Contents Vol. 56b (2001)

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No 2, No 3, No 4/5, No 6, No 7, No 8, No 9, No 10, No 11, No 12

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N u m b e r  1
Original Communications
Structure and Properties of the Stannides CeAuSn, Ce3Rh4Sn13, and Ce3Ir4Sn13
Key words: Intermetallic Compounds, Cerium, Mössbauer Spectra
D. Niepmann, R. Pöttgen, K. M. Poduska, F. J. DiSalvo, H. Trill, and B. D. Mosel
1  Full Text
Preparation and Spectroscopic Characterization of Sodium Pentacyano(phosphane/phosphite)ferrates(III) (In German)
Key words: Pentacyanoferrates(III), Mössbauer Spectra, Phosphorus Ligands
H. Inoue, S. Osone, and E. Fluck
9  Full Text
Interaction in Molecular Crystals, 166. Polyiodo Molecules I2C=CI2, (IC)4S, (IC)4NH, (IC)4N-CH3 and HCI3: Structure Determination Following Crystallization or by Density Functional Theory Calculation (In German)
Key words: Tri- and Tetraiodo-Substituted Carbon Compounds, Density Functional Theory Calculations
H. Bock, S. Holl, and V. Krenzel
13  Full Text
Synthesis and Structure of Chiral Silatranes Derived from Terpenes
Key words: Silatranes, Terpenes, Chiral Pool
G. Wagner, R. Herrmann, B. Pedersen, and W. Scherer
25  Full Text
Crystal Structure of Tetraphenylphosphonium Dichloroiodate(I) [PPh4][ICl2] (In German)
Key words: Dichloroiodate
R. Minkwitz and M. Berkei
39  Full Text
Crystal Structure and Magnetic Properties of a Linear Trinuclear Ni(II) Complex
Key words: Linear Trinuclear Nickel(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling
E. Kavlakoglu, A. Elmali, Y. Elerman, R. Werner, I. Svoboda, and H. Fuess
43  Full Text
New Information on the Na-Ti-Se Ternary System
Key words: Molten Salt Fluxes, Polychalcogenide, Polyselenide
J. A. Aitken and M. G. Kanatzidis
49  Full Text
Some Organic-Inorganic Hybrid Compounds Based on iso-Thiuronium Cations and Lead Halide Anions
Key words: Organic-Inorganic Hybrids, Low-Dimensional Semiconductors, Fluorescence
G. C. Papavassiliou, G. A. Mousdis, and I. B. Koutselas
57  Full Text
Metal Complexes of Biologically Important Ligands, CXXXI. Pentamethylcyclopentadienyl Halfsandwich Complexes of Rhodium and Iridium with Glycosyl-aa-iminocarboxylates as Chelate Ligands (In German)
Key words: Rhodium, Iridium, Pentamethylcyclopentadienyl
S. Krawielitzki and W. Beck
62  Full Text
Metal Complexes of Biologically Important Ligands, CXXXII. N,O-Chelate Complexes of Palladium(II),Platinum(II),and Iridium(III)with the Anion of Glucosaminic Acid (2-Amino-2-deoxy-D-gluconic Acid) (In German)
Key words: Palladium, Platinum, Iridium
S. Krawielitzki and W. Beck
69  Full Text
Synthesis and Structure of Benzyl Substituted Derivatives of the Dinickel Triple-Decker Complex m-h5,h5-(2,3-Dihydro-1,3-diborolyl)-(h3-allyl)(h4-1,5-hexadiene)dinickel (In German)
Key words: Nickel, Polydecker Complexes
W. Siebert, S. Huck, and H. Pritzkow
73  Full Text
Synthesis and Crystal Structure of Mn2(C2H5NH2)2Sb2S5 Exhibiting a Reversible Phase Transition
