jing Zhang, Rui Fang, Yan Yu, Hai-Jun Pang, Hui-Yuan Ma, De-Sheng Cui, and Dong-Ping Li
345  Full Text
Synthesis and Crystal Structure of a Mn(II) Metal-Organic Framework Based on a Polydentate Schiff Base Ligand
Key words: Manganese(II), Metal-Organic Framework, Schiff Base, Crystal Structure
Jun Li Wang, Hai Yan Li, Chen Hong Liu, and Yan Bai
351  Full Text
Mixed Linker Strategy for the Construction of a Fluorescent 2D Network Based on [Ag2(COO)2] as Secondary Building Unit
Key words: Silver(I), 2-Amino-4,6-dimethylpyrimidine, 2,6-Naphthalenedicarboxylic Acid, Photoluminescence
Di Sun, Shuai Yuan, Shan-Shan Liu, Ya-Qin Zhao, Lu-Lu Han, and Xing-Po Wang
357  Full Text
TiO2 Nanoparticles as an Efficient Catalyst for the One-pot Preparation of Tetrahydrobenzo[c]acridines in Aqueous Media
Key words: Aqueous Media, Domino Knoevenagel-Michael Condensation, Tetrahydrobenzo[c]acridinones, TiO2 Nanoparticles
Shahrzad Abdolmohammadi, Mahdieh Mohammadnejad and Faezeh Shafaei
362  Full Text
3-Pyrenylacrylates: Synthetic, Photophysical, Theoretical and Electrochemical Investigations
Key words: Arenes, Polycycles, Pyrene, Density Functional Calculations, Electrochemistry, UV/Vis Spectroscopy
Sebastian Reimann, Muhammad Sharif, Kai Wittler, Leif R. Knöpke, Annette-E. Surkus, Christian Roth, Ralf Ludwig, and Peter Langer
367  Full Text
Regioselective Synthesis of 5-(2-Methoxyethyl)biphenyls by Formal [3+3] Cyclocondensations of 1,3-Bis(trimethylsilyloxy)-1,3-butadienes
Key words: Arenes, Cyclizations, Silyl Enol Ethers, Regioselectivity
Franziska Bendrath, Verena Specowius, Zharylkasyn A. Abilov, Ashot. S. Saghyan, Christine Fischer, and Peter Langer
378  Full Text
Synthesis and Biological Activity of Novel Deoxynojirimycin Derivatives as Potent α-Glucosidase Inhibitors
Key words: 1-Deoxynojirimycin, α-Glucosidase Inhibitor, Diabetes Mellitus
Dan Yu, Fangfang Hu, Yu Zhang, Xiaorui Zheng, Chunxiang Kuang, and Qing Yang
383  Full Text
Synthesis of 1,4-Disubstituted 1,2,3-Triazoles from Aromatic α-Bromoketones, Sodium Azide and Terminal Acetylenes via Cu/Cu(OTf)2-catalyzed Click Reaction under Microwave Irradiation
Key words: Click Reaction, Copper/Copper Triflate, Cycloaddition, α-Bromoketones, 1,4-Disubstituted 1,2,3-Triazoles, Three-Component Reaction, Microwave Irradiation
Azadeh Fazeli, Hossein A. Oskooie, Yahya S. Beheshtiha, Majid M. Heravi, Firouz Matloubi Moghaddam, and Behzad Koushki Foroushani
391  Full Text
Synthesis of N-Acylated 1,5-Benzodiazepines: Differentiation between Two Possible Acylation Sites via Hydrogen Bonding
Key words: 1,5-Benzodiazepine, Intramolecular Hydrogen Bond, N-Acylation, Regioselectivity
Carlos A. Escobar, Odette A. Alvarado, Judith A. K. Howard, and Mauricio Fuentealba
397  Full Text
Synthesis, Crystal Structure and Properties of a Chiral 2D Zn(II) Coordination Polymer with Helical Chains
Key words: Helical, Chiral, Supramolecule, Hydrogen Bonding, Luminescence, Zinc, Benzoate Ligands
Ting-Ting Kang, Hao Tang, Yong-Li Wei, and Shuang-Quan Zang
403  Full Text
N u m b e r  5 / 6 (Graphical Abstracts)
To Professor Heinrich Nöth on the Occasion of his 85th Birthday
Hubert Schmidbaur, Rainer Pöttgen, Gerhard Maas, Thomas Lindel, Annette Schier, Gerhard Müller, and Tamina Greifeld
409 Open Access
Regioselective Functionalization of Pyridines using a Directed Metalation or a Halogen/Metal Exchange
Key words: Pyridines, C-H Activation, Halogen/Metal Exchange
Sophia M. Manolikakes, Nadja M. Barl, Christoph Sämann, and Paul Knochel
411  Full Text
Fluorescence Microscopy Studies of Porous Silica Materials
Key words: Porous Silica, Fluorescence Microscopy, Single Molecule Spectroscopy, Review Article
Bastian Rühle, Melari Davies, Thomas Bein, and Christoph Bräuchle
423  Full Text
Original Communications
Coordination of N-Heterocyclic Carbene to H2SiX2 (X = Cl, OTf) and H3SiOTf (OTf = OSO2CF3): Synthesis of Donor-stabilized Parent Silylium Salts with Four- and Five-coordinate Silicon Atoms
Key words: Silicon, Silane Complexes, Hypercoordination, Main Group Elements
Yun Xiong, Shenglai Yao and Matthias Driess
445  Full Text
N-Heterocyclic Carbene-facilated Condensation of 3-Methylphenylboronic Acid to the Boroxine
Key words: Carbene, Boroxine, Adduct
Dongxiang Zhang, Jie Li, Xiao Dong, Xing Zhou, Zhi Yang, and Herbert W. Roesky
453  Full Text
Nickel(II) and Iron(II) Complexes with Tetradentate NHC/Amide Hybrid Ligands
Key words: Nickel, Iron, N-Heterocyclic Carbene, Chelate Ligand, X-Ray Crystallography, Mößbauer Spectroscopy, Redox Properties
