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Z. Naturforsch. 2013,
68b, 1214 – 1218
doi:10.5560/ZNB.2013-3124
A Heterometallic MOC Assembled from Cobalt-bisupported Keggin Subunits
Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, P. R. China
Reprint requests to Huiyuan Ma. Tel.: 86-0451-86392716. Fax: 86-0451-86392716. E-mail:
mahy017@163.com, or Haijun Pang. Tel.: 86-0451-88060623. Fax: 86-0451-88060085. E-mail:
panghj116@163.com
Received April 27, 2013 / published online November 4, 2013
A heterometallic metal-organic complex (MOC), K[Co(1,10-phen)2(H2O)]2[BW12O40]·2H2O (phen = 1,10-phenanthroline) (1), has been synthesized hydrothermally and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The complex exhibits cobalt-bisupported tungstoborate units and potassium cations. The luminescence of the title complex has been investigated.
Key words: Polyoxometalate, Tungstoborates, Cobalt
Supporting Material: