A C
 

Contents Vol. 62b (2007)
Authors Index
 

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N u m b e r  1
Original Communications
Synthesis and Crystal Structure of K6Mo10O33
Key words: Potassium, Molybdenum, Oxides, K6Mo10O33, Structure Determination
N. Arumugam, E.-M. Peters, and M. Jansen
1  Full Text
Structure, Magnetic Properties and 151Eu, 119Sn Mössbauer Spectroscopy of Eu5Sn3S12 and Eu4LuSn3S12
Key words: Europium Compounds, Mixed Valence, Magnetism, Mössbauer Spectroscopy
P. Jakubcová, D. Johrendt, C. P. Sebastian, S. Rayaprol, and R. Pöttgen
5  Full Text
Coinage Metal Lanthanide Chalcogenides: II. Copper(I) Lanthanide(III) Sulfides of the Composition CuMS2 (M = Dy - Lu) with the Orthorhombic B-Type Structure (In German)
Key words: Sulfides, Lanthanides, Copper, Crystal Structures
S. Strobel and T. Schleid
15  Full Text
Syntheses and Crystal Structures of the New Ternary Barium Halide Hydrides Ba2H3X (X = Cl or Br)
Key words: Barium, Bromide, Chloride, Hydride, Synthesis, Structure Elucidation
O. Reckeweg, J. C. Molstad, S. Levy, and F. J. DiSalvo
23  Full Text
Crystal Structures and Thermal Behavior of Isostructural Bis(dibenzyldimethylammonium) Tetrachlorometallate [M = Mn(II), Co(II), Ni(II) and Zn(II)] Solvates Crystallized from Acetonitrile and/or Methanol Solutions
Key words: Quaternary Ammonium Compound, Tetrachlorometallate, Tetrahalometallate, X-Ray Single Crystal Diffraction, Thermal Studies
S. Busi, R. Fröhlich, M. Lahtinen, J. Valkonen, and K. Rissanen
28  Full Text
Crystal Structures and Thermal Behavior of Bis(dibenzyldimethylammonium) Tetrabromometallates(II) [M = Mn(II), Co(II) and Zn(II)] and Their Solvates
Key words: Quaternary Ammonium Compound, Tetrabromometallate, Tetrahalometallate, X-Ray Single Crystal Diffraction, Thermal Analysis
S. Busi, R. Fröhlich, M. Lahtinen, R. Sillanpää, and K. Rissanen
35  Full Text
Distortions of [Sb2Cl10]4- Bioctahedra and Phase Transitions in the Chloroantimonate(III) (C3H5NH3)2[SbCl5] · (C3H5NH3)Cl
Key words: Chloroantimonates(III), Phase Transitions, Crystal Structure, Octahedral Distortions, Hydrogen Bonding
B. Zarychta, M. Bujak, and J. Zaleski
44  Full Text
Synthesis, Crystal Structure and Thermal Decomposition Mechanism of a Dysprosium(III) p-Fluorobenzoate 1,10-Phenanthroline Complex
Key words: p-Fluorobenzoic Acid, Crystal Structure, 1,10-Phenanthroline, Dysprosium Complex, Thermal Analysis
S.-L. Xu, J.-J. Zhang, H.-F. Yang, N. Ren, and H.-Y. Zhang
51  Full Text
Alternative Ligands XXXVIII. Further Attempts to Synthesize Pd(0) and Pt(0) Complexes with the Tripod Phosphane Ligand FSi(CH2CH2PMe2)3 (In German)
Key words: Phosphane Ligands, Silicon Acceptor Centres, Chromium(0), Palladium(0), Platinum(0) Complexes, Through-Cage-Bonding
J. Grobe, K. Lütke-Brochtrup, B. Krebs, M. Läge, H.-H. Niemeyer, and E.-U. Würthwein
55  Full Text
2,5-Diformylbenzene-1,4-diol: A Versatile Building Block for the Synthesis of Ditopic Redox-Active Schiff Base Ligands
Key words: Aldehydes, N,O Ligands, p-Interactions, Quinones, Tridentate Ligands
T. Kretz, J. W. Bats, H.-W. Lerner, and M. Wagner
66  Full Text
1,2-Hydroboration of Alkyn-1-yl(chloro)silanes: Alkenes Bearing Chlorosilyl and Dialkylboryl Groups in Geminal Positions
Key words: Alkynes, Alkenes, Boranes, Silanes, Hydroboration, NMR
B. Wrackmeyer, E. Khan, and R. Kempe
75  Full Text
Acylation of Tropane Alkaloids Displaying Reversed Diastereoselectivities under Enzymatic versus Chemical Conditions
Key words: Desymmetrization, 3,4-Dihydroxytropinone Derivatives, Lipases, Monoacetylation, Mosher Esters
O. Affolter, A. Baro, S. Laschat, and P. Fischer
82  Full Text
Ring Transformations of 1,2,4-Dithiazoles: Synthesis and Biological Studies of Novel S-Heterocycles, and Their Relevant Phosphono Derivatives
Key words: Heterocyclic Disulfides, Vinyl and Allylphosphonium Salts, a-Alkylthiomethylphosphonates, 1,3,5-Dithiazines, 1,3-Thiazoles
W. M. Abdou and M. D. Khidre
93  Full Text
Interionic C-H···O Hydrogen Bonds in 1,3-Diisopropyl-4,5-dimethylimidazolium-2-nitrodiethylmalonate (In German)
Key words: Hydrogen Bonds, Crystal Structure, Imidazoles, Heterocycles
N. Kuhn, C. Maichle-Mößmer, M. Steimann, and K. Sweidan
101  Full Text
Convenient Selective Synthesis of Substituted Pyrido[2,3-d]pyrimidones and Annulated Derivatives
Key words: Uracil, Annulation, Biselectrophilic Reagent, Cyclocondensation
W. S. Hamama, M. A. Ismail, H. A. Al-Saman, and H. H. Zoorob
104  Full Text
Studies with 6,7-Dimethoxy-3,4-dihydroisoquinolin-1-yl-acetonitrile: Novel Syntheses of 1-Azolyl- and Pyridoisoquinolines
Key words: (6,7-Dimethoxy-3,4-dihydroisoquinolin-1-yl)-acetonitrile, Enaminonitrile, Malononitrile, 2-Aminobenzimidazole, DMFDMA
H. M. E. Hassaneen, E. M. Awad, H. M. Hassaneen
111  Full Text
Asymmetric Synthesis of (+)-Hinokinin, (+)-Dihydrocubebin and Cubebin Dimethyl Ether, a New Lignan from Phyllanthus niruri
Key words: Lignans, Nucleophilic Acylation, a-Aminonitrile, Michael Addition, Asymmetric Synthesis
D. Enders and M. Milovanovi\'c
117  Full Text
Two New Hydroxy Chalcone Derivatives from Thymus cilicicus
Key words: Thymus cilicicus, Labiatae, 7, 8-Dihydro Chalcone Derivatives
B. Ahmed and T. A. Al-Howiriny
121  Full Text
Jasonone, a Nor-sesquiterepene from Jasonia montana
Key words: Jasonia montana, Asteraceae, Nor-sesquiterpenes
A. E.-H. H. Mohamed
125  Full Text
Calostomal, a Polyene Pigment from the Gasteromycete Calostoma cinnabarinum (Boletales)
Key words: Calostoma, Boletales, Polyenes, Mushroom Pigments, Chemotaxonomy
G. Gruber and W. Steglich
129  Full Text
A New Sesquiterpene Lactone Sulfate from Reichardia gaditana (Asteraceae)
Key words: Reichardia, Chemosystematics, NMR Spectroscopy, Sesquiterpenoids, Structure Elucidation
C. Zidorn, E.-P. Ellmerer, W. Heller, K. Jöhrer, M. Frommberger, R. Greil, M. Guggenberger, K.-H. Ongania, and H. Stuppner
132  Full Text
Anthranoyl-substituted Norditerpene Alkaloids from Aconitum vulparia Rchb. and Their Cytotoxic Activities
Key words: Aconitum vulparia, Norditerpene Alkaloid, Cytotoxicity
D. Csupor, P. Forgo, I. Zupkó, P. Szabó, and J. Hohmann
135  Full Text
N u m b e r  2
Original Communications
La6C2Br9: La Bitetrahedral Clusters with Endohedral C4- Ions (In German)
Key words: Lanthanum Carbide Bromide, La Bitetrahedra, C-La Tetrahedra
H. Mattausch, C. Hoch, and A. Simon
143  Full Text
Dysprosium Carbide Iodides Dy10(C2)2I18, Dy4(C2)I6, and Dy12(C2)3I17 (In German)
Key words: Lanthanum Carbide Bromide, La Bitetrahedra, C-La Tetrahedra
H. Mattausch, C. Hoch, and A. Simon
148  Full Text
New Arsenides with ThCr2Si2-type or Related Structures: The Compounds ARh2As2 (A: Eu, Sr, Ba) and BaZn2As2 (In German)
Key words: Arsenide, Europium, Alkaline Earth Metal, Rhodium, Zinc, Crystal Structures
A. Hellmann, A. Löhken, A. Wurth, and A. Mewis
155  Full Text
New Intermetallic Compounds RE4Co2Mg3 (RE} = Pr, Gd, Tb, Dy) - Syntheses, Structure, and Chemical Bonding
Key words: Magnesium, Intermetallics, Crystal Chemistry, Chemical Bonding
S. Tuncel, U. Ch. Rodewald, S. F. Matar, B. Chevalier, and R. Pöttgen
162  Full Text
Magnetic and Electrical Properties of the Intermetallic Compounds RE2Au2Sn (RE = Y, Dy - Tm, Lu) and RE2Au2In (RE = Ho, Lu)
Key words: Solid State Synthesis, Magnetism, Electrical Resistivity
R. Pöttgen, R. K. Kremer, S. Rayaprol, B. Heying, and R.-D. Hoffmann
169  Full Text
Structural Investigation of ScAuSi and ScAuGe using 45Sc Solid State NMR
Key words: Scandium, Intermetallics, Crystal Chemistry, Solid State NMR
C. P. Sebastian, L. Zhang, H. Eckert, and R. Pöttgen
173  Full Text
Mixed Alkaline Earth Trielides AIIM1xIIIM22-xIII2-x (AII = Ca, Sr, Ba; MIII = Al, Ga, In). A Structural and Theoretical Study
Key words: Trielides, Alkaline Earth, Band Structure Calculation, Structure Map
W. Harms, M. Wendorff, and C. Röhr
177  Full Text
Synthesis, Crystal Structure, and Spectral Characterization of Novel Three-dimensional Supramolecular Networks with One-dimensional Channels Based on Keggin-type Polyoxoanions and Mixed-Valence Dibenzotetrathiafulvalenes
Key words: Radical Cation Salts, Electrochemical Oxidation, Polyoxometalate, DBTTF, Supramolecular
D. Shi, Y. Chen, H. Pang, F. Meng, Y. Sun, K. Liu, and H. Liu
195  Full Text
Unsymmetrical Single-Component Nickel 1,2-Dithiolene Complexes with Extended Tetrachalcogenafulvalenedithiolato Ligands
Key words: Metal 1,2-Dithiolenes, Nonlinear Optics, Organic Semiconductors
G. C. Anyfantis, G. C. Papavassiliou, P. Aloukos, S. Couris, Y. F. Weng, H. Yoshino, and K. Murata
200  Full Text
Synthesis and Unique Function of a Copper(II) Compound Possessing an Imidazole Moiety as an Anchor Group
Key words: Copper(II) Complex with a Histidine Anchor, Aggregation of Amyloid Peptide
S. Nishino, Y. Sutoh, T. Togashi, and Y. Nishida
205  Full Text
Synthesis, Spectroscopic and X-Ray Structure Characterisation of Bis(tetramethylammonium) and Bis(tetra-n-butylammonium) Tetrathiomolybdates
Key words: Crystal Structure, Tetrathiomolybdates, IR and Raman Spectroscopy
M. Poisot, C. Näther, and W. Bensch
209  Full Text
Hydrogen Bonds in the Crystal Structure of Strontium Hydroxide Octahydrate Sr(OH)2 · 8H2O
Key words: Hydrogen Bonds, Coordination Chemistry, Hydrates, Hydroxides, Strontium
H. Reuter, S. Kamaha, and O. Zerzouf
215  Full Text
Spin-Spin Coupling Constants 1J(15N,11B) in Boron-Nitrogen Compounds. Experimental Data and DFT Calculations
Key words: 15N NMR, 11B NMR, Boron-Nitrogen Compounds, Coupling Constants, DFT Calculations
B. Wrackmeyer and O. L. Tok
220  Full Text
Hypercoordinate Diorganosilanes Featuring an <ONO> Tridentate Ligand. A Surprising Equilibrium Between Penta- and Tetracoordination
Key words: Allyl, Chelate, Equilibrium, Hypercoordination, Silicon
J. Wagler and E. Brendler
225  Full Text
The Sum of van der Waals Radii - A Pitfall in the Search for Bonding
Key words: Polarized Covalent Bonds, Supramolecular Aggregates, Weak Attractive Interactions, van der Waals Radii, Limits of Precision
G. P. Schiemenz
235  Full Text
Synthesis of 3,4,5-Trimethoxy-4'-hydroxystilbene Derivatives and Crystal Structure of Ethyl {4-[(E)-2-(3,4,5-trimethoxyphenyl)vinyl]phenoxy}acetate
Key words: 3,4,5-Trimethoxy-4'-hydroxystilbene Derivatives, Crystal Structure, Hydrogen Bond
L. Baolin, G. Jian, Z. Xiquan, L. Yitian, and H. Huaiming
244  Full Text
Oxidation of Cyclic a-Aminoketones (In German)
Key words: Periodate, Hydroxyisoquinolinium Salt, Hg(II)-EDTA, N-Acylcarbinolamine
H. Möhrle and C. Rohn
249  Full Text
Studies With Enamines: Synthesis and Reactivity of 4-Nitrophenyl-1-piperidinostyrene. Synthesis of 4-Nitrophenyl-1-piperidinostyrene. Synthesis of Pyridazine, Oxadiazole, 1,2,3-Triazole and 4-Aminopyrazole Derivatives
Key words: 2-Arylhydrazononitriles, Pyridazinimine, Oxadiazole, 1,2,3-Triazole, 4-Aminopyrazoles
T. A. Abdallah, A. M. Salaheldin, and N. F. Radwan
261  Full Text
Sesquiterpenes and Phenolic Compounds from Achillea clypeolata
Key words: Achillea clypeolata, Sesquiterpenes, Phenolic Compounds
I. Werner, P. Mucaji, A. Presser, and S. Glasl
267  Full Text
New Eudesmane and Cadalane Sesquiterpenes from Parepigynum funingense
Key words: Parepigynum funingense, Eudesmane Sesquiterpene, Cadalane Sesquiterpene
Y. Hua, H.-Y. Liu, J. Zhou, and C.-X. Chen
272  Full Text
Biotransformation of Jatrophone by Aspergillus niger ATCC 16404
Key words: Biotransformation, Jatrophone, Aspergillus niger
M. Pertino, G. Schmeda-Hirschmann, L. S. Santos, J. A. Rodríguez, and C. Theoduloz
275  Full Text
New Cycloartane-type Triterpenoids from Artocarpus nobilis
Key words: Artocarpus nobilis, Acetylcholinesterase, Cycloartane-type Triterpenoids
S. Zahid, A. Ata, and R. Samarasekera
280  Full Text
Unusual Tropane Alkaloid Pattern in Two African Convolvulaceous Species. Phytochemistry and Chemotaxonomy of the Convolvulaceae, Part 20
Key words: Astripomoea malvacea, Falkia repens, Convolvulaceae, 3-Tropanol Esters, Astrimalvine A N-Oxide
S. C. Ott, B. Tofern-Reblin, K. Jenett-Siems, K. Siems, F. Müller, M. Hilker, B. Onegi, L. Witte, and E. Eich
285  Full Text
Sterols from a Vietnamese Wood-Rotting Phellinus sp.
Key words: Phellinus, Sterol, Phellinol, Nitric Oxide
D. N. Quang, D. D. Bach, and Y. Asakawa
289  Full Text
N u m b e r  3
Preface to the Celebration Issue for Professor Helgard G. Raubenheimer
H. Schmidbaur and S. Cronje
293  Full Text
Original Communications
N,N'-Di(alkyloxy)imidazolium Salts: New Patent-free Ionic Liquids and NHC Precatalysts
Key words: Carbene, Imidazolium Salt, Ionic Liquid, NHC, Nickel, Palladium
G. Laus, A. Schwärzler, P. Schuster, G. Bentivoglio, M. Hummel, K. Wurst, V. Kahlenberg, T. Lörting, J. Schütz, P. Peringer, G. Bonn, G Nauer, and H. Schottenberger
295  Full Text
C-H Bond Activation of Methane with Gaseous [(CH3)Pt(L)]+ Complexes (L = Pyridine, Bipyridine, and Phenanthroline)
Key words: C-H Bond Activation, Electrospray Ionization, Mass Spectrometry, Methane, Platinum
B. Butschke, M. Schlangen, H. Schwarz, and D. Schröder
309  Full Text
Boryl-substituted Zirconocene Dichloride Complexes as Catalyst Precursors for Homogeneous Ethylene Polymerization
Key words: Zirconium, Ethylene Polymerization, Donor-Acceptor Catalysts, Bimodal Molecular Weight Distributions
A. Kestel-Jakob and H. G. Alt
314  Full Text
Poly(pyrazol-1-ylmethyl)benzene Palladium Complexes: Synthesis, Characterisation and Evaluation as Heck Coupling Catalysts
Key words: Poly(pyrazol-1-ylmethyl)benzene Ligands, Palladium Complexes, Crystal Structures, Heck Coupling, Catalysts
N. M. Motsoane, I. A. Guzei, and J. Darkwa
323  Full Text
The Synthesis of Copper(II) Salicylaldiminato Complexes and their Catalytic Activity in the Hydroxylation of Phenol
Key words: Salicylaldimine, Tetracoordinated Copper(II) Complexes, Hydroxylation, Phenol
J. L. v. Wyk, S. Mapolie, A. Lennartson, M. Håkansson, and S. Jagner
331  Full Text
Tri(3-pyridyl)phosphine as Amphiphilic Ligand in the Rhodium-catalysed Hydroformylation of 1-Hexene
Key words: Pyridylphosphine, Amphiphilic Ligand, Rhodium, Hydroformylation, X-Ray Structure
W. H. Meyer, R. J. Bowen, and D. G. Billing
339  Full Text
Ethynylthioamide Complexes: Synthesis, Reactivity and an Unusual Coupling Reaction with Diethylaminopropyne
Key words: Thioamide Complexes, Chromium Complexes, Nucleophilic Addition, Coupling Reaction
N. Szesni, M. Drexler, B. Weibert, and H. Fischer
346  Full Text
Molecular Structures and Catalytic Activity of Palladium Complexes Derived from Lutidine-bridged Bis(benzimidazolin-2-ylidene) Ligands
Key words: Heterocyclic Carbene Complexes, Palladium(II) Complexes, Pincer Complexes
M. C. Jahnke, T. Pape, and F. E. Hahn
357  Full Text
The Effect of Catalyst Isomerization on Polypropylene Properties
Key words: Metallocene, Isomerization, Polypropylene, Fractionation, Tacticity
A. J. v. Reenen and O. Sultan
362  Full Text
Theoretical Study of Ethylene Addition to O=W(=CH2)(CH3)2
Key words: Reaction Mechanism, DFT Calculations, Oxo Carbene Complexes, Cycloaddition, Metallacycle
R. Haunschild and G. Frenking
367  Full Text
Angular Momentum in Chemistry
Key words: Bohr Conjecture, Laplace's Equation
J. C. A. Boeyens
373  Full Text
The Affinity of Indium(III) for Nitrogen-donor Ligands in Aqueous Solution. A Study of the Complexing of Indium(III) with Polyamines by Differential Pulse Voltammetry, Density Functional Theory, and Crystallography
Key words: Indium, Formation Constants, Polarography, Nitrogen Donor Ligands
J. M. Harrington, K. A. Oscarson, S. B. Jones, J. H. Reibenspies, L. J. Bartolotti, and R. D. Hancock
386  Full Text
New Synthetic Routes for 1-Benzyl-1,4,7,10-tetraazacyclododecane and 1,4,7,10-Tetraazacyclododecane-1-acetic Acid Ethyl Ester, Important Starting Materials for Metal-coded DOTA-Based Affinity Tags
Key words: Tetraazacyclododecane, Macrocycle, DOTA, Affinity Tag, Rare Earth Complexes
S. W. Kohl, K. Kuse, M. Hummert, H. Schumann, C. Mügge, K. Janek, and Hardy Weißhoff
397  Full Text
Group 11 Complexes with the Bidentate (SePPh2)2CH2 and Tridentate [(SePPh2)2CH]- Ligands
Key words: Group 11 Metals, Selenium Ligands, Methanide Ligands
S. Canales, O. Crespo, M. C. Gimeno, P. G. Jones, and A. Laguna
407  Full Text
On the Reaction of C(PPh3)2 with [Co2(CO)8]: Formation and Structure of an Unusual Tetranuclear Cluster
Key words: Tetranuclear Cobalt Cluster, Carbodiphosphorane, Phosphacumulene Ligand, Proton Abstraction, Crystal Structure
W. Petz, K. Wenck, and B. Neumüller
413  Full Text
Di-tungsten Bis-carbene Complexes Linked by Condensed Heteroaromatic Spacers
Key words: Dinuclear Carbene Complexes, Condensed Heterocycles, Thiophene, Pyrrole, Tungsten
S. Lotz, M. Landman, H. Görls, C. Crausea, H. Nienaber, and A. Olivier
419  Full Text
Synthesis and Characterization of New Diiron and Diruthenium m-Aminocarbyne Complexes Containing Terminal S-, P- and C-Ligands
Key words: Diiron Complexes, Carbyne, Alkynyl, Nitrile Ligands, Crystal Structures
V. G. Albano, L. Busetto, F. Marchetti, M. Monari, S. Zacchini, and V. Zanotti
427  Full Text
A Novel Calix[4]arene-Dipyrrole Conjugate Designed for Complexation of Ion Pairs
Key words: Calixarenes, Receptors, Ion Pairs
J. Budka, P. Curinova, R. Gu, P. Lhotak, I. Stibor, J. Schraml, and W. Dehaen
439  Full Text
Synthesis and Luminescence Properties of [Pt{4-(o-MeC6H4)pzbipy}Cl]SbF6 [pzbipy = 6-(2''-pyrazinyl)-2,2'-bipyridine]
Key words: Pyrazinylbipyridyl Ligand, Platinum Complex, Luminescence
J. S. Field, J.-A. Gertenbach, R. J. Haines, O. Q. Munro and D. R. McMillin
447  Full Text
Solvent-free Substitution Reactions of Solid Phosphines with(h5-RC5H4)Fe(CO)2I (R = H, Me) Complexes
Key words: Melt Phase, Solvent-free Reaction, Iron Cyclopentadienyl Complex, Metal Dimer Catalyst, Green Chemistry
A. Munyaneza, M. D. Bala, and N. J. Coville
453  Full Text
Introduction of Phosphine-Gold(I) Precursors into a Cys-modified Enkephalin Neuropeptide as Part of Solid Phase Peptide Synthesis
Key words: Enkephalin, Gold Compounds, Medicinal Inorganic Chemistry, Peptides
J. Caddy, U. Hoffmanns, and N. Metzler-Nolte
460  Full Text
The First Bridged, Bifunctional Cyclopentadienyl-Imidazolylidene Ligand and Complexes with Titanium and Zirconium (In German)
Key words: Titanium, Zirconium, Bridged Cyclopentadienyl N-Heterocyclic Carbene Ligands, Crystal Structures, Agostic Interaction
J. Müller, I. Piotrowski, and L. v. Chrzanowski
467  Full Text
Derivatives of b-Hydroxydithiocinnamic Acids as Ligands. Syntheses and Characterisation of Novel 1,1-Ethenedithiolato and O,S-Chelate Complexes (In German)
Key words: 1,1-Ethenedithiolates, Dithiocinnamic Acid Esters, Transition Metals, S Ligands
K. Schubert, H. Görls, and W. Weigand
475  Full Text
The Separation of Fe from Ga to Produce Ultrapure 67Ga
Key words: 67Ga, Fe, Purification, Ion Exchange
N. P. v. d. Meulen and T. N. v. d. Walt
483  Full Text
Note
Bis-Imide Derivatives of the Heterometallic Alkoxide Li4Ti4O4(OiPr)12
Key words: Titanium Alkoxide Derivatives, Lithium Alkoxide Derivatives, Imide Ligands
H. Fric and U. Schubert
487  Full Text
N u m b e r  4
Original Communications
One-dimensional Hydrogen-bonded Chloride-Hydrate Assembly {[(H2O)4Cl2]2-}oo
Key words: Supramolecular Chemistry, Hydrogen Bond, Chloride-Hydrate, Self-Assembly, Iron(II) Complex
J.-X. Dai, F.-H. Wu, W.-R. Yao, and Q.-F. Zhang
491  Full Text
Synthesis, Characterisation and Crystal Structure of a Copper(II) Dichromate Complex with the N,N'-Bis(2-pyridylmethylene)butane-1,4-diamine Schiff Base Ligand
Key words: Copper(II), Dichromate, Schiff Base, Synthesis, X-Ray Structure
B. Samanta, J. Chakraborty, S. Shit, S. R. Batten, P. Jensen, and S. Mitra
495  Full Text
Synthesis, Crystal Structure and Properties of CuBr(2,3-dimethylpyrazine) Coordination Polymers
Key words: Coordination Polymers, CuBr(2,3-dimethylpyrazine), Crystal Structures, Thermal Properties, Luminescence Properties
I. Jeß, P. Taborsky, and C. Näther
501  Full Text
Preparation and Characterization of Mononuclear Ni Complexes of Tetradentate Amine-thioether and Amine-thiolate Ligands
Key words: Nickel Complexes, Macrocyclic Ligands, N Donor, S Donor
T. Fritz, G. Steinfeld, and B. Kersting
508  Full Text
Carbamoyl Derivatives of a Pyridine-Based Tetraamine
Key words: Tetrapodal Pentadentate Ligand, Urea, Chelates, Hydrogen Bonding
A. K. Bilakhiya, F. W. Heinemann, and A. Grohmann
519  Full Text
Nitroimidazoles, Part 3. Synthesis and anti-HIV Activity of New N-Alkyl-4-nitroimidazoles Bearing Benzothiazole and Benzoxazole Backbones
Key words: anti-HIV Activity, Benzothiazoles, Benzoxazoles, 4-Nitroimidazoles, NNRTIs
Y. A. Al-Soud, H. Al-Sa'doni, H. A. S. Amajaour, and N. A. Al-Masoudi
523  Full Text
Studies with 2-(Arylhydrazono)aldehydes: Synthesis and Chemical Reactivity of Mesoxalaldehyde 2-Arylhydrazones and of Ethyl 2-Arylhydrazono-3-oxopropionates
Key words: 2-Arylhydrazonopropane-1,3-dial, 2-Aryl-1,2,3-triazole-4-carbonitrile, Formazanes
S. Makhseed, H. M. E. Hassaneen, and M. H. Elnagdi
529  Full Text
Chemoselective One-pot Conversion of Primary Alcohols to their Bis(indolyl)methanes Promoted by Bi(NO3)3·5H2O
Key words: Bis(indolyl)methane, Primary Alcohol, Bi(NO3)3·5H2O, Solvent-free Reaction
A. R. Khosropour, I. Mohammadpoor-Baltork, M. M. Khodaei, and P. Ghanbary
537  Full Text
Mannich Bases as Synthetic Intermediates: Synthesis of 3- and 4-Functionalized 2-Pyrazolines
Key words: Styryl Ketonic Mannich Bases, 3- and 4-Functionalized 2-Pyrazolines
E. M. Afsah, E. M. Kandeel, M. M. Khalifa, and W. M. Hammouda
540  Full Text
Studies of Dihydropyridines by X-Ray Diffraction and Solid State 13C NMR
Key words: 13C CP-MAS NMR, 1,4-Dihydropyridines, Chiral Rotamers, Crystal Structures
M. S. Morales-Ríos, A. Martínez-Richa, Z. Hernández-Gallegos, A. Hernández-Barragán, R. Vera-Graziano, and P. Joseph-Nathan
549  Full Text
Efficient Asymmetric Synthesis of Prostaglandin E1
Key words: Prostaglandin, Asymmetric Michael Addition, Cuprates, Deprotection
J.-C. Jung and O.-S. Park
556  Full Text
TMC-151 A Monoacetate, a New Polyketide from Bionectria ochroleuca
Key words: Hypocreales, Bionectria ochroleuca, Polyketides, Fermentation Broth, Cytotoxicity
Y.-M. Ju, S.-H. Juang, K.-J. Chen, and T.-H. Lee
561  Full Text
Laurentixanthone C: A New Antifungal and Algicidal Xanthone from Stem Bark of Vismia laurentii
Key words: Vismia laurentii, Xanthone, Anthraquinone, Biological Activity
M. F. Tala, K. Krohn, H. Hussainb, S. F. Kouam, H. K. Wabo, P. Tane, B. Schulz, and Q. Hu
565  Full Text
Xylogranatin E, a New Phragmalin with a Rare Oxygen Bridge between C1 and C29, from the Fruit of a Chinese Mangrove Xylocarpus granatum
Key words: Phragmalin, Xylocarpus granatum, Complete Assignment of 1H and 13C NMR Data
J. Wu, H. Ding, M. Li, and S. Zhang
569  Full Text
A New Antifeedant Withanolide from Jaborosa lanigera
Key words: Jaborosa, Withanolides, Jaborosalactol
M. C. Tettamanzi, F. N. Biurrun, and A. M. Cirigliano
573  Full Text
A Novel Norditerpene from Eupatorium adenophorum
Key words: 4aR,7R,8S,8aR)-1,2,4a,5,6,7,8,8a-Octahydro-8-[3-methylenebut-4-alyl]-4,4a,7,8-tetramethylnaphthalen-2(1H)-one, Eupatorium adenophorum, Biodegradation, Clerodane
M.-Z. Wang, X.-H. Cai, G.-S. Du, and X.-D. Luo
577  Full Text
Glutathione S-Transferase, Acetylcholinesterase Inhibitory and Antibacterial Activities of Chemical Constituents of Barleria prionitis
Key words: Barleria prionitis, Balarenone, Pipataline, Lupeol, 13,14-seco-Stigmasta-5,14-diene-3-a-ol, Glutathione S-Transferases, Acetylcholinesterase
K. S. Kosmulalage, S. Zahid, C. C. Udenigwe, S. Akhtar, A. Ata, and R. Samarasekera
580  Full Text
Two New Leucosesterterpenes from Leucosceptrum canum
Key words: Leucosceptrum canum, Sesterterpenes, Leucosesterterpenes, 14b-Methylleucosesterterpenone, 17a-Hydroxyleucosceptrine
M. I. Choudhary, R. Ranjit, Atta-ur-Rahman, K. P. Devkota, and T. M. Shrestha
587  Full Text
Microbial Hydroxylation of Hydroxyprogesterones and a-Glucosidase Inhibition Activity of Their Metabolites
Key words: 11a-Hydroxyprogesterone, 17a-Hydroxyprogesterone, Microbial Transformation, Cunninghamella elegans, Candida albicans, Fusarium lini, Gibberella fujikuroi, a-Glucosidase Inhibition
M. I. Choudhary, M. Nasir, S. N. Khan, M. Atif, R. A. Ali, S. M. Khalil, and Atta-ur-Rahman
593  Full Text
MS-guided Fractionation as a Fast Way to the Identification of New Natural Products - MALDI-TOF-MS Screening of the Marine Sponge Stylissa caribica
Key words: Natural Products, Marine Sponge, Mass Spectrometry
A. Grube, T. Maier, M. Kostrzewa, and M. Köck
600  Full Text
Synthesis and X-Ray Crystal Structure of Two Novel Ester Ferrocenophanes
Key words: Ester Ferrocenophanes, Synthesis, X-Ray Crystal Structure, Hydrogen Bonds
L. Tao, Y. Bingqin, and G. Bo
605  Full Text
Notes
Solid State Syntheses and Structure of LaPdCd2 and PrNi0.951(4)Cd2
Key words: Cadmium, Intermetallics, Crystal Chemistry
A. Dogan, U. Ch. Rodewald, and R. Pöttgen
610  Full Text
Structure Refinement of CePtSi and Hydrogenation Behavior of CePdGe, CePtSi and CePtGe
Key words: Cerium Intermetallics, Hydrogenation
W. Hermes, U. Ch. Rodewald, B. Chevalier, and R. Pöttgen
613  Full Text
Preparation of a Copper(I) Halide Coordination Polymer by Thermal Decomposition of a Precursor with Predefined Stoichiometry
Key words: Copper(I) Halide Coordination Polymers, Crystal Structures, Thermal Decomposition
I. Jeß and C. Näther
617  Full Text
Crystal Structures of New Schiff Bases N,N'-Bis(2-hydroxy-3-methoxybenzylidene)-1,4-diaminobutane and N,N'-Bis(2-hydroxy-4-methoxybenzylidene)-1,2-diaminoethane
Key words: Schiff Base, X-Ray Structure
M. H. Habibi, M. K. Sardashti, K. Barati, R. W. Harrington, and W. Clegg
621  Full Text
N u m b e r  5
Original Communications
Crystal Structure and Properties of Chromium(II)-Tetrachloroaluminate (In German)
Key words: Chromium, Tetrachloroaluminate, Crystal Structure, Jahn-Teller Distortion, Group-Subgroup Relations
R. Müller, G. V. Vajenine, and U. Keßler
625  Full Text
RE2+xI2{M}2+y (RE = Ce, Gd, Y; M = Al, Ga): Reduced Rare Earth Halides with a Hexagonal Metal Atom Network
Key words: Cerium, Gadolinium, Yttrium, Aluminum, Gallium, Reduced Halide
M. Lukachuk, C. Zheng, H. Mattausch, M. G. Banks, R. K. Kremer, and A. Simon
633  Full Text
Rare Earth-rich Magnesium Compounds RE4RhMg (1{RE} = Y, La - Nd, Sm, Gd - Tm, Lu)
Key words: Magnesium, Intermetallics, Crystal Chemistry
S. Tuncel, U. Ch. Rodewald, B. Chevalier, and R. Pöttgen
642  Full Text
Structure and Properties of a- and b-CeCuSn: A Single Crystal and Mössbauer Spectroscopic Investigation
Key words: Stannides, Crystal Structure, Magnetism
C. P. Sebastian, S. Rayaprol, R.-D. Hoffmann, U. Ch. Rodewald, T. Pape, and R. Pöttgen
647  Full Text
Synthesis, Crystal Structure and Optical Spectra of Yb2[CN2]3
Key words: Trivalent Ytterbium, Carbodiimide, Cyanamide, Crystal Structure, Optical Spectroscopy
O. Reckeweg, T. Schleid, and F. J. DiSalvo
658  Full Text
Effect of High-energy Milling on the Solid State Formation of Zinc Manganites (ZnxMn3-xO4, 0.5 <= x <= 1.5) from the System ZnC2O4 · 2H2O-n MnCO3 (n = 1, 1.5 and 2)
Key words: Zink Manganites, ZnMn2O4, Mechanical Milling, Simultaneous TG/DSC
V. Berbenni, C. Milanese, G. Bruni, and A. Marini
663  Full Text
The Coordination Behavior of the Acetylenedisulfide Bis(benzylthio)acetylene with Zero-valent Metal Complexes of W, Co and Pt (In German)
Key words: Dithioalkynes, Alkyne Complexes, Organometallic Compounds, Crystal Structure
W. W. Seidel, M. J. Meel, and T. Lügger
669  Full Text
Syntheses and Structures of Two Arene-Ruthenium(II) Complexes with Cyclometalating 2-Pyridyl-m-tolyl Ligands
Key words: Arene-Ruthenium, Ruthenacycle, Cyclometalated Ligands, Organometallic Compounds
X.-Z. Zhang, W.-R. Yao, Q.-F. Zhang, and W.-H. Leung
675  Full Text
Some New Nickel 1,2-Dichalcogenolene Complexes as Single-component Semiconductors
Key words: Metal 1,2-Dichalcogenolenes, Single-component Semiconductors
G. C. Papavassiliou, G. C. Anyfantis, B. R. Steele, A. Terzis, C. P. Raptopoulou, G. Tatakis, G. Chaidogiannos, N. Glezos, Y. Weng, H. Yoshino, and K. Murata
679  Full Text
A Spectroscopic and Kinetic Investigation on the Substitution of Fe(III) for Ni(II) in a Siderophore Model
Key words: Siderophore, Raman Resonance, Dopamine, Catecholamine, Iron
W. J. Barreto, W. P. Silva, I. S. Scarmínio, S. R. G. Barreto, and L. F. S. Silva
685  Full Text
A Novel Hydrogen-bonded Zigzag Chain Manganese(III) Complex: Synthesis, Crystal Structure and Magnetic Properties
Key words: Crystal Structures, Manganese(III) Complex, Schiff Base Ligand, Hydrogen Bond, Supramolecular Chemistry
H. Kara
691  Full Text
Charge Density of L-Alanyl-glycyl-L-alanine Based on X-Ray Data Collection Periods from 4 to 130 Hours
Key words: Tripeptides, Charge Density, Topological Analysis, Synchrotron Radiation
D. Förster, A. Wagner, C. B. Hübschle, C. Paulmann, and P. Luger
696  Full Text
Synthesis and Single Crystal X-Ray Structure of Ethyl 2-(1,3-Benzoxazol-2-yl)-5-oxo-3-(4-toluidino)-2,5-dihydro-4-isoxazolecarboxylate
Key words: Synthesis, Hydroxylamine, 2-Chlorobenzoxazole, N-Substituted Isoxazolone, X-Ray Single Crystal Structure
A. Souldozi, J. Khalafy, A. P. Marjani, K. \'Slepokura, T. Lis, and A. Ramazani
705  Full Text
Syntheses and Structures of 9-Bromo-10-diphenylphosphanylanthracene and its Oxidation Products
Key words: Anthracene, Asymmetrical Synthesis, Phosphane, Phosphorylation, Selenium
G. Schwab, D. Stern, D. Leusser, and D. Stalke
711  Full Text
Synthesis and Spectral Characterization of Hydrazone Schiff Bases Derived from 2,4-Dinitrophenylhydrazine. Crystal Structure of Salicylaldehyde-2,4-Dinitrophenylhydrazone
Key words: Hydrazone, Schiff Base, 2,4-Dintrophenylhydrazine, Salicylaldehyde, X-Ray Structure
H. H. Monfared, O. Pouralimardan, and C. Janiak
717  Full Text
A Convenient Procedure for the Preparation of Sulfonamidoureas Using Triphosgene
Key words: Sulfonamidourea, Triphosgene, Sulfonylhydrazides
J. Safaei-Ghomi, A. Bamoniri, and A. Abbaszadeh-Nooshabady
721  Full Text
Secondary Interactions in Bromomethyl-substituted Benzenes: Crystal Structures of Three a,a'-Bis-bromoxylenes, 1,2,3,5-Tetrakis(bromomethyl)benzene, and 1,2,4,5-Tetrakis(bromomethyl)benzene
Key words: a,a'-Bis-bromoxylenes, X-Ray, "Weak" Hydrogen Bonds, Halogen-Halogen Contacts
P. G. Jones and P. Ku\'s
725  Full Text
One-pot Green Synthesis for Pyrimido[4,5-d]pyrimidine Derivatives
Key words: Barbituric Acid, Pyrimido[4,5-d]pyrimidines, Water, Multicomponent Reaction
M. Kidwai, K. Singhal, and S. Kukreja
732  Full Text
Synthesis, Structure and Acid-Base Behaviour of Some 4-Hydroxycoumarin Derivatives
Key words: 4-Hydroxycoumarin, X-Ray Diffraction Analysis, Acid-Base Titration, Spectrophotometry, Indicators
S. Stanchev, C. Maichle-Mössmer, and I. Manolov
737  Full Text
Xylodiol, a New Atisane Diterpenoid from Xylopia Langsdorffiana St.-Hil. & Tul. (Annonaceae)
Key words: Xylopia langsdorffiana, Annonaceae, Atisane, Labdane, Cytotoxicity
J. F. Tavares, M. V. B. Silva, K. F. Queiroga, M. F. F. M. Diniz, J. M. B. Filho, M. Haun, P. S. Melo, and M. S. d. Silva
742  Full Text
Triterpenoid Saponins from Metadina trichotoma
Key words: Metadina trichotoma, Triterpenoid Saponins, Metatrichoside A, Metatrichoside B
Y.-M. Zhang, N.-H. Tan, H.-Q. Huang, and G.-Z. Zeng
745  Full Text
Two New Iridoid Glycosides from Lagotis yunnanensis
Key words: Logatis yunnanensis, Iridoid Glycosides, Lagotisoside D, Lagotisoside E
X.-D. Yang, L.-J. Yang, S. Yang, J.-F. Zhao, H.-B. Zhang, and L. Li
749  Full Text
N u m b e r  6