Iris Klawitter, Steffen Meyer, Serhiy Demeshko, and Franc Meyer
458  Full Text
Ligand Exchange at a Gold(I) Carbene Complex
Key words: N-Heterocyclic Carbene, Phosphine, Acetylide Ligand, Gold Complexes
Mareike C. Jahnke, Tania Pape and F. Ekkehardt Hahn
467  Full Text
Amine Complexes of Gold, Part 7: Pseudosymmetry in Amine Complexes of Gold(I) Cyanide (In German)
Key words: Gold, Cyanide, Amine, Secondary Interactions
Cindy Döring and Peter G. Jones
474  Full Text
Cyclic Alkyl(aryl)boranes for 1,1-Carboboration of Monoalkynyltin Compounds
Key words: Triorganoboranes, 1,1-Carboboration, Alkynyltin Compounds, NMR Spectroscopy, X-Ray Analysis
Bernd Wrackmeyer, Peter Thoma and Wolfgang Milius
493  Full Text
Hydroalumination versus Deprotonation of Alkynes with Sterically Demanding Substituents
Key words: Aluminium, Gallium, Hydroalumination, Hydrogallation, Alkynes
Werner Uhl, Marcus Layh, Ines Rhotert, Agnes Wollschläger, and Alexander Hepp
503  Full Text
Synthesis and Characterization of Strontium Bis(N-isopropylanilide) and Comparison with the Lighter Magnesium and Calcium Congeners
Key words: Amides, Anilides, Magnesium Amides, Strontium Amides, N-Isopropylanilides
Claas Loh, Carsten Glock, Steffen Ziemann, Helmar Görls, Sven Krieck, and Matthias Westerhausen
518  Full Text
Preparation of CaCO3 and CaO Replicas Retaining the Hierarchical Structure of Spruce Wood
Key words: Wood Template, Calcium Carbonate, Submicron Particles, Hierarchical
Somruedee Klaithong, Daniel Van Opdenbosch, Cordt Zollfrank, and Johann Plank
533  Full Text
The 1:1 Adduct of 1,3-Diisopropyl-4,5-dimethyl-2,3-dihydroimidazol-2-ylidene and Nitrous Oxide
Key words: N-Heterocyclic Nucleophilic Carbenes, Nitrous Oxide, Stereochemistry, X-Ray Crystallography
M. Göhner, P. Haiss, N. Kuhn, M. Ströbele, and K.-P. Zeller
539  Full Text
Coordination Chemistry of Polynitriles, I. Syntheses and Crystal Structures of [Ag(PCC)(DMF)], [Ni(DMF)6](PCC)2 and [Co(DMF)6](PCC)2 (PCC = [C5(CN)5], DMF = N,N-Dimethylformamide)
Key words: Silver, Cobalt, Nickel, Zinc, Pentacyanocyclopentadienide, Dimethylformamide Complexes
Karlheinz Sünkel and Dietmar Reimann
546  Full Text
Synthesis and Coordination Chemistry of a Tris(benzene-o-dithiolato)-functionalized Ligand as a Siderophore Analog
Key words: Tripods, Benzene-o-dithiolato Ligand, X-Ray Diffraction, Titanium
Susanne Ruppel, Christian Schulte to Brinke and F. Ekkehardt Hahn
551  Full Text
A Dinuclear Palladium(II) Complex of the {N(SPPh2)2} Ligand – Synthesis and Structure
Key words: Bimetallic Complex, Palladium, PNP Ligand, S Donor Ligand
Sebastian Marks and Peter W. Roesky
557  Full Text
Heterometallic Complexes with Rhenium- and Iron-Bismuth Bonds
Key words: Bismuth, Rhenium, Iron, Hydrides, Heterometallic Complexes
Rafael Schiwon, Ramona Metzinger, Christina Pfirrmann, and Christian Limberg
561  Full Text
Isolation, Optical Properties and Core Structure of a Water-soluble, Phosphine-stabilized [Au9]3+ Cluster
Key words: Cluster Compounds, Gold, Structure Elucidation, Nanotechnology
Benjamin S. Gutrath, Carina Merkens, Frank Schiefer, Ulli Englert, Günter Schmid, and Ulrich Simon
569  Full Text
[Cu40Se16(S-C6H4-CN)8(dppm)8]: A Disc-like Copper Cluster with a Nitrile-functionalized Ligand Shell
Key words: Copper, Chalcogens, Cluster Compounds, X-Ray Diffraction, IR Spectroscopy
Robert Langer, Dieter Fenske and Olaf Fuhr
575  Full Text
Ferromagnetism and the Formation of Interlayer As2 Dimers in Ca(Fe1−xNix)2As2
Key words: Intermetallic Compounds, Crystal Structures, ThCr2Si2-type Structure, Chemical Bonding, Ferromagnetism
Roman Pobel, Rainer Frankovsky and Dirk Johrendt
581  Full Text
Oxidation Reactions Catalyzed by Polyoxomolybdate Salts
Key words: Catalysis, Ionic Liquids, Molybdenum, Oxidation, Polyoxomolybdate, Epoxides, Sulfoxides
Bo Zhang, Su Li, Alexander Pöthig, Mirza Cokoja, Shu-Liang Zang, Wolfgang A. Herrmann, and Fritz E. Kühn
587  Full Text
Synthesis and Characterization of Imidazolium Perrhenate Ionic Liquids
Key words: Ionic Liquids, Physical Properties, Perrhenate, Rhenium, Synthesis
Shuang Yue, Da-Wei Fang, Jun Li, Shu-Liang Zang, Ming-Dong Zhou, Bo Zhang, Iulius I. E. Markovits, Mirza Cokoja, and Fritz E. Kühn
598  Full Text
Infinite Anionic Chains Formed by Alternating Bidentately Acting [SbS4]3− Anions and [Mn(dien)]2+ Complexes in the Compound [Mn(dien)2][Mn(dien)SbS4]2
Key words: Thioantimonates, Solvothermal Syntheses, Crystal Structure
Nicola Herzberg, Christian Näther and Wolfgang Bensch