Key words: Thioantimonates, Solvothermal Synthesis, Chalcogenides
M. Schur, C. Näther, and W. Bensch
79  Full Text
Preparation, 11B, 13C-NMR and Vibrational Spectra of Cs2[B6Cl5(p-C6H4(NH2))] and Crystal Structure of (Ph4P)2[B6Cl5(p-C6H4(NH2))] · 2 CHCN · 0.5 Et2O (In German)
Key words: Arylhydrohexaborate
S. Zander and W. Preetz
85  Full Text
Dimeric Di(N-lithio-tert-butylamino)bis(dimethylamino)silane - [Si(N(CH3)2)2(NLiC(CH3)3)2]2 - Synthesis and Crystal Structure (In German)
Key words: N-Lithio Aminosilane, CP-MAS-NMR
J. Engering, E.-M. Peters, and M. Jansen
90  Full Text
On Complexes of the Type {(PhCºC)3P}3M(CO)3 (M = Cr, Mo, W) (In German)
Key words: Chromium, Molybdenum, Tungsten
N. Kuhn, M. Göhner, and M. Steimann
95  Full Text
Crystallographic and Spectroscopic Evidence of O-Bonding in 3d-Metal Dicyanomethanidonitrite Complexes
Key words: Dicyanomethanidonitrite Complexes
M. Hvastijová, J. Kohout, J. W. Buchler, H. W. Katzenmeier, J. Ko\vzíšek, and C. Didierjean
100  Full Text
Orthoamide2, LV. C7H7N3O6 - Tris(diformylamino)methane ("Formylaalen") - an Orthoformic Acid Amide Derivative with Six Formyl Groups (In German)
Key words: Orthoformic Acid Amide Derivate
W. Kantlehner, G. Ziegler, M. Ciesielski, O. Scherr, and M. Vettel
105  Full Text
Germanium Isotope Effect on the 19F Chemical Shift in Difluorodimethylgermane and the 13C Chemical Shift in Tetramethylgermane (In German)
Key words: Difluorodimethylgermane, Germanium Isotope Effect
W. Buchner and W. Wolfsberger
108  Full Text
N u m b e r  2
Original Communications
Interaction in Molecular Crystals, 167. Crystallization and Structure Determination of s-Donor/Acceptor Complexes between 1,4-Dioxane and the Polyiodine Molecules I2, I2C=CI2, (IC)4S and (IC)4NR (R = H, CH3) (In German)
Key words: Donor/Acceptor Complexes, 1,4-Dioxane and Polyiodine Compounds, Selforganization Phenomena
H. Bock and S. Holl
111  Full Text
Reaction between Yttrium Nitrate and 2,2':6',2"-Terpyridine (terpy) in MeCN: Preparation, Crystal Structures and Spectroscopic Characterization of [Y(NO3)3(terpy)(H2O)] and [Y(NO3)3(terpy)(H2O)] · terpy · 3 MeCN
Key words: 2,2':6',2"-Terpyridine Complexes, Yttrium Nitrate Complexes
A. K. Boudalis, V. Nastopoulos, A. Terzis, C. P. Raptopoulou, and S. P. Perlepes
122  Full Text
Acylation of 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene (In German)
Key words: Acylation, Heterocycles, Imidazoles
N. Kuhn, M. Steimann, and M. Walker
129  Full Text
Syntheses and Characterization of 1-Haloazagermatranes
Key words: Germanium, Azagermatranes
P. L. Shutov, S. S. Karlov, J. Lorberth, and G. S. Zaitseva
137  Full Text
Mono- and Bis(cyclopentadienyl)hafnium(IV) Derivatives with Higher Fatty Acids
Key words: Cyclopentadienyl, Hafnium(IV), Fatty Acids
O. P. Pandey, S. K. Sengupta, B. P. Baranwal, S. K. Shukla, and A. Bhatt
141  Full Text
Remarkably Large 15N, 13C and 18O Isotope NMR Shifts of the Mono-coordinate Phosphorus Atoms in the Compounds (Me3Si)iPrNCP, K+[iPrNCP]- and KOCP · 2 DME (DME = 1,2-Dimethoxyethane)
