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Z. Naturforsch. 2014,
69b, 183 – 192
doi:10.5560/ZNB.2014-3279
Synthesis and Optical Properties of Li3Ba2La3(MoO4)8:Sm3+ Powders for pcLEDs
1 Department of Chemical Engineering, Münster University of Applied Sciences, Stegerwaldstraße 39, 48565 Steinfurt, Germany
2 Department of Analytical and Environmental Chemistry, Vilnius University, Naugarduko 24, LT-03225 Vilnius, Lithuania
3 Department of Applied Chemistry, Vilnius University, Naugarduko 24, LT-03225 Vilnius, Lithuania
4 Merck KGaA, Frankfurter Straße 250, 64291 Darmstadt, Germany
Reprint requests to Prof. Dr. T. Jüstel. Tel.: +49 2551 962205. Fax: +49 2551 962502. E-mail:
tj@fh-muenster.de
Received October 6, 2013 / published online February 17, 2014
A series of Sm3+-activated molybdates Li3Ba2(La1−xSmx)3(MoO4)8 with 0 ≤ x ≤ 1 (0 % to 100 % Sm3+) have been prepared by the conventional solid-state synthesis method, and their optical properties were investigated. Reflection, excitation and emission spectra were recorded and put in relation to the various [Xe]4f5 → [Xe]4f5 transitions of Sm3+. The positions of the charge transfer bands of Sm3+ and Mo6+ were resolved by Gaussian peak fitting. Emission spectra recorded at 100 K revealed the Stark sublevels
of the Sm3+ energy levels. Time-dependent emission measurements of the 4G5/2 →6H9/2 transition were performed to disentangle the influence of temperature and activator concentration on the decay constants. The results are discussed in the context of the structure of the host material. Sm3+ occupies two different crystallographic sites at higher activator concentrations, which results in a bi-exponential decay curve. Temperature-dependent emission spectra were recorded to determine the thermal quenching behavior of the material. Internal and external quantum efficiencies (IQE and EQE) have been calculated. The IQE is independent of temperature, while the emission intensity strongly decreases at temperatures higher than 400 K. It is concluded that the photon escape efficiency in
Li3Ba2La3(MoO4)8 correlates with temperature. An EQE of 44 % was achieved for the 2 % Sm3+ sample, which is comparatively high for Sm3+. Color points and luminous efficacies were calculated. The color point is independent of the Sm3+ concentration, but a blue-shift was observed with increasing temperature. This shift may be caused by lattice expansion and a subsequent decrease of spin-orbit coupling.
Key words: Time- and Temperature-dependent Luminescence, Molybdates, Sm3+ Luminescence and Quenching, Phosphors for LEDs