605  Full Text
Novel Polyanionic Topologies in Ag2VAsO6 and Ag6V2As2O13
Key words: Silver, Vanadates, Arsenates, Crystal Structure, High Pressure Synthesis
Jürgen Nuss, Jan Curda and Martin Jansen
611  Full Text
Syntheses and Crystal Structures of the Bromide-derivatized Lanthanoid(III) Ortho-Oxomolybdates(VI) LnBr[MoO4] (Ln = Pr, Nd, Sm, Gd–Lu)
Key words: Lanthanoids, Bromides, Oxomolybdates, Crystal Structure
Tanja Schustereit, Harald Henning, Thomas Schleid, and Ingo Hartenbach
616  Full Text
Single-crystal Data of Ternary Germanides RE2Nb3Ge4 (RE = Sc, Y, Gd–Er, Lu) and Sc2Ta3Ge4 with Ordered Sm5Ge4-type Structure
Key words: Rare Earth Compounds, Crystal Structure, Chemical Bonding, Germanium
Bastian Reker, Samir F. Matar, Ute Ch. Rodewald, Rolf-Dieter Hoffmann, and Rainer Pöttgen
625  Full Text
RE4B4O11F2 (RE = Pr, Nd): Two New Rare-earth Fluoride Borates Isotypic to Gd4B4O11F2
Key words: Rare-Earth, Fluoride, Borate, High Pressure, Crystal Structure
Matthias Glätzle and Hubert Huppertz
635 Open Access
Synthesis, Crystal Structures and Polymorphism of New Cadmium and Zinc Thio- and Selenocyanato Coordination Compounds with 4-Acetylpyridine as N-Donor Ligand
Key words: Synthesis, Thio- and Selenocyanato Coordination Compounds, Crystal Structures, Thermoanalytical Measurements
Julia Werner, Inke Jess and Christian Näther
643  Full Text
Novel Tin(IV) Complexes with the Hybrid Guanidine Ligand DMEGqu
Key words: Guanidine Ligands, Tin Complexes, X-Ray Diffraction, Density Functional Theory
Anton Jesser, Ines dos Santos Vieira and Sonja Herres-Pawlis
653  Full Text
Facile 1,1-Carboboration Reaction of a Diarylphosphino-substituted Conjugated Diyne with Tris(pentafluorophenyl)borane
Key words: Carboboration, Boron, Phosphorus, Frustrated Lewis Pair
Philipp Feldhaus, Gerald Kehr, Roland Fröhlich, Constantin G. Daniliuc, and Gerhard Erker
666  Full Text
New Pulvinic Acid and Phenylalaninol Derivatives from the Mushrooms Retiboletus griseus and R. nigerrimus
Key words: Pulvinic Acids, N-(Protocatechuyl)phenylalaninols, Fungi, Taxonomy, Synthesis
Gertraud Gruber, Lydia Kerschensteiner, Ryuji Marumoto, and Wolfgang Steglich
675  Full Text
NIR Absorption of Perylene Dyes and Fluorescence with Large Stokes' Shift by Simple Deprotonation
Key words: Dyes, Fluorescence Spectroscopy, NIR, ESPT, ESIPT, Perylenes
Heinz Langhals and Maximilian Rauscher
683  Full Text
Molecular and Crystal Structure of Chlorido[2-(N,N,N′,N′-tetramethylamidinio)ethynido]silver
Key words: Acetylenic Amidinium Salts, Alkynyl Silver Compound, 3,3-Diaminoallenylidene Silver Complex
Werner Weingärtner and Gerhard Maas
687  Full Text
Nucleophilic Reactivities of Schiff Bases
Key words: Kinetics, Linear Free Energy Relationship, Imine, Azomethine, Carbenium Ions
Biplab Maji and Herbert Mayr
693  Full Text
Synthesis of 6-Ethyl-1,2,9-trioxopyrrolo[3,2-f]quinoline-8-carboxylic Acid
Key words: 6-Amino-1-ethyl-4-oxoquinoline-3-carboxylic Ester, Isonitroso-acetamido Derivative, Regioselective Annelation, Stable Hydrated Isatin Moiety, 1,2,9-Trioxopyrrolo[3,2-f]quinoline Derivatives
Randa M. Al-As'ad, Mustafa M. El-abadelah, Salim S. Sabri, Jalal A. Zahra, and Wolfgang Voelter
700  Full Text
Synthesis of a 30-Membered Macrocycle Incorporating Two Ruthenium Sandwich Complexes
Key words: Cation Exchange Chromatography, Diaryl Ethers, Macrocycles, Ruthenium, Sandwich Complexes
Alexander Schmid, Kurt Polborn and Thomas Lindel
707  Full Text
Novel Insensitive Energetic Nitrogen-rich Polymers Based on Tetrazoles
Key words: Tetrazoles, Polymers, Energetic Performance, Thermal Properties
Franziska M. Betzler, Ruth Boller, Adriana Grossmann, and Thomas M. Klapötke
714  Full Text
Structures of Energetic Acetylene Derivatives HC≡CCH2ONO2, (NO2)3CCH2C≡CCH2C(NO2)3 and Trinitroethane, (NO2)3CCH3
Key words: Gas-phase Electron Diffraction, X-Ray Diffraction, High Energy Dense Oxidizer, Trinitromethyl, Silver NMR
Thomas M. Klapötke, Burkhard Krumm, Richard Moll, Alexander Penger, Stefan M. Sproll, Raphael J. F. Berger, Stuart A. Hayes, and Norbert W. Mitzel
719  Full Text
First Incorporation of the Tetrahedral [Sn4]4− Cluster into a Discrete Solvate Na4[Sn4]·(NH3)13 from Solutions of Na4Sn4 in Liquid Ammonia
Key words: Cluster Compounds, Zintl Anions, X-Ray Diffraction, Solubility, Tetrahedral Zintl Clusters, Tin Clusters
Markus Waibel and Thomas F. Fässler
732  Full Text
Synthesis and Structure of 2,2,2-Nitrilotriacetyl Chloride with a Flat NC3 Pyramide
Key words: 2,2,2-Nitrilotriacetic Acid, Phosphorus Pentachloride, Multinuclear NMR Spectroscopy, Vibrational Analysis, X-Ray Diffraction
Thomas M. Klapötke, Burkhard Krumm and Richard Moll
735  Full Text
Cobalt(III)-Binding of Gluconate and 2-Amino-2-Deoxy-Gluconate
Key words: Gluconate, 2-Amino-2-deoxy-gluconate, Glucosaminate, Cobalt(III)
Max Pfister, Sarah Illi and Peter Klüfers
739  Full Text
Activation of C–Cl Bonds: Synthesis and Structural Characterization of [Ru2(μ-Cl)(μ-PtBu2)(μ-Ph2PN(H)PPh2)(CO)4]
Key words: Ruthenium, Phosphanido-bridged, Coordinative Unsaturation, X-Ray Diffraction
Tobias Mayer and Hans-Christian Böttcher
743  Full Text
A Base-stabilized Iodoborylene Complex of Platinum(II)
Key words: Boron, Borylene, Base Stabilization, Iodine, Transition Metal Complex
Holger Braunschweig, Peter B. Brenner, Rian D. Dewhurst, and Krzysztof Radacki
747  Full Text
N u m b e r  7 (Graphical Abstracts)
Original Communications
Oxide Fluoride Sulfides of the Lanthanoids with the Formula M6O2F8S3 (M = La–Nd, Sm, Gd) (In German)
Key words: Lanthanoids, Oxide Fluoride Sulfides, Crystal Structures
Hagen Grossholz, Dirk D. Zimmermann, Oliver Janka, and Thomas Schleid
751  Full Text
Potassium Double Salts with the Mixed Trisulfidometalate Ions [MoOS3]2− and [WOS3]2− (In German)
Key words: Molybdenum, Tungsten, Thiooxometalates, Oxidosulfidometalates, Crystal Structure
Anna J. Lehner and Caroline Röhr
761  Full Text
Three 3D Metal-Organic Frameworks Constructed from Keggin Polyanions and Multi-nuclear AgI Clusters: Assembly, Structures and Properties
Key words: Keggin Polyoxometalate, Tetrazole-based Ligand, Metal-Organic Framework, Photocatalytic Properties, Electrochemical Properties
Xiu-Li Wang, Na Li, Ai-Xiang Tian, Jun Ying, Guo-Cheng Liu, Hong-Yan Lin, and Dan Zhao
778  Full Text
Zn(II) and Cd(II) Coordination Polymers with an N,O-Donor Ligand: Structural Characterization and Fluorescence Properties
Key words: Zn(II), Cd(II), Metal-Organic Frameworks, Fluorescence and Thermal Decay
Hai-Wei Kuai, Xiao-Chun Cheng and Xiao-Hong Zhu
789  Full Text
Loop-containing One-dimensional Metal-Organic Frameworks from Flexible Betaine Linkers and Zinc Salts by Controlled Synthesis
Key words: Metal-Organic Frameworks, Loop Motif, Solvothermal Synthesis, Double Betaine, Solvent Effects
Doufeng Wu, Yang Wang, Qiaowei Li, and Lijuan Zhang
797  Full Text
Synthesis and Characterization of 3-Chloropropyl-substituted o-Carboranes: Crystal Structures of 1,2-(1,3-Propanediyl)-o-carborane, 1-(3-Chloropropyl)-o-carborane and 1,2-Bis(3-chloropropyl)-o-carborane
Key words: o-Carborane, Chloropropyl, Functionalization, Synthesis, Crystal Structure
Deqian Bian, Yong Nie, Jinling Miao, Zhenwei Zhang, and Ping Lu
804  Full Text
Diastereoselective 1,3-Dioxolane Formation by Photocatalytic Ring Opening of α-Epoxyketones
Key words: DDQ, Electron Transfer, α-Epoxyketones, Photocatalyst, Ring Opening
Hamid Reza Memarian and Sakineh Zare
811  Full Text
Solvent-free Synthesis of 1,2-Disubstituted Derivatives of 1,2-Dihydroisoquinoline, 1,2-Dihydroquinoline and 1,2-Dihydropyridine
Key words: 1,2-Dihydroisoquinoline, Solvent-free, Phenylcarbamate, 1,2-Dihydroquinoline, 1,2-Dihydropyridine
Rahimeh Hajinasiri and Sobhan Rezayati
818  Full Text
Cyclocondensations of Substituted Thiosemicarbazides with 2-Bromo-1,2-diphenylethan-1-one
Key words: Cyclizations, Heterocycles, Thiadiazines, Regioselectivity, Thiazoles, Rearrangement
Wolf-Diethard Pfeiffer, Helmut Gille, Ehrenfried Bulka, Ashot Saghyan, and Peter Langer
823  Full Text
Synthesis of Homophthalates by [3 + 3] Cyclocondensation Reactions of 1,3-Bis(silyloxy)-1,3-butadienes with Silylated Methyl 3,5-Dioxohexanoate
Key words: Homophthalates, Cyclizations, Silyl Enol Ethers, Regioselectivity
Jennifer Hefner, Alexander Villinger and Peter Langer
831  Full Text
4-tert-Butoxy-1-ethoxy-1,3-bis(trimethylsilyloxy)-1,3-butadiene. A New Diene and its Application to the Synthesis of γ-Alkylidenetetronic Acids
Key words: Butenolides, Cyclizations, O-Heterocycles, Oxalic Acid, Silyl Enol Ethers
Van Thi Hong Nguyen, Bui Duy Cam, Zafar Ahmed, and Peter Langer
836  Full Text
Equilibrium Structures and Vibrational Assignments for Isoamyl Alcohol and tert-Amyl Alcohol: A Density Functional Study
Key words: Isoamyl Alcohol, tert-Amyl Alcohol, Vibrational Assignments, Molecular Structures, DFT Study
Wolfgang Förner and Hassan M. Badawi
841  Full Text
N u m b e r  8 (Graphical Abstracts)
Original Communications
Crystal Structures of the Gold(I) Phosphinine Complexes [AuCl(C5H2P-2,6-Me2-4-Ph)] and [AuCl(C5H2P-2,4,6-Ph3)]
