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Zeitschrift für Naturforschung B Contents Vol. 68b (2013)

Z. Naturforsch. 2013, 68b, 1333 – 1339

doi:10.5560/ZNB.2013-3185

Synthesis, Structure and Properties of a 2D Cadmium(II) Coordination Polymer Based on Fluconazole and Isophthalate Ligands

Gang-Hong Pan, Jing-Niu Tang, Xian-Hong Yin, Wei-Man Tian, and Zhong-Jing Huang

College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, P. R. China

Reprint requests to Dr. Zhong-Jing Huang. E-mail: pgh1919@163.com

Received June 17, 2013 / published online November 22, 2013

A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H₂O)]·H₂O}_n (1), (HFlu = fluconazole; H₂IPA = isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV/Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry.

Key words: Triple Hydrogen Bond, Coordination Polymer, Fluconazole, UV/Vis Spectra, Fluorescence, Thermogravimetry

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