Original Communications
BaFe3.39(5)Ru2.61(5)O11 and BaCo1.85(6)Ru4.15(6)O11. Preparation, Crystal Structures, and Magnetic and Transport Properties of Quaternary Transition Metal Oxoruthenates
Key words: Oxoruthenates, Ferrates, Cobaltates, Magnetism, Crystal Structure
B. Schüpp-Niewa, L. Shlyk, S. Kryukov, L. E. De Long, and R. Niewa
753  Full Text
High-pressure Synthesis, Crystal Structure, and Properties of d-Ce(BO2)3
Key words: High-pressure Phase, Borate, Crystal Structure, Multianvil
A. Haberer, G. Heymann, and H. Huppertz
759  Full Text
High-pressure Syntheses, Crystal Structures, and Thermal Behaviour of b-RE(BO2)3 (RE = Nd, Sm, Gd)
Key words: High-pressure Phases, Borates, Crystal Structure
H. Emme, G. Heymann, A. Haberer, and H. Huppertz
765  Full Text
Synthesis Methods for Ce(CrO4)2 · xH2O and Crystal Structures of K2CrSO7, (NH4)2Cr2O7 and Na2Cr2O7 · 2H2O
Key words: Hydrated Cerium Chromates, Chromatosulfate, Dichromates, Oxidizing Agents, Single Crystal X-Ray Diffraction
B. M. Casari, A. K. Eriksson, and V. Langer
771  Full Text
Syntheses and Structural Characterizations of Heterometallic Copper(I)/Indium(III) Complexes Containing Phosphine Ligands
Key words: Synthesis, Crystal Structure, Copper(I) Complex, Indium(III) Complex, Heterometallic Complex
X.-Z. Zhang, Y.-W. Song, F.-H. Wu, and Q.-F. Zhang
778  Full Text
A Salt Metathesis Route to Ruthenium Carbene Complex Isomers with Pyridine Dicarboxamide-derived Chelate Pincer Ligands
Key words: Chelate Ligand, Salt Metathesis, Ruthenium Carbene Complexes, Isomeric Coordination Compounds
C. Wallenhorst, K. V. Axenov, G. Kehr, J. S. M. Samec, R. Fröhlich, and G. Erker
783  Full Text
Substitution Reactions of Nb(III) and Mo(II) Bis(benzylthio)acetylene Complexes (In German)
Key words: Dithioalkynes, Alkyne Complexes, Substitution Reactions, Crystal Structure
W. W. Seidel, M. Schaffrath, M. J. Meel, T. Hamilton, S. C. Ariza, and T. Pape
791  Full Text
Self-assembly of 1D- and 3D-Networks Through Non-coordination Intermolecular Forces: Synthesis and Crystal Structures of Copper(I) Complexes Based on Pyridazine-type Ligands
Key words: Copper(I), Pyridazine, Phthalazine, Benzo[c]cinnoline, Self-assembly
L. Plasseraud, A. Scheurer, and F. Hampel
799  Full Text
Syntheses, Spectroscopy and Crystal Structures of (R)-N-(1-Aryl-ethyl)salicylaldimines and [Rh{(R)-N-(1-aryl-ethyl)salicylaldiminato}(h4-cod)] Complexes
Key words: (R)-Schiff Bases, Rh(h4-cod) Complexes, Chelate Complexes, p Interactions, Optical Activity, Chirality
M. Enamullah, A. K. M. R. Uddin, A.-C. Chamayou, and C. Janiak
807  Full Text
Synthesis and Spectral, Thermal and Structural Characterization of a Vitamin B13 Complex of Nickel(II) with 2-Aminothiazole, mer-[Ni(HOr)(H2O)2(ata)2]
Key words: Orotato Complex, Vitamin B13 Complex, 2-Aminothiazole
O. Z. Ye\csilel, K. Akda\ug, H. Pa\csao\uglu, and O. Büyükgüngör
818  Full Text
Syntheses, Spectral, Thermal and Structural Characterization of 2-Hydroxyanilinium and 2-Amino-3-hydroxy-pyridinium Squarates
Key words: Squaric Acid, Squarate Salts, Thermal Analyses
O. Z. Ye\csilel, H. Pa\csao\uglu, O. O. Y\ilan, and O. Büyükgüngör
823  Full Text
Regio- and Stereoselective Addition of Imides to Ethyl 3-Phenyl-2-propynoate in the Presence of Triphenylphosphine. Single Crystal X-Ray Structure of Ethyl (Z)-2-(1,3-Dioxo-1,3,3a,4,7,7a-hexahydro-2H-isoindol-2-yl)-3-phenyl-2-propenoate
Key words: Phosphorus Ylide, Ethyl 3-Phenyl-2-propynoate, Vinyltriphenylphosphonium Salts, Crystal Structure, N-Vinyl Imide
A. T. Mahyari, N. Shajari, A. R. Kazemizadeh, K. \'Slepokura, T. Lis, and A. Ramazani
829  Full Text
Synthesis and Single Crystal X-Ray Structure of 2-(1,3,4-Oxadiazol-2-yl)aniline
Key words: 2-Aminobenzoic Acid, (N-Isocyanimino)triphenylphosphorane, 2-(1,3,4-Oxadiazol-2-yl)aniline, Aza-Wittig Reaction, Crystal Structure Determination
A. Souldozi, K. \'Slepokura, T. Lis, and A. Ramazani
835  Full Text
Neighbouring Group Effect of Oxime Functions in the Dehydrogenation of 2-Phenylpiperidine Derivatives
Key words: Hg(II)-induced Dehydrogenation, Oxime Participation, Nitrone, Oxadiazine, Iminium Oximate
H. Möhrle and M. Gehlen
841  Full Text
Chemical Constituents from the Roots and Rhizomes of Clematis hexapetala Pall.
Key words: Clematis hexapetala, Chemical Constituents, Structure Elucidation}
C.-x. Dong, S.-p. Shi, K.-s. Wu, and P.-f. Tu
854  Full Text
Two New Limonoids with a 3-3-O-b-Tigloyl Group from the Seeds of the Chinese Mangrove Xylocarpus granatum
Key words: Mexicanolide, Phragmalin, 3-O-b-Tigloyl Group, Xylocarpus granatum, Complete NMR Assignments
J. Wu, M. Li, S. Zhang, Q. Xiao, and Q. Li
859  Full Text
Atriplisides A and B, Two New Glycosides from Perovskia atriplicifolia
Key words: Perovskia atriplicifolia, Atripliside A, Atripliside B, Triterpenoidal and Flavonone Glycosides
S. Perveen, A. Malik, R. B. Tareen, N. Afza, and L. Iqbal
863  Full Text
Notes
Synthesis and Structural Characterization of 1-Butyl-2,3-dimethylimidazolium Bromide and Iodide
Key words: 1-Butyl-2,3-dimethylimidazolium Bromide, 1-Butyl-2,3-dimethylimidazolium Iodide, X-Ray Crystal Structure
J. Kutuniva, R. Oilunkaniemi, R. S. Laitinen, J. Asikkala, J. Kärkkäinen, and M. K. Lajunen
868  Full Text
Trimethyl(4-iodophenyl)ammonium Iodide, a Hypervalent Compound of Iodine (In German)
Key words: Iodine, Hypervalent Compounds, Crystal Structure
N. Kuhn, Q. Abu-Salem, T. Gädt, S. Reit, and M. Steimann
871  Full Text
N u m b e r  7
Original Communications
Crystal Structures of New Pyrovanadates A2MnV2O7 (A = Rb, K)
Key words: Vanadate, Melilite, Crystal Chemistry, Single Crystal X-Ray Diffraction, Oxides
H. B. Yahia, E. Gaudin, and J. Darriet
873  Full Text
"Covalent Magnetism" and Invar-like Behavior within Ternary Nitrides: An ab initio Study
Key words: Ternary Iron Nitrides, Magnetic Properties, Magnetovolume Effects, Invar-like Behavior, Covalent Magnetism
S. F. Matar, A. Houari, M. A. Belkhir, and M. Zakhour
881  Full Text
Heavy Fermion Behaviour in Ce2Ni1.88Cd
Key words: Ce2Ni1.88Cd, Heavy Fermion, Kadowaki-Woods Relation
E. V. Sampathkumaran, K. K. Iyer, N. Mohapatra, S. Rayaprol, and R. Pöttgen
891  Full Text
Single Crystal Investigation and Physical Properties of the Binary Compound CeB4
Key words: Cerium Boride, Crystal Structure, Magnetic Behaviour, Electrical Resistivity
V. Babizhetskyy, A. Simon, and K. Hiebl
896  Full Text
Magnetic Properties and Specific Heat Studies of the Plumbides CeTPb (T} = Cu, Pd, Ag, Au)
Key words: Cerium Intermetallics, Plumbides, Magnetism
W. Hermes, S. Rayaprol, and R. Pöttgen
901  Full Text
Magnesium Hydride: From the Laboratory to the Tank
Key words: Magnesium Hydride, Milling under Hydrogen, Hydrogen Storage, Diffusion and Nucleation Process, Hydrogen Tank
J.-G. Roquefere and J.-L. Bobet
907  Full Text
Hydriding Properties of MgH2-Mg2Ni0.8Co0.2 Composites Obtained by Ball Milling
Key words: Hydrogen Storage, Magnesium Composites, Ball Milling, Intermetallic Additives
T. Mandzhukova, J.-L. Bobet, M. Khrussanova, and P. Peshev
915  Full Text
Superstructures in Room-temperature Ordered Deuterides CeCuSiDx and CeCuGeDx
Key words: Superstructure, Ordered Hydride, Intermetallics, Cerium, Neutron Diffraction
M. Pasturel, F. Weill, and J.-L. Bobet
922  Full Text
Refinement of the Crystal Structures of Palladium-rich In-Pd Compounds by X-Ray and Neutron Powder Diffraction
Key words: Intermetallic Compounds, Palladium, Neutron Diffraction, Powder Diffraction, Disorder
H. Kohlmann and C. Ritter
929  Full Text
Chemical Bonding and Physical Properties of Yb5Bi3
Key words: Ytterbium, Bismuth, Intermetallic Compound, Chemical Bonding, Magnetism, Electrical Resistivity, X-Ray Absorption Spectroscopy
Y. Liang, R. Cardoso-Gil, W. Schnelle, M. Schmidt, J. T. Zhao, and Y. Grin
935  Full Text
Magnetic Properties of Polycrystalline PrCu2: A Quadrupolar Transition Material