Key words: Aurophilicity, Crystal Structure, Gold, Gold-π Interaction, Phosphinine
Jonathan Stott, Clemens Bruhn and Ulrich Siemeling
853  Full Text
Phosphane Chalcogenides and their Metal Complexes. I. Structures of some Diphosphane Monochalcogenides (In German)
Key words: Diphosphane, Chalcogenide
Christina Taouss and Peter G. Jones
860  Full Text
One-dimensional Gold Clusters in HP-Ce7Au13+xGe10−x
Key words: High-pressure Synthesis, Cerium, Germanide, Crystal Structure, Gold
Gunter Heymann, Birgit Heying, Jan F. Riecken, Hubert Huppertz, and Rainer Pöttgen
871  Full Text
A Mn(II) Coordination Polymer with Sulfate and trans-1,2-Bis(4-pyridyl)ethylene Bridges: Synthesis, Structure, Magnetic and Ferroelectric Properties
Key words: Manganese, trans-1,2-Bis(4-pyridyl)ethene, Sulfate, Coordination Polymer, Topology, Properties
Wei Xu and Jian-Li Lin
877  Full Text
Ligand-free Palladium/Copper Co-catalyzed Direct Arylation of Polyfluoroarenes with Aryl Iodides
Key words: C–H Activation, Arylation, Polyfluoroarenes
Xinyan Zhang, Jian Yu and Guobing Yan
885  Full Text
Photooxidation of Methane to Methanol by Perrhenate in Water under Ambient Conditions
Key words: Rhenium Complexes, Photochemistry, Methane, Catalysis
Horst Kunkely and Arnd Vogler
891  Full Text
A Novel Route to Isoquinoline[2,1-g][1,6]naphthyridine, Pyrazolo[5,1-a] isoquinoline and Pyridazino[4′,5′:3,4]pyrazolo[5,1-a]isoquinoline Derivatives With Evaluation of Antitumor Activities
Key words: Isoquinoline-1-acetonitrile, Naphthyridines, Pyrazoloisoquinolines, Pyridazinopyrazoloisoquinolines, Hydroxamoyl Chlorides, Antitumor Activity
Hamdi M. Hassaneen, Wagnat W. Wardkhan and Yasmin Sh. Mohammed
895  Full Text
Facile Synthesis of Thiazole, Thiazine and Isoindole Derivatives via EDA Approach and Conventional Methods
Key words: N-Amidinothiourea, Thiazoles, Thiazines, Isoindole, EDA Interaction
Kamal M. El-Shaieb, Mohamed A. Ameen, Fathy F. Abdel-latif, and Asmaa H. Mohamed
905  Full Text
The Chemical and Structural Properties of 2-Aminobenzylamine Derivatives
Key words: 2-Aminobenzylamine, π Acceptors, Anhydrides, Quinazolines, Diazepines
Kamal M. El-Shaieb and Peter G. Jones
913  Full Text
Steroids and Ceramide from the Stem Bark of Odyendyea gabonensis
Key words: Odyendyea gabonensis, Simaroubaceae, Steroids, Ceramide, Antimicrobial and Cytotoxicity Activities
Emmanuel Ngeufa Happi, Simone Véronique Fannang, Marie Fomani, Suzye Mireille Moladje Donkwe, Nkoungou Yomzak Carine Nicaise, Jean Duplex Wansi, and Norbert Sewald
924  Full Text
Antimicrobial and Antioxidant Isoflavonoid Derivatives from the Roots of Amphimas pterocarpoides
Key words: Amphimas pterocarpoides, Isoflavones, Chemical Transformations, Antimicrobial Properties, Antioxidant Activities
Edwige P. Fodja Saah, Valerie Tedjon Sielinou, Victor Kuete, Stephen T. Lacmata, and Augustin E. Nkengfack
931  Full Text
Zahramycins A-B, Two New Steroids from the Coral Sarcophyton trocheliophorum
Key words: Zahramycins, Polyoxygenated Sterols, Sarcophyton trocheliophorum, Biological Activity
Mohamed Shaaban, Mohamed A. Ghani and Khaled A. Shaaban
939  Full Text
Reductive Ullmann Coupling of Aryl Halides by Palladium Nanoparticles Supported on Cellulose, a Recoverable Heterogeneous Catalyst
Key words: Ullmann C–C Coupling, Aryl Halides, Palladium Nanoparticles, Cellulose Support, Recoverable Catalyst
Mohammad Ali Rasouli and Parviz Rashidi Ranjbar
946  Full Text
N u m b e r  9 (Graphical Abstracts)
Original Communications
High-pressure Synthesis and Characterization of the Rare-earth Fluoride Borate LaB2O4F
Key words: High Pressure, Borate, Crystal Structure, DFT
Ernst Hinteregger, Krisztina Kocsis, Thomas S. Hofer, Gunter Heymann, Lukas Perfler, and Hubert Huppertz
951  Full Text
Cerium Valence Change in the Solid Solutions Ce(Rh1−xRux)Sn
Key words: Cerium, Intermediate, Valence, Magnetic Properties
Oliver Niehaus, Paula M. Abdala, Jan F. Riecken, Florian Winter, Bernard Chevalier, and Rainer Pöttgen
960  Full Text
Ternary Antimonides RE4T7Sb6 (RE = Gd–Lu; T = Ru, Rh) with Cubic U4Re7Si6-type Structure
Key words: Antimonides, Crystal Structure, Magnetic Properties
Inga Schellenberg, Ute Ch. Rodewald, Christian Schwickert, Matthias Eul, and Rainer Pöttgen
971  Full Text
Zirconium Transition Metal (Poly)antimonides – Syntheses, Characterization and Electrochemical Properties
Key words: Polyantimonides, Zirconium, Transition Metals, Antimony
Magnus Greiwe, Maximilian Krause, Oliver Osters, Alma Dorantes, Michele Piana, and Tom Nilges
