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Z. Naturforsch. 2013,
68b, 557 – 560
doi:10.5560/ZNB.2013-3066
A Dinuclear Palladium(II) Complex of the {N(SPPh2)2}− Ligand – Synthesis and Structure
Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstr. 15, 76131 Karlsruhe, Germany
Reprint requests to Prof. Dr. P. W. Roesky. Fax: +49-721-608-44854. E-mail:
roesky@kit.edu
Received February 22, 2013 / published online Juli 2, 2013
Dedicated to Professor Heinrich Nöth on the occasion of his 85th birthday
The synthesis and characterization including the crystal structure of the dinuclear palladium(II) complex [(κ-S,S′)-{N(SPPh2)2}Pd(μ-{κ2-S′′,S′′′})-{N(SPPh2)2}PdCl2] (1) are reported. Compound 1 was obtained from the reaction of [PdCl2(COD)] (COD = 1,5-cyclooctadiene) and HN(SPPh2)2 in a 1:1 molar ratio in CH2Cl2. The {N(SPPh2)2}− ligands act both as bridging and/or terminally chelating units.
Key words: Bimetallic Complex, Palladium, PNP Ligand, S Donor Ligand