Key words: Quadrupolar Effects, PrCu2, Magnetic Properties, Electrical Resistivity, Crystal Field
J. R. Fernández
941  Full Text
Chemical Bonding in Metallic Rutile-type Oxides TO2 (T = Ru, Rh, Pd, Pt)
Key words: Oxides, RuO2, RhO2, PdO2, PtO2, Rutile-type, DFT
G. Demazeau, S. F. Matar, and R. Pöttgen
949  Full Text
Ag10Te4Br3-xClx and Ag10Te4Br3-yIy: Structural and Electrical Property Tuning of a Mixed Conductor by Partial Anion Substitution
Key words: Silver Ion Conductors, Coinage Metal Polytelluride Halides, Chemical Property Tuning
T. Nilges
955  Full Text
Magnetocaloric and Thermal Properties of Ho(Co1-xSix)\Dw{2 Compounds
Key words: HoCo2, Magnetic Phase Transition, Specific Heat, Magnetocaloric Effect, Thermal Conductivity
V. Sechovsk\'y, D. Vasylyev, and J. Prokleška
965  Full Text
Solid State and Electronic Structure of Rare Earth Metal Intercalated Graphite from First-principles Theory
Key words: Intercalated Graphite, Density Functional Calculations, Electronic Structure, Rare Earth Metals, GIC's
C.-M. Fang, J. Bauer, J.-Y. Saillard, and J.-F. Halet
971  Full Text
Low-temperature Properties of U2Co2InH1.9
Key words: Uranium, Hydrides, Magnetism
L. Havela, Kh. Miliyanchuk, L. C. J. Pereira, and E. Šantavá
977  Full Text
N u m b e r  8
Original Communications
Crystal Structure of the Trihydrate of the Neuraminidase Inhibitor C15H28N4O4 (Peramivir), a Potential Influenza A/B and Avian-influenza (H5N1) Drug
Key words: Crystal Structure, Peramivir, Neuraminidase Inhibitor
E. Keller and V. Krämer
983  Full Text
Synthesis and Solid-state Structure of a Star-shaped Oligobenzoate
Key words: Star-shaped Molecules, Single Crystal, Supramolecular Chemistry, Mesogens, Liquid Crystals, Nano-segregation
M. Lehmann, M. Jahr, T. Rüffer, and H. Lang
988  Full Text
Orthoamides, LXIV. Formylation of Aromatic Compounds by Tris(dichloromethyl)amine and Oligoformylamine Derivatives in the Presence of Superacids
Key words: Formylation, Aromatic Aldehydes, Tris(dichloromethyl)amine, Triformamide, Formyl-aalen, Superacids, Zeolites (In German)
W. Kantlehner, S. Leonhardt, G. Ziegler, O. Scherr, R. Kreß, A. Goeppert, and J. Sommer
995  Full Text
Orthoamides, LXV. Condensation Reactions of Amidines, Guanidines, Hydrazine and Hydrazine Derivatives with Orthoamides of Alkyne Carboxylic Acids (In German)
Key words: Orthoamides of Alkynecarboxylic Acids, Ketene Aminals, 2,3-Dihydro-pyrazolethiones, Crystal Structure Analysis
W. Kantlehner, J. Mezger, R. Stieglitz, K. Edelmann, H. Lehmann, M. Vettel, R. Kreß, W. Frey, and S. Ladendorf
1015  Full Text
Catalytic Ring Opening of a-Epoxyketones Using DDQ in Methanol Solution at Room Temperature and under Reflux Conditions in Excellent Yields
Key words: Ring Opening, a-Epoxyketones, 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone
H. R. Memarian, A. Saffar-Teluri, and M. Khosravi-Babadi
1030  Full Text
Four Additional Meroterpenes Produced by Penicillium sp Found in Association with Melia azedarach. Possible Biosynthetic Intermediates to Austin
Key words: Melia azedarach, Penicillium, Endophytic Fungi, Meroterpenes, Meroterpenoids
T. P. Fill, G. K. Pereira, R. M. G. d. Santos, and E. Rodrigues-Fo
1035  Full Text
Synthesis of Some Ethyl 3-(Aryldiazenyl)-7-oxo-dihydropyrido[2,3-f]quinoxaline-8-carboxylates
Key words: 7,8-Diamino-4-oxoquinoline-3-carboxylate, a-Acetyl-N-arylhydrazonoyl Chlorides, Ethyl 7-Oxopyrido[2,3-f]quinoxaline-8-carboxylates
J. A. Zahra, M. A. Khanfar, M. M. El-Abadelah, B. A. A. Thaher, N. S. El-Abadla, and W. Voelter
1045  Full Text
Crystal Structures of Ni(AlCl4)2, Ni(GaCl4)2 and Na[Ni(AlCl4)3] (In German)
Key words: Nickel, Tetrachloroaluminate, Tetrachlorogallate, Crystal Structure
U. Keßler and R. Müller
1052  Full Text
Ba5Al2Ge7 and Ba7Al4Ge9: Two New Intermetallic Phases with Unusual Al-Ge Anions (In German)
Key words: Barium, Aluminium, Germanium, Zintl Phases, Cluster Compounds
M. Wendorff and C. Röhr
1059  Full Text
Sr3Al2Ge4, Ca10Al6Ge9 and Ca20Al6Ge13. New Aluminium Germanides (In German)
Key words: Aluminium, Germanium, Zintl Phases
M. Wendorff and C. Röhr
1071  Full Text
3,4-, 4,7- and 1,4,7-Substituted Indenyl-TiCl3 Complexes: Synthesis and Comparison of Substituent Effects (In German)
Key words: Halfsandwich Complexes, Indenyl, Titanium, UV/vis, Cyclovoltammetry, Substituent Effects
T. Weiß, E. Meichel, H. Sachse, S. Spange, and H. Lang
1083  Full Text
Synthesis and Structural Characterization of Bis(aziridine) Cobalt(II), Zinc(II) and Palladium(II) Complexes
Key words: Cobalt, Zinc, Palladium, Aziridine, X-Ray Crystallography
J. N. Roedel, R. Bobka, M. Pfister, M. Rieger, B. Neumann, and I.-P. Lorenz
1095  Full Text
Note
Crystal Structure, Vibrational Spectrum and Thermal Behavior of the Ammonium Hexathiohypodiphosphate Dihydrate, (NH4)4P2S6 · 2 H2O
Key words: Hexathiodiphosphate(IV), Hexathiohypodiphosphate, Crystal Structure, Raman, IR
M. Gjikaj and W. Brockner
1102  Full Text
N u m b e r  9
Original Communications
Organometallic Compounds of the Lanthanides 182. Calcium and Neodymium Complexes Containing the dpp-BIAN Ligand System: Synthesis and Molecular Structure of [(dpp-BIAN)CaI(THF)2]2 and [(dpp-BIAN)NdCl(THF)2]2
Key words: Neodymium, Calcium, Diimine Ligands, X-Ray Structure
H. Schumann, M. Hummert, A. N. Lukoyanov, V. A. Chudakova, and I. L. Fedushkin
1107  Full Text
2D and 3D Silver(I)-Ethylenediamine Coordination Polymers with Ag-Ag Argentophilic Interactions
Key words: Silver Compound, Ethylenediamine, Coordination Polymer, Crystal Structure, Ag-Ag Interaction
J.-X. Dai, H.-L. Zhu, A. Rothenberger, and Q.-F. Zhang
1112  Full Text
Synthesis and Structures of \mU3-Oxo-centered Mixed-valent Trinuclear Iron Complexes with 1-Methyl-imidazole Ligands
Key words: Synthesis, Crystal Structure, Trinuclear Iron Complex, Mixed-valent Iron Complex
J.-X. Dai, F.-H. Wu, A. Rothenberger, and Q.-F. Zhang
1117  Full Text
Reactions of Nickel(II) Sulfate Hexahydrate with Methyl(2-pyridyl)ketone Oxime: Two Mononuclear Sulfato Complexes Containing the Neutral Ligand
Key words: Crystal Structures, Infrared Spectra, Methyl(2-pyridyl)ketone Oxime Complexes, Nickel(II) Complexes, Sulfate Ligand
C. Papatriantafyllopoulou, C. P. Raptopoulou, Aris Terzis, J. F. Janssens, S. P. Perlepes, and E. Manessi-Zoupa
1123  Full Text
Crystal Structure, Spectroscopic and Redox Properties of Copper(II) Bis{2-[(2,6-dimethylphenyl)iminomethyl-3-methoxyphenolate]}
Key words: Crystal Structure, C-H···p(Ph) Bonding, Superexchange
V. T. Kasumov, \.I. Uçar, A. Bulut, and F. Köksal
1133  Full Text
Structure and Fluorescent Properties of a Chiral Cd(II) Complex: Cd(bpy)(H2O)(PhCH=CHCO2)2
Key words: Crystal Structure, Cadmium, Chirality, Fluorescent Properties
X.-W. Wang, J.-Z. Chen, and J.-H. Liu
1139  Full Text
Solid State Phase Equilibria in the Er-Ni-P and Er-Ni-As Systems at 800°
Key words: Rare Earth Compounds, Phosphide, Arsenide, Phase Diagram, Crystal Structure
M. Zelinska, O. Zhak, S. Oryshchyn, T. Polianska, and J.-Y. Pivan
1143  Full Text
ScPtP and LaPtP - Two Phosphides with "Inverse" TiNiSi-Type Structure (In German)
Key words: Phosphide, Scandium, Lanthanum, Platinum, Crystal Structures
A. Imre and A. Mewis
1153  Full Text
Polysulfonylamines, CLXXIX. Intermolecular Interactions in Crystalline Di(organosulfonyl)amines. Part 4. Di(4-iodobenzenesulfonyl)amine and Two Methylpyridinium Di(4-iodobenzenesulfonyl)amides: Iodine-Oxygen vs. Iodine-Iodine Interactions (In German)
Key words: Hydrogen Bonding, Iodine-Oxygen Interactions, Iodine-Iodine Interactions, Sulfonamides, Nitrogen Heterocycles
E.-M. Zerbe, M. Freytag, P. G. Jones, and A. Blaschette
1157  Full Text
Polysulfonylamines, CLXXX. Bis(triphenylphosphoranylidene)ammonium Di(methanesulfonyl)amide: A Crystal Structure Featuring Methyl-Phenyl CH/p Interactions
Key words: Activated Methyl Groups, Methyl-Phenyl CH/p Interactions, Weak Hydrogen Bonding, Multiple Phenyl Embraces, Sulfonamides (In German)