979  Full Text
Synthesis and Crystal Structure of a Copper(II) Inorganic-Organic Hybrid Polymer Based on [β-Mo8O26]4− and 4,4′-Bipyridine-N,N′-dioxide
Key words: β-Octamolybdate, Copper(II), Polymer, Crystal Structure
Yan Hua Fan, Lei Li, Shuai Chen, Rui Min Zhou, Yan Bai, and Dong Bin Dang
987  Full Text
Syntheses, Crystal Structures and Electrochemical Properties of Acetylacetonato-Ruthenium Complexes Containing Substituted Pyridine Ligands
Key words: Ruthenium, Acetylacetonato Ligand, Pyridine, Synthesis, Crystal Structure
Xiuli Wu, Rufei Ye, Ai-Quan Jia, Qun Chen, and Qian-Feng Zhang
993  Full Text
Co(II) and Cd(II) Complexes Based on 5-[(2-Methyl-1H-imidazol-1-yl)methyl]isophthalate: Syntheses, Characterization and Properties
Key words: Cobalt(II), Cadmium(II), Structural Characterization, Fluorescence
Xiao-Chun Cheng, Xiao-Hong Zhu and Hai-Wei Kuai
1000  Full Text
Syntheses, Structural Characterization and Fluorescence of Zn(II) and Cd(II) Polymers from 5-(Pyridin-2-ylmethylamino)isophthalic acid
Key words: Zinc(II), Cadmium(II), Structural Characterization, Fluorescence
Xiao-Chun Cheng, Xiao-Hong Zhu and Hai-Wei Kuai
1007  Full Text
Synthesis, Crystal Structure and Magnetic Properties of a Mn(II) Fluorenedicarboxylate Complex
Key words: Solvothermal Synthesis, Crystal Structure, Fluorenedicarboxylate, Mn(II) Complex
Xiu-Hua Zhao, Ya-Yun Zhao, Mei-Qin Zha, and Xing Li
1015  Full Text
Synthesis of Functionalized Acetophenones by Formal [3 + 3] Cyclocondensations of 1,3-Bis(silyloxy)-1,3-butadienes with 3-Alkoxy- and 3-Silyloxy-2-acetyl-2-en-1-ones
Key words: Cyclizations, Arenes, Regioselectivity, Acetophenones, Silyl Enol Ethers
Rüdiger Dede, Abdolmajid Riahi, Mohanad Shkoor, Mirza A. Yawer, Ibrar Hussain, Nazken Kelzhanova, Zharylkasyn A. Abilov, Abiodun Falodun, Helmar Görls, and Peter Langer
1021  Full Text
Synthesis of 4-Aminocoumarin Derivatives with N-Substitutents Containing Hydroxy or Amino Groups
Key words: Hydroxycoumarins, Aminocoumarins, Aminoalcohols, Alkanediamines, Crystal Structure
Ivo C. Ivanov, Violina T. Angelova, Nikolay Vassilev, Ioannis Tiritiris, and Boyan Iliev
1031  Full Text
Isolation and Characterization of Limonoids from Kigelia africana
Key words: Kigelia africana, Methanolic Extract, Limonoids, Solid-state ECD/TDDFT Method, Enzyme Inhibition
Bushra Jabeen, Naheed Riaz, Muhammad Saleem, Muhammad Akram Naveed, Maqsood Ahmed, Muhammad Nawaz Tahir, Gennaro Pescitelli, Muhammad Ashraf, Syeda Abida Ejaz, Irshad Ahmed, and Abdul Jabbar
1041  Full Text
Heterocycles [f]-Fused onto Quinolones. Synthesis of Novel Dioxo-N-ethylpyrano[2,3-f]- and [3,2-f]quinoline-10-carboxylic Acids
Key words: 7-Aminoflavone, 6-Aminoflavone, 7-Amino-2-methyl-4H-chromen-4-one, Regioselective Cyclization, Pyrano[2,3-f] and [3,2-f]quinolones
Almeqdad Y. Habashneh, Mustafa M. El-Abadelah, Mohammad S. Mubarak, and Wolfgang Voelter
1049  Full Text
N u m b e r  10 (Graphical Abstracts)
Ionic Liquids in Chemical Synthesis – Progress and Advantages as Compared to Conventional Solvents
C. Feldmann
1057 Open Access
Ionic Liquids for the Synthesis and Stabilization of Metal Nanoparticles
Key words: Metal Nanoparticles, Ionic Liquids, Metal Carbonyls, Microwave Irradiation, Catalysis
Christoph Janiak
1059  Full Text
Original Communications
[SbCl2(η2-1,4-dt)(μ2-1,4-dt)][AlCl4]: Ionic Liquid-based Synthesis of a Stibenium Cation (dt = dithiane)
Key words: Stibenium Cation, Ionic Liquid, Crystal Structure, 1,4-Dithiane
Dominic Freudenmann and Claus Feldmann
1090  Full Text
Ionic Liquids Based on Hexachloridometalate(V) Anions (Sb, Nb and Ta) and Nitrile-functionalized Pyridinium Cations
Key words: Ionic Liquids, [SbCl6], [NbCl6], [TaCl6], Crystal Structure, Raman Spectroscopy
Tao Xie, Zong Guan, Niels-Patrick Pook, and Mimoza Gjikaj
1095  Full Text
[HMIM][Br9]: a Room-temperature Ionic Liquid Based on a Polybromide Anion
Key words: Ionic Liquids, Polybromide Anions, Halogen Chemistry, Single-crystal X-Ray Diffraction, Raman Spectroscopy
Heike Haller, Michael Hog, Franziska Scholz, Harald Scherer, Ingo Krossing, and Sebastian Riedel
1103  Full Text
Substitution of Conventional High-temperature Syntheses of Inorganic Compounds by Near-room-temperature Syntheses in Ionic Liquids
Key words: Cluster Compounds, Ionic Liquids, Low-valent Compounds, Resource-efficient Synthesis, Sustainable Chemistry
Matthias F. Groh, Ulrike Müller, Ejaz Ahmed, Alexander Rothenberger, and Michael Ruck
1108  Full Text
