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Z. Naturforsch. 2014,
69b, 899 – 905
doi:10.5560/ZNB.2014-4103
Arylation of 1,2,4-Triazines in the Presence of AlCl3
Ural Federal University, Mira St. 19, Ekaterinburg, 620 002, Russia
Reprint requests to Dr. Ilya N. Egorov. E-mail:
i.n.egorov@gmail.com
Received May 15, 2014 / published online August 12, 2014
This paper presents a method for introducing toluene and bromobenzene moieties into 1,2,4-triazines as an alternative to cross-coupling reactions. It is demonstrated that the C=N bond of a wide range of 1,2,4-triazines undergoes addition of arenes in the presence of AlCl3.
Key words: Arylation, 1,2,4-Triazine, Aluminum Chloride