C. Wölper, P. G. Jones, and A. Blaschette
1167  Full Text
Triethylborane: An "Old" Reagent with New Functions. 1,2-Hydroboration
Key words: Alkynes, Alkenes, Triethylborane, Silanes, Hydroboration, NMR
B. Wrackmeyer, E. Khan, S. Bayer, and K. Shahid
1174  Full Text
One-pot Microwave-assisted Tandem Deprotection of Arylmethanesulfonates / SNAr Reaction for K2CO3-mediated C(Aryl)-O Bond Formation
Key words: Tandem Reaction, Arylmethanesulfonates, SNAr, Aryl Halides, Cross-coupling
H. Xu and H.-F. Li
1183  Full Text
Malonyl-4,5-dihydroniphimycin: A New Polyol Macrolide Antibiotic, Produced by Streptomyces hygroscopicus
Key words: Streptomyces hygroscopicus 15, Malonyl-4,5-dihydroniphimycin, Antifungal and Antibacterial Activity
V. Ivanova, M. Kolarova, and K. Aleksieva
1187  Full Text
A New Bioactive Steroidal Saponin from Agave brittoniana
Key words: Agave brittoniana, Agavaceae, Steroidal Saponin, Antiinflammatory Activity}
B. P. da Silva and J. P. Parente
1193  Full Text
Isoquinoline Alkaloids from Corydalis taliensis
Key words: Corydalis taliensis Franch, Isoquinoline Alkaloid, Talensineside
Y.-R. Wu, Y.-X. Zhao, Y.-Q. Liu, and J. Zhou
1199  Full Text
Fusapyridons A and B, Novel Pyridone Alkaloids from an Endophytic Fungus, Fusarium sp. YG-45
Key words: Fusarium sp., Endophyte, Pyridone, Sambutoxin, Fusapyridons A and B
M. Tsuchinari, K. Shimanuki, F. Hiramatsu, T. Murayama, T. Koseki, and Y. Shiono
1203  Full Text
Laportoside A and Laportomide A: A New Cerebroside and a New Ceramide from Leaves of Laportea ovalifolia
Key words: Cerebroside, Ceramide, Laportea ovalifolia
D. Tazoo, K. Krohn, H. Hussain, S. F. Kouam, and E. Dongo
1208  Full Text
A Novel Phenylethanoid Dimer and Flavonoids from Jacaranda mimosaefolia
Key words: Jacaranda mimosaefolia, Bignoniaceae, Leaves, Acetocide Dimer, Flavone and Flavonol Glycosides
F. A. Moharram and M. S. A. Marzouk
1213  Full Text
Notes
The Crystal Structure of 5-Bis(thiomethyl)methylene Meldrum's Acid (In German)
Key words: Zwitterionic States, Heterocycles, Crystal Structure
N. Kuhn, A. Al-Sheikh, C. Maichle-Mößmer, M. Steimann, and K. Sweidan
1221  Full Text
The Complex BiCl3 · CH3C6H5
Key words: Bismuth, Arene Complex, X-Ray Crystallography
H. J. Breunig, E. Lork, and C. Ra\ct
1224  Full Text
N u m b e r  10
Original Communications
Sr14[Al4]2[Ge]3: A Zintl Phase with Isolated [Ge]4- and [Al4]8- Anions
Key words: Aluminium, Germanium, Zintl Phases, Band Structure Calculation
M. Wendorff and C. Röhr
1227  Full Text
Hydrates of Li3VO4: Synthesis and Structural Chemistry
Key words: Vanadates, Lithium, Hydrates (In German)
S. Schnabel and C. Röhr
1235  Full Text
A Metal Nitride Carbodiimide with a Stuffed Skutterudite-type Structure: Synthesis, Crystal Structure and IR Spectra of (Ba6N5/6)2[NbN4][CN2]6
Key words: Barium, Carbodiimide, IR Spectroscopy, Niobium, Nitride, Skutterudite Structure, Structure Elucidation
O. Reckeweg, M. Somer, and F. J. DiSalvo
1246  Full Text
A Xanthene-based Ligand with Two Adjacent Malonate Binding Sites
Key words: Zinc, Lithium, Ligand Synthesis, Xanthene, Malonate, Metalation
I. Siewert and C. Limberg
1251  Full Text
1,3,2-Diazaalumina-[3]ferrocenophanes with Alkyn-1-yl Substituents at Aluminum
Key words: Aluminum, Ferrocenophane, Alkynes, NMR, X-Ray
B. Wrackmeyer, E. V. Klimkina, and W. Milius
1259  Full Text
Crystal Structure and Fluorescence Properties of a New Ternary Binuclear Complex: Sm2(C3H3O2)6(phen)2
Key words: Crystal Structure, Binuclear Samarium(III) Complex, Ternary Complex, Fluorescence Properties
X.-W. Wang, F.-P. Chen, L. Chen, and J.-Z. Chen
1267  Full Text
Crystal Structures and Stability of Two Bipyridyl Complexes of Metal Chloroacetates
Key words: Crystal Structures, Metal Chloroacetate Complexes, Thermal Behavior
L. Chen, X.-W. Wang, J.-Z. Chen, and J.-H. Liu
1271  Full Text
Adsorption of Carboxylate Anions on a CaCO3 Surface
Key words: Adsorption, Enthalpy, Carboxylic Acids, Zeta Potential, Calcite
J. Plank and G. Bassioni
1277  Full Text
Synthesis of the Amides M[N(SiMetBu2)(SitBu3)] (M = Li, Na) by N2-Elimination Reaction of the Triazenides M[tBu3SiNNNSiMetBu2] (M = Li, Na) (In German)
Key words: Triazene, Nitrogen, Silanide, Silyl Amine, X-Ray Structure Analysis
H.-W. Lerner, I. Sänger, F. Schödel, K. Polborn, M. Bolte, and M. Wagner
1285  Full Text
Synthesis and Crystal Structures of Silver Thianthrene Complexes with Weakly Coordinating Anions
Key words: Silver Complexes, Sulfur Dioxide, Thianthrene Complexes, Weakly Coordinating Anions, Crystal Structure
R. T. Tjahjanto and J. Beck
1291  Full Text
One-pot, Three-component Synthesis of 7H-[1,3,4]Thiadiazolo[3,2-a]pyridines from 2-Phenacyl-[1,3,4]thiadiazole Derivatives and Arylmethylene-cyanoacetic Acid Derivatives
Key words: 7H-[1,3,4]Thiadiazolo[3,2-a]pyridines, 2-Methyl-5-phenacyl-1,3,4-thiadiazoles, Aromatic Aldehydes, CH2-Acidic Compounds, Arylmethylene-cyanoacetic Acid Derivatives
I. A. Hashmi, W. Frey, I. C. Ivanov, and W. Kantlehner
1298  Full Text
Synthesis and a Configurational Correlation within cis- and trans-Oxazolotetrahydroisoquinolinones with an Angular Substituent
Key words: Homophthalic Anhydride, 2-Oxazolines, 2D-H-NOESY, Oxazolotetrahydroisoquinolinones, Diastereomers, Configurational Correlation
P. P. Christov and M. D. Palamareva
1305  Full Text
Cytotoxic Hybrids Between the Aromatic Alkaloids Bauerine C and Rutaecarpine
Key words: Cytotoxic Activity, Hybrids, Bauerine C, Rutaecarpine, Alkaloids
K. Huber and F. Bracher
1313  Full Text
An Improved and Green Preparation of 3-(Alkylthio)propionic Acids
Key words: Thio-alkylation, Microwave-assisted Synthesis, Unsymmetrical Sulfide, b-(Alkylthio)carboxylic Acid
M. J. P. Vaismaa, S. M. Yliniemelä, and M. K. Lajunen
1317  Full Text
New Chemical Derivatives of the Natural Compound Dictyophlebine Inhibiting Acetyl- and Butyrylcholinesterase
Key words: Dictyophlebine, Acetyl- and Butyrylcholinesterase, Chemical Derivatives, N-Alkylation, Hydrochlorination
K. P. Devkota, M. I. Choudhary, S. Anjum, S. A. Nawaz, B. N. Lenta, and N. Sewald
1324  Full Text
Benzopyran-4-one Derivatives from the Fungus Ganoderma applanatum
Key words: Ganoderma applanatum, Benzopyran-4-one Derivatives, Applanatins A and B
F. Wang, Z.-J. Dong, and J.-K. Liu
1329  Full Text
A New Germacranolide and a New Ceramide from Salvia nubicola (Lamiaceae)
Key words: Nubtrienolide, Nubenamide, Salvia nubicola, X-Ray Crystallography, Bioactivity
M. S. Ali, S. A. Ibrahim, S. Ahmed, and E. Lobkovsky
1333  Full Text
Note
Simple Methylcadmium Alkoxides
Key words: Alkoxide, Cadmium, Crystal Structure
S. Jana, T. Pape, and N. W. Mitzel
1339  Full Text
N u m b e r  11
Original Communications
Alkali Salts of 1-Methyl-5-nitriminotetrazole - Structures and Properties
Key words: 1-Methyl-5-nitriminotetrazole, Alkali Salts, Crystal Structures, DSC, Pyrotechnics, Calorimetry
T. M. Klapötke, H. Radies, and J. Stierstorfer
1343  Full Text
Synthesis and Structural Characterization of trans-Bis[1,3-bis(methoxyethyl)-4,5-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichloropalladium(II)
Key words: Bulky Substituents, N-Heterocyclic Carbene, Palladium(II) Complex, Imidazolidin-2-ylidene, Methoxy-donor
A. G. Gökçe, R. K\il\inçarslan, M. Aygün, B. Çetinkaya, and S. Garc\'ia-Granda
1353  Full Text
Synthesis of Fluorosilylenolates, Aminosilylenolates, -ethers, and Aldol Condensates (In German)
Key words: Keto-Enol Tautomerism, Fluorosilylenolates, Fluorosilylethers, Aldol Condensates, Cyclosiloxanes
T. Büschen, W. Dietz, U. Klingebiel, M. Noltemeyer, and Y. Schwerdtfeger
1358  Full Text
Bis (1-cyclohexene-3-on-1-oxy)silanes, Silyl-enoles of b-Ketones (In German)
Key words: Silylenole, Cyclohexane-1,3-dione, Spirocyclic Diketone
W. Dietz, Y. Schwerdtfeger, U. Klingebiel, and M. Noltemeyer
1371  Full Text
Some Phosphide Halides of Lanthanum and Related Compounds (In German)