BIOnic Liquids: Imidazolium-based Ionic Liquids with Antimicrobial Activity
Key words: Ionic Liquids, Active Pharmaceutical Ingredients (API), Imidazolium Salts, Antibiotics, Antimicrobials, Analgesics
Frank Postleb, Danuta Stefanik, Harald Seifert, and Ralf Giernoth
1123  Full Text
Surface-active Ionic Liquids for Micellar Extraction of Piperine from Black Pepper
Key words: Ionic Liquids, Micelles, Active Ingredient Isolation, Piperine, Biomass Processing, Sustainable Chemistry
Anna K. Ressmann, Ronald Zirbs, Martin Pressler, Peter Gaertner, and Katharina Bica
1129  Full Text
Epoxidation of Olefins Catalyzed by Polyoxomolybdates Formed in-situ in Ionic Liquids
Key words: Ionic Liquids, Homogeneous Catalysis, Epoxidation, Molybdenum
Lilian R. Graser, Sophie Jürgens, Michael E. Wilhelm, Mirza Cokoja, Wolfgang A. Herrmann, and Fritz E. Kühn
1138  Full Text
The Differential Capacitance of Ionic Liquid | Metal Electrode Interfaces – A Critical Comparison of Experimental Results with Theoretical Predictions
Key words: Ionic Liquid, Au(111), Interface, Differential Capacitance, Electrochemical Impedance Spectroscopy
Jens Wallauer, Marcel Drüschler, Benedikt Huber, and Bernhard Roling
1143  Full Text
Synthesis and Sorption Analysis of Task-specific Fluorous Ionic Liquids
Key words: Fluorous, Hydrofluoroether, Imidazole, Ionic Liquid, Sorption, Triazole
Verena Adamer, Gerhard Laus, Ulrich J. Griesser, and Herwig Schottenberger
1154  Full Text
Ionogel Fiber Mats: Functional Materials via Electrospinning of PMMA and the Ionic Liquid Bis(1-butyl-3-methyl-imidazolium) Tetrachloridocuprate(II), [Bmim]2[CuCl4]
Key words: Ionic Liquid, Ionogel, Electrospinning, Fiber, Hydrogen Production, Filtration
Christian Bagdahn and Andreas Taubert
1163  Full Text
N u m b e r  11 (Graphical Abstracts)
Original Communications
Bis(triphenylphosphine)gold(I) Perrhenate
Key words: Gold(I), Rhenate(VII), Crystal Structure, IR Spectra, Phosphine
Sebastian A. Baer, Alexander Pöthig, Salem M. Bawaked, Hubert Schmidbaur, and Florian Kraus
1173  Full Text
Tribosynthesis of Fe3−xMnxC Phases via Mechanical Alloying and Annealing
Key words: Cementite, Rietveld Refinement, Mixed Carbides, Tribochemistry, Planetary Mill, Manganese Steel
Hannes Dierkes, Andreas Möller and Richard Dronskowski
1180  Full Text
Lead-flux Growth of Eu4Ir8As7 Crystals
Key words: Arsenide, Lead Flux, Crystal Structure
Ulrike Pfannenschmidt and Rainer Pöttgen
1185  Full Text
From REZnSn to REZnSnH1.5 (RE = Pr, Nd) – Inducing Ferromagnetism through Hydrogenation
Key words: Stannides, Hydrogenation, Magnetic Properties
Bastian Reker, Bernard Chevalier, Oliver Niehaus, Ute Ch. Rodewald, and Rainer Pöttgen
1191  Full Text
High-pressure Syntheses and Characterization of the Rare-earth Fluoride Borates RE2(BO3)F3 (RE = Tb, Dy, Ho)
Key words: High Pressure, Lanthanoides, Fluoride, Borate, Crystal Structure
Ernst Hinteregger, Michael Enders, Almut Pitscheider, Klaus Wurst, Gunter Heymann, and Hubert Huppertz
1198  Full Text
Synthesis, Structures, and Catalytic Properties of Two Silver(I) Coordination Polymers Constructed from 1,4-Bis(benzimidazolyl)butane
Key words: Azo Dye, Bis(benzimidazolyl)butane, Catalysis, Crystal Structure, Photoluminescence, Phthalic Acid, Silver
Cui-Hong He, Jin-Ming Hao, Shu-Lin Xiao, and Guang Hua Cui
1207  Full Text
A Heterometallic MOC Assembled from Cobalt-bisupported Keggin Subunits
Key words: Polyoxometalate, Tungstoborates, Cobalt
Heng Liu, Ying Guo, Rui Ran, Huiyuan Ma, Haijun Pang, Huiqiu Zhang, and Chunyan Zhao
1214  Full Text
Synthesis, Structural Investigation and Characterization of an α-Keggin-based Organic-Inorganic Hybrid, [Cu(BIIM)2]{[Cu(BIIM)2(H2O)][Cu(BIIM)2BW12O40]·3H2O}2 (BIIM = 2,2′-Biimidazole)
Key words: Crystal Structure, Copper(II), Keggin, Hirshfeld Surface, Fingerprint Plots
Lin-Heng Wei, Zi-Liang Wang and Ming-Xue Li
1219  Full Text
Syntheses of Two Co(II) and Ni(II) Complexes with 2-(1H-Imidazolyl-1-methyl)-1H-benzimidazole and 1,4-Benzenedicarboxylate Ligands and Their Effect on Cardiac Fibroblasts Proliferation
Key words: Co(II) and Ni(II) Complexes, 2-(1H-Imidazolyl-1-methyl)-1H-benzimidazole, 1,4-Benzenedicarboxylate, Cardiac Fibroblast, Proliferation
Ying Wang, Shuxun Yan, Yanzhou Zhang, Lina Sun, and Zihan Wei
1225  Full Text
Synthesis, Structure and Properties of Lanthanide-Organic Frameworks with Imidazolylmethylisophthalate Ligands
Key words: Lanthanide(III), Isophthalate, Imidazolyl Ligand, Fluorescence
Xiao-Chun Cheng and Xiao-Hong Zhu
1233  Full Text