Key words: Aminomethylidynephosphane, Phosphantriylmethylamide, Isotope Shifts
G. Heckmann, G. Becker, S. Horner, H. Richard, H. Kraft, and P. Dvortsak
146  Full Text
Interaction in Molecular Crystals, 168. s-Donor/Acceptor Complexes {HCI3···X-} (X- = Cl-, Br-, I-) of Triiodomethane in Tetraphenylphosphonium Halides (In German)
Key words: Triiodomethane Adducts, Tetraphenylphosphonium Halides, s-Donor/Acceptor and Phenyl/Phenyl Interactions
H. Bock and S. Holl
152  Full Text
Preparation and Characterization of Bis(trichlorosilyl)phenylamine and 2,2,4,4-Tetrachloro-1,3-diphenyl-[1,3,2,4]diazadisiletidine (In German)
Key words: Cross Linking, Silazanes
S. Bzik and M. Jansen
164  Full Text
Rubidium and Caesium Oxoantimonates(V) with Channel Structures. Syntheses, Crystal Structures and Vibrational Spectra (In German)
Key words: Antimonates(V), Oxoantimonates, Raman Spectra
C. Hirschle, J. Rosstauscher, F. Emmerling, and C. Röhr
169  Full Text
Syntheses and Characterization of cis- and trans-Dicyclohexyl-3,3',4,4'-tetracarboxylic Acids and their Dianhydrides (In German)
Key words: Dicyclohexyl-3,3',4,4'-tetracarboxylic Acids, Dianhydrides, Isomerization
A. Shiotani
179  Full Text
Preparation and Structural Characterization of cis-and trans-Tetramethyl Dicyclohexyl-3,3',4,4'-tetracarboxylates (In German)
Key words: Tetramethyl Dicyclohexyl-3,3',4,4'-tetracarboxylates
A. Shiotani
189  Full Text
Spectro-Electrochemistry of Diethyldithiocarbamate Complexes of Ni(II),Pd(II)and Pt(II)
Key words: Cyclic Voltammetry, Sulphur Donor Ligands, Diethyldithiocarbamate Complexes
\cS. Ö. Yaman, A. M. Önal, and H. Isci
202  Full Text
Preparation and Crystal Structureof Cs6Cl4O (In German)
Key words: Cesium, Halide, Solid State Synthesis
A.-V. Mudring and M. Jansen
209  Full Text
Preparation and Characterization of 4-[4-(Dimethylamino)styryl]-1-methyl-pyridinium Lead Triiodide and its Tribromide Analog
G. C. Papavassiliou, G. A. Mousdis, and I. B. Koutselas
Key words: Organic-Inorganic Hyprids, Low-Dimensional Semiconductors, Optical Properties
213  Full Text
The Crystal and Molecular Structure of m-Oxo)bis{chloro(methyl)thienyltellurium(IV)}
Key words: Methyl Thienyl Telluride, Tellurium(IV)
R. Oilunkaniemi, R. S. Laitinen, and Markku Ahlgrén
215  Full Text
N u m b e r  3
Original Communications
Synthesis and Structural Characterization of Metal Complexes of 2-Formylpyrrole 4N-methylthiosemicarbazone (4ML1) and 2-Acetylpyrrole 4N-methylthiosemicarbazone (4ML2). The X-Ray Crystal Structures of [Ni(4ML1-H)2], [Pd(4ML1-H)2] and [Cd(4ML2)2I2]
Key words: Thiosemicarbazones, Nickel, Palladium
R. Alonso, E. Bermejo, R. Carballo, A. Castiñeiras, and T. Pérez
219  Full Text
Structural Study of a Binuclear Zinc Complex of 2,6-Diacetylpyridine Bis{N(4)-dimethylthiosemicarbazone}, [Zn(2,6Ac4DM)]2 · MeCN
Key words: Zinc, 2,6-Diacetylpyridine Bis{N(4)-dimethylthiosemicarbazone}, Electrochemical Synthesis
E. Labisbal, A. Castiñeiras, C. A. Brown, and D. X. West
229  Full Text