Key words: Phosphide Halides, Lanthanum, Condensed Clusters, Polytypism
O. Oeckler, H. Mattausch, and A. Simon
1377  Full Text
Ba3YRu0.73(2)Al1.27(2)O8 and Ba5Y2Ru1.52(2)Al1.47(2)O13.5: New Perovskite Ruthenates with Partial Octahedra Replacement
Key words: Crystal Structure, Solid State Synthesis, Ruthenium, Perovskite
B. Schüpp-Niewa, L. Shlyk, Y. Prots, G. Krabbes, and R. Niewa
1383  Full Text
Synthesis and Crystal Structure of Hg2V8O20 - the First Ternary Mercury Vanadate with Mixed-valent Vanadium (IV/V)
Key words: Mercury, Vanadium, Crystal Structure, Mixed Valence, Vanadium Oxide Framework
M. Weil, B. Stöger, A. L. Wessels, and W. Jeitschko
1390  Full Text
Transition Metal-Indium Substitution in Y3Rh2-type Compounds
Key words: Indium, Intermetallics, Crystal Chemistry
R. Zaremba, U. Ch. Rodewald, V. I. Zaremba, and R. Pöttgen
1397  Full Text
New Indium-rich Indides SrTIn4 (T = Ni, Pd, Pt)
Key words: Intermetallics, Indium, Alkaline Earth Compounds
I. Muts, V. I. Zaremba, V. V. Baran, and R. Pöttgen
1407  Full Text
NOHSO4/HF - A Novel Etching System for Crystalline Silicon
Key words: Acidic Etching, Mono- and Multicrystalline Silicon, Nitrosyl Ion
S. Patzig, G. Roewer, E. Kroke, and Ingo Röver
1411  Full Text
Solid-state 17O NMR Study of Small Biological Compounds
Key words: Solid-state 17O NMR, Electric-field-gradient Tensor, Chemical Shielding Tensor, Amino Acid, Peptide
K. Yamada, T. Shimizu, M. Yoshida, M. Asanuma, M. Tansho, T. Nemoto, T. Yamazaki, and H. Hirota
1422  Full Text
A Class of Non-Kekulé Molecules with Low Excitation Energies
Key words: Non-Kekulé Molecules, Triplet Diradicals, Molecular Systems with Low Excitation Energies
F. Dietz, N. Drebov, and N. Tyutyulkov
1433  Full Text
Third-order Nonlinear Optical Properties and Crystal Structures of N-(2-Nitrobenzalidene)-2,4-dimethylaniline and N-(3-Nitrobenzalidene)-2,4-dimethylaniline
Key words: Third-order Optical Nonlinearity, One-photon Absorption, First Hyperpolarizability, Second Hyperpolarizability, Configuration Interaction
A. Karaka\cs, H. Ünver, and A. Elmal\i
1437  Full Text
Polysulfonylamines, CLXXXII. Bis(triphenylphosphoranylidene)ammonium Di(4-fluorobenzenesulfonyl)amide: Two Polymorphs Featuring Different Conformations of the Cation and the Anion
Key words: Conformational Polymorphism, Weak Hydrogen Bonding, CH/p Interactions
C. Wölper, I. Dix, M. Freytag, P. G. Jones, and A. Blaschette
1443  Full Text
Synthesis and Antibacterial Potency of 4-Methyl-2,7-dioxo-1,2,3,4,7,10-hexahydropyrido[2,3-f]quinoxaline-8-carboxylic acid, Selected [a]-Fused Heterocyles and Acyclic Precursors
Key words: Pipecolinic Acid, Sarcosine, 7-Chloro-8-nitro-4-oxoquinoline-3-carboxylic Acid, SNAr Reactions, Reductive Lactamization, Antibacterial Activity
Y. M. Al-Hiari, A. M. Qaisi, M. Y. Abu Shuheil, M. M. El-Abadelah, and W. Voelter
1453  Full Text
Synthesis of New b-Lactam Analogs and Evaluation of Their Histone Deacetylase (HDAC) Activity
Key words: b-Lactams, Histone Deacetylase, Coupling Reaction, Anticancer, Synthesis
S. Oh, J.-C. Jung, and M. A. Avery
1459  Full Text
Chemical Constituents from Pedicularis rex} C. B. Clarke
Key words: Scrophulariaceae, Pedicularis rex, Pedicurexoside, Flavonoid, Iridoid
H.-B. Chu, N.-H. Tan, and Y.-M. Zhang
1465  Full Text
N u m b e r  12
Original Communications
A Chain-like Polyoxotungstate Constructed from [CeW10O36]9-, [Na5(H2O)17Cl]4+, and [Na2(H2O)8]2+ Units: (NH4)3[Na5(H2O)17Cl]{[Na(H2O)4]2[CeW10O36]} · 6 H2O
Key words: Polyoxotungstate, Cerium, Cluster, Crystal Structure
L. Yuan, C. Qin, X. Wang, and E. Wang
1471  Full Text
Synthesis and Structural Characterization of a Tetranuclear Zinc(II) Complex with P,P'-Diphenylmethylenediphosphinate (pcp) and 2,2'-Bipyridine (2,2'-bipy) Ligands
Key words: Zinc(II), Tetranuclear Complex, Diphosphinate, 2,2'-Bipyridine, Inorganic-Organic Hybrid
A. Ienco, S. Midollini, A. Orlandini, and F. Costantino
1476  Full Text
Some Air-stable Unsymmetrical Nickel 1,2-Dithiolenes with Extended Tetrathiafulvalenedithiolato Ligands
Key words: Metal 1,2-Dithiolenes, Single-component Semiconductors, Thin Films
G. C. Papavassiliou, G. C. Anyfantis, and I. B. Koutselas
1481  Full Text
Structure, Characterization and ab Initio Calculations of [Mn(4,4'-bipy)2(H2O)4][HOOCC6H4SSC6H4COO]2
Key words: Crystal Structure, ab Initio Calculation, Hydrogen Bonds, Supramolecule
Z. L. Wang, L. R. Yang, and J. P. Wang
1487  Full Text
A Quantum Chemistry Approach to the Force Fields of the Thionyl and Selenyl Halides, SOX2 and SeOX2
Key words: Thionyl Halides, Selenyl Halides, Force Constants, Structure, DFT Calculations
L. E. Fernández and E. L. Varetti
1491  Full Text
C48 Buckybowl and C60 Fullerene Precursors on the Basis of Truxenone
Key words: Fullerene, Truxenes, Flash Pyrolysis, Cyclization
K. Y. Amsharov and M. Jansen
1497  Full Text
Phenylboration of Monoalkyn-1-yltin Compounds
Key words: Triphenylborane, Organoboration, Alkynes, Organotin, NMR, X-Ray
B. Wrackmeyer, O. L. Tok, and W. Milius
1509  Full Text
Oxidation of Methylpiperidine Derivatives with Regard to Chirality (In German)
Key words: Hg(II)-induced Dehydrogenation, Methylpiperidine, Oxazolidine
H. Möhrle and T. Berkenkemper
1514  Full Text
Conjugated Compounds Based on Vinylthiazole Units
Key words: Absorption, Conjugation, Fluorescence, Polarization, Push-pull Effect
H. Meier, F. Nicklas, and R. Petermann
1525  Full Text
A New Supramolecular Assembly Obtained by Reaction Between Thiosaccharin and Hexamethylenediamine
Key words: Hexamethylenediammonium Bis(thiosaccharinate) Dihydrate, Crystallographic Data, Supramolecular Adduct, IR Spectra
E. J. Baran, O. E. Piro, and J. Zinczuk
1530  Full Text
Optical and Structural Properties of a Eu(II)-Doped Silico-aluminate with Channel Structure and Partial Site Occupation
Key words: Disorder, Structure Refinement, Silico-aluminate, Luminescence, Channel Structure
A. Rief, F. Kubel, and H. Hagemann
1535  Full Text
The Crystal Structure of NbO2I - A Double-layer Structure with 7-Coordinated Niobium
Key words: Niobium Oxide Halide, Double-layer Structure, 7-Coordination, Single Crystal, Structure Determination
S. Hartwig and H. Hillebrecht
1543  Full Text
Zinc-rich Alkaline Earth Compounds AZn5 and AZn11: Crystal Structures and Chemical Bonding (In German)
Key words: Zinc, Intermetallics, Band Structure Calculation
M. Wendorff and C. Röhr
1549  Full Text
Synthesis and Structure of Sr2Pd2In and Sr2Pt2In
Key words: Strontium Intermetallics, Crystal Structure
I. Muts, T. Nilges, U. Ch. Rodewald, V. I. Zaremba, and R. Pöttgen
1563  Full Text
Ternary Scandium-rich Indides Sc50T13In3 and Sc50Rh13In3Oy (T = Rh, Ir; y ~ 8) - Synthesis and Crystal Structure
Key words: Scandium, Intermetallics, Suboxides, Crystal Structure
R. Zaremba and R. Pöttgen
1567  Full Text
Transition Metal-centered Trigonal Prisms as Building Units in RE14T3In3(RE = Y, Ho, Er, Tm, Lu; T = Pd, Ir, Pt) and Y4IrIn
Key words: Metal-rich Compounds, Intermetallics, Crystal Structure
R. Zaremba, U. Ch. Rodewald, and R. Pöttgen
1574  Full Text
Structure and Magnetic Properties of CePtZn
Key words: Intermetallics, Cerium, Magnetic Properties
R. Mishra, W. Hermes, and R. Pöttgen
1581  Full Text
Two Drimane-type Sesquiterpenes, Strobilactones A and B, from the Liquid Culture of the Edible Mushroom Strobilurus ohshimae
Key words: Strobilurus ohshimae, Drimane, Strobilactones A and B, Edible Mushroom
Y. Shiono, F. Hiramatsu, T. Murayama, T. Koseki, T. Funakoshi, K. Ueda, and H. Yasuda
1585  Full Text
Note
Synthesis, Crystal Structure, Spectral and Thermal Characterization, and Antimicrobial Activity of [Cu(HOr)(aepy)(H2O)] \cDot H2O (aepy = 2-aminoethylpyridine, HOr2- = orotate)
Key words: Orotate Complex, Vitamin B13, 2-Aminoethylpyridine, Antimicrobial Activity
O. Z. Ye\csilel, N. Dege, C. Darcan, and Orhan Büyükgüngör
1590  Full Text