Synthesis and Crystal Structures of New 1,3-Disubstituted Imidazoline-2-thiones
Key words: Crystal Structure, Hydrogen Bond, Imidazole, Thione
Gerhard Laus, Volker Kahlenberg, Klaus Wurst, Thomas Müller, Holger Kopacka, and Herwig Schottenberger
1239  Full Text
Synthesis of Chiral Pyrimidin-2(1H)-ones from N-Carbamoyl Amino Acids
Key words: Heterocycles, Amino Acids, Condensation, Chirality, Pyrimidines
Ilya N. Egorov, Vladimir L. Rusinov and Oleg N. Chupakhin
1253  Full Text
Depsidones from an Endophytic Fungus Chaetomium sp. Associated with Zanthoxylum leprieurii
Key words: Endophyte, Chaetomium sp., Depsidones, Toxicity, Antimicrobial Activity
Ferdinand Mouafo Talontsi, Clovis Douanla-Meli and Hartmut Laatsch
1259  Full Text
The Crystal Structure of GdZn3
Key words: Intermetallics, Gadolinium, Zinc, Crystal Chemistry
Inna Bigun and Yaroslav M. Kalychak
1265  Full Text
Crystal Structure, and Magnetic and Fluorescence Properties of a New Terbium(III) Complex, [Tb(L)3(2,2′-bipy)(DMF)]·(2,2′-bipy)
Key words: Terbium(III) Complex, Crystal Structure, Magnetic and Fluorescence Properties
Ying-Qun Yang, Shao-Hua Zhang, Hong-Bo Tan, and Li-Xia Fu
1269  Full Text
N u m b e r  12 (Graphical Abstracts)
Original Communications
Magnesium-rich Intermetallics RE3RuMg7 (RE = Y, Nd, Dy, Ho) – Rows of Condensed Ru@RE6/2 Octahedra in Magnesium Matrices
Key words: Magnesium, Crystal Structure, Magnetic Properties, Dysprosium, Rare Earths, Ruthenium
Marcel Kersting, Ute Ch. Rodewald, Christian Schwickert, and Rainer Pöttgen
1273  Full Text
The Solid Solutions (Ce1−xLax)RuSn
Key words: Cerium, Stannide, Intermediate Valence
Oliver Niehaus, Bernard Chevalier, Paula M. Abdala, Florian Winter, and Rainer Pöttgen
1279  Full Text
In Search of the True Structure of the Sodium Chromium Alum II: Crystal Growth and Structure of the Double Salt NaCr(SO4)2(H2O)6 · (CH3OH)0.6(2) · (H2O)1.5(5)
Key words: Chromium Alums, Double Salt, Crystal Growth, Crystal Structure
Luitgard Rees-Isele, Hans-Peter Winkler and Egbert Keller
1288  Full Text
New Sulfido Antimonates of the Heavy Alkali Metals: Synthesis, Crystal Structure and Chemical Bonding of (K/Rb/Cs)3SbS3 and Cs3SbS4 ·H2O (In German)
Key words: Sulfidoantimonates, Thioantimonates, Rubidium, Cesium, Crystal Structure, Band Structure Calculation, Group-subgroup Relation
Lisa V. Schindler, Michael Schwarz and Caroline Röhr
1295  Full Text
Thermally Stable 3,6-Disubstituted 1,2,4,5-Tetrazines
Key words: Tetrazines, Energetic Materials, Crystal Structures
Thomas M. Klapötke, Andreas Preimesser and Jörg Stierstorfer
1310  Full Text
Synthesis of a Tri(gold)boride Complex (Cy3P)B[AuP(o-Tol)3]3
Key words: Gold, Boride, Phosphine Borane, Boron Coordination
Hubert Schmidbaur, M. Annette Blumenthal and Florian Kraus
1321  Full Text
Synthesis and Characterization of a Zinc(II) Complex of Bispicen
Key words: Zn(II)-bispicen Complex, Crystal Structure, FTIR Spectra
Beatriz S. Parajón-Costa, Gustavo A. Echeverría, Oscar E. Piro, and Enrique J. Baran
1327  Full Text
Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands
Key words: Triple Hydrogen Bond, Coordination Polymer, Fluconazole, UV/Vis Spectra, Fluorescence, Thermogravimetry
Gang-Hong Pan, Jing-Niu Tang, Xian-Hong Yin, Wei-Man Tian, and Zhong-Jing Huang
1333  Full Text
Preparation, Structural and Spectroscopic Characterization of a Pentaiodide [Rb(12-Crown-4)2]I5 (In German)
Key words: Pentaiodide, Crown Ether, Alkali Metal, Crystal Structure, Spectroscopy
Zehra Edis and Samir Haj Bloukh
1340  Full Text
Preparation of 1,2,5,6,9,10-Hexaalkoxyhexahelicenes
Key words: Helicenes, Photocyclization, Wittig–Horner Reaction, Siegrist Reaction
Manfred Schwertel, Sabine Hillmann and Herbert Meier
1347  Full Text
Electronic Structures of Organometallic Complexes of f Elements, 81. Calculation of the Normal Modes of La(η5-C5H5)3(NCCH3)2 on the Basis of Density Functional Theory as well as Vibronic Couplings and Identification of Further Purely Electronic Absorption and Luminescence Transitions of [La(η5-C5H5)3(NCCH3)2:Nd3+] (In German)
Key words: Lanthanides, Cyclopentadienyl Ligand, Density Functional Theory Calculations, Normal Vibrations, Vibronic Sidebands
Hanns-Dieter Amberger and Hauke Reddmann
1356  Full Text
Preliminary Communication
Photoreduction of CO to Methanol. The Photolysis of Aqueous Solutions of [Os(NH3)5(CO)]2+
Key words: Photochemistry, Osmium Complexes, Metal Carbonyl Complexes, CO Reduction, Artificial Photosynthesis
Horst Kunkely and Arnd Vogler
1371  Full Text