Synthesis, Spectroscopic Characterization and Crystal and Molecular Structures of {Ph4P[(SeO4)(SnPh3)(SnPh3X)]}n (X = Cl, Br)
Key words: Tin(IV), Triphenyltin Complexes, Selenate Complexes
C. A. Diop, L. Diop, U. Russo, A. Sánchez-Díaz, and A. Castiñeiras
233  Full Text
New Magnesium Compounds RE2Cu2Mg (RE = Y, La - Nd, Sm,Gd - Tm, Lu) with Mo2FeB2 Type Structure
Key words: Intermetallic Compounds, Magnesium, Crystal Structure
R. Mishra, R.-D. Hoffmann, and R. Pöttgen
239  Full Text
The Crystal Structures of [(TMEDA)LiCl]2·Toluene and [(MeCN)2LiCl]n (In German)
Key words: Lithium Chloride Solvates
S. Chitsaz, J. Pauls, and B. Neumüller
245  Full Text
A New Binuclear Lutetium(III) Dimethyl-N-trichloroacetylamidophosphate Complex with a gg'-Dipyridyl Bridge, {Lu[CCl3C(O)NP(O)(OCH3)2]3}2-m(gg'-dipy)
Key words: Lutetium, Carbacylamidophosphate, Dipyridyl
V. A. Trush, J. Swiatek-Kozlowska, V. V. Skopenko, and V. M. Amyrkhanov
249  Full Text
Synthesis, Reactions and 51V NMR Spectroscopic Studies of Imidovanadium(V) Trichlorides: RN=VCl3 (R = H, SiMe3, Alkyl) (In German)
Key words: Imidovanadium(V) Trichlorides
F. Preuss, U. Fischbeck, F. Tabellion, J. Perner, W. Frank, and G. Reiss
255  Full Text
Oxovanadium(IV), Nickel(II) and Palladium(II) Complexes of Tridentate Salicylaldiminates Derived from 2,4-Di-tert-butyl-6-aminophenol
Key words: Tridentate Salicylaldiminates of VO(IV), Ni(II) and Pd(II), ESR, Catalytic Activity
V. T. Kasumov
263  Full Text
Studies on Polyhalides, XXXXII. The Pentaiodide-Ion I5-; an Overview: Preparation and Crystal Structure of [Rb(C16H24O6)](I5)·H2O (In German)
Key words: Crown Ether, Pentaiodide, Polyiodides
I. Pantenburg und K.-F. Tebbe
271  Full Text
Kinetics of the Substitution of Norbornadiene in Tetracarbonyl(norbornadiene)molybdenum(0) by 2,2'-Bipyridine
Key words: 2,2'-Bipyridine, Norbornadiene, Molybdenum
C. Kayran and E. Okan
281  Full Text
[((C6H5)3P)2N]O3 and [(((CH3)2N)3PN)4P]O3, New Ionic Ozonides with Cations suitable for Phase Transfer (In German)
Key words: Ionic Ozonides, Phase Transfer
W. Klein and M. Jansen
287  Full Text
Metal Complexes of Biologically Important Ligands, CXXXIII. a-Aminocarboxylate Chelates of Cyclometalated Rhodium Complexes (In German)
Key words: Rhodium, a-Aminocarboxylate, Cyclometalated Complexes
A. Böhm, K. Polborn, and W. Beck
293  Full Text
New p-Donor Molecules with a Pyrazino Group and their Conducting Salts
Key words: p-Donors, Charge Transfer Complexes, Organic Conductors
G. C. Papavassiliou, Y. Misaki, K. Takahashi, J.-i. Yamada, G. A. Mousdis, T. Sharahata, and T. Ise
297  Full Text
Synthesis, Characterization, Crystal Structure and hybrid DFT Computation of the Chlorooxoarsenate(III), [NMe4]2[As4O2Cl10] · 2 CH3CN
Key words: Arsenic, Chlorooxoarsenate(III), NBO Analysis
T. M. Klapötke and T. Schütt
301  Full Text
Reactions of C(NMe2)4 with Group 6 Carbonyl Compounds. Crystal Structures of [C(NMe2)3][(CO)5CrC(O)NMe2], [C(NMe2)3]2[Mo2(CO)10] and [}C(NMe2)3][(CO)4Mo(O2CNMe2)] (In German)
Key words: Carbamoyl Compounds, Orthoamide, Guanidinium Cation
W. Petz, B. Neumüller, J. Lorberth, K. Megges, and W. Massa
306  Full Text
Quassinoids and Other Constituents from Picrasma crenata
Key words: Picrasma crenata, Simaroubaceae, Quassinoids
H. C. Krebs, P. J. Schilling, R. Wartchow, and M. Bolte
315  Full Text
Modes of Xanthine Complexation to Dirhodium Tetrakis [(R)-a-methoxy-a-(trifluoromethyl)-phenylacetate] in Solution and in the Solid State
Key words: Rhodium Complexes, Xanthines
S. Rockitt, R. Wartchow, H. Duddeck, A. Drabczynska, and K. Kiec-Kononowicz
319  Full Text
Total Synthesis of S-(+)-Argentilactone
Key words: Argentilactone, Carbohydrate Templates, Asymmetric Total Synthesis
M. Saeed, M. Abbas, K. M. Khan, and W. Voelter
325  Full Text
N u m b e r  4 / 5
Original Communications
Chemical Vapour Transport of Intermetallic Phases IV: The System Fe - Ge (In German)
Key words: Chemical Vapour Transport, Phase Diagram
O. Bosholm, H. Oppermann, and S. Däbritz
329  Full Text
A Simple High-Yield Synthesis of Gallium(I) Tetrachlorogallate(III) and the Reaction of Digallium Tetrachloride Tetrahydrofuran Solvate with 1,2-Diols
Key words: Gallium Halides, Gallium Diolates, Oxidative Addition
E. S. Schmidt, A. Schier, N. W. Mitzel, and H. Schmidbaur
337  Full Text
Ethylboration of Stannyl-Substituted Sulfur Diimides
Key words: Aminoboranes, Organoboration, Sulfur Diimides
M. Herberhold, S. Gerstmann, and B. Wrackmeyer
342  Full Text
A Novel Access to Tertiary and Secondary ortho-Aminophenylphosphines by Protected Group Synthesis and Palladium Catalyzed P-C Coupling Reactions
Key words: tert-Butoxycarbonylaniline, ortho-Lithiation, Chlorophosphines
A. Heßler, K. W. Kottsieper, S. Schenk, M. Tepper, and O. Stelzer
347  Full Text
X-Ray Structure of 6(E)-[2(Z)-(Hydroxyimino)-2-phenylethylidene]-7,7,8,8,9,9-hexamethyl-3-phenyl-1,2-oxazaspiro[4.4]non-2-ene
Key words: 1,3-Dipolar Cycloaddition Product, Oxime, Isoxazoline
T. Borowiak, I. Wolska, H. Mayr, and J. Baran
354  Full Text
Synthesis and Characterization of the Manganese Pyroarsenate Mn2As2O7 · 2 H2O
Key words: Pyroarsenate
N. Stock, G. D. Stucky, and A. K. Cheetham
359  Full Text
Atomic Volume, Atomic Distances and Chemical Bonding in Solid Metallic Elements (In German)
Key words: Atomic Volume, Valences, Metallic Elements
M. Trömel und S. Hübner
364  Full Text
Structural Study of an N(4)-Substituted Thiosemicarbazone Prepared from 1-Phenyl-1,2-propanedione-2-oxime, and of a Related Nickel(II) Complex
Key words: Oxime Thiosemicarbazones, Nickel(II)
E. Bermejo, A. Castiñeiras, and D. X. West
369  Full Text
Crystal Structure and Conformation of 2-{(2'-Aminobenzyl)iminoethyl}-5-methoxyphenol
Key words: Schiff Base, 2-{(2'-Aminobenzyl)iminoethyl}-5-methoxyphenol
D. K. Dey, S. P. Dey, A. Elmali, and Y. Elerman
375  Full Text
Synthesis of Novel Tetracarboxylato Dirhenium(III) Compounds and Crystal Structure of [Re2(1-Adamantylcarboxylate)4Cl2] · 4 CHCl3
Key words: Rhenium, Clusters, Adamantane
A. V. Shtemenko, A. A. Golichenko, and K. V. Domasevitch
381  Full Text
The Chemical Evolution of a Nitrogenase Model, XXIII. The Nature of the Active Site and the Role of Homocitric Acid in MoFe-Nitrogenase
Key words: Nitrogen, Acetylene, Homocitric Acid
J. G. Palmer, P. A. Doemeny, and G. N. Schrauzer
386  Full Text
New Dinuclear Transition Metal Complexe with the [M2(m-dhbq)]n+ Core and 2-(2'-Pyridyl)quinoxaline (L) as a Terminal Ligand: Preparation and Characterization (dhbq2- = the Dianion of 2,5-Dihydroxy-1,4-benzoquinone; M = AgI, MnII, CoII, NiII, CuII, RuII, PdII, FeIII, RhIII; n = 0,2,4)
Key words: 2,5-Dihydroxy-1,4-benzoquinonate(-2)Complexes, Dinuclear Complexes, 2-(2'-Pyridyl)quinoxaline Complexes
S. I. Mostafa, S. P. Perlepes, and N. Hadjiliadis
394  Full Text
Metal Complexes of Biologically Important Ligands, CXXXVII. Halfsandwich Complexes with N,O-Chelates and Schiff Bases of b-Amino Acids (In German)
Key words: b-Alanine, b-Phenylalanine, Ruthenium
D. Koch, W. Hoffmüller, K. Polborn, and W. Beck
403  Full Text
Synthesis of a-Tocopheryl Glycosides
Key words: Vitamin E, Glucosylation, a-Tocopheryl Glycosides
S. Witkowski and P. Wa\/lejko
411  Full Text
Synthesis of 3,4-Dihydro-2H-pyrans by Hetero-Diels-Alder Reactions of Functionalized a,b-Unsaturated Carbonyl Compounds with Styrenes
Key words: Hetero-Diels-Alder Reaction, a,b-Unsaturated Ketones, Styrenes
K. Bogdanowicz-Szwed and A. Pa\/lasz
416  Full Text
The Alkaline Metal Oxo-Silicates A6[Si3O9] and A6[Si2O7] (A = Rb, Cs): Preparation and Crystal Structure (In German)
Key words: Silicates, Disilicates, Cyclotrisilicates
C. Hoch and C.Röhr
423  Full Text
Optical Outer-Sphere Charge Transfer and Photoreactivity of the Ion Pair Tetrabutylammonium Tetrabutylborate
Key words: Photochemistry, Tetraalkylammonium, Tetraalkylborate
H. Kunkely and A. Vogler
431  Full Text
Rb8AlO4Au3ºRb5AlO4·3RbAu an Aluminate Auride (In German)
Key words: Aluminates, Aurides, Solid State Synthesis
A.-V. Mudring and M. Jansen
433  Full Text
Efficient Medium-Scale Synthesis of 2-Bromo-5-tert-butylbenzene-1,3-dicarbaldehyde
Key words: 2-Bromo-5-tert-butylbenzene-1,3-dicarbaldehyde, Benzene Derivatives
M. H. Klingele and B. Kersting
437  Full Text
Cocrystallisation of rimethylchloro-stannane with a Distannoxane
Key words: Tin, Stannoxanes, Supramolecular Aggregate
N. W. Mitzel, C. Lustig, and S. Scharfe
440  Full Text
Crystal Structure o a Lithium Chloride Cubane Cluster Solvated by Diethyl Ether
Key words: Lithium Chloride, Aggregation, Crystal Structure
N. W. Mitzel and C. Lustig
443  Full Text
Synthesis and Structure of YbPdSn2
Key words: Stannide, Crystal Structure, Solid State Synthesis
D. Kußmann and Rainer Pöttgen
446  Full Text
Deoxycyclopaldic Acid and Cyclopaldic Acid, Plant Growth Regulators, Produced by Penicillium sp.
Key words: Deoxycyclopaldic Acid, Cyclopaldic Acid, Growth Regulator
A. Shimada, K. Nakaya, S. Takeuchi, and Y. Kimura
449  Full Text
N u m b e r  6
Original Communications
A One-Dimensional Polymeric Form of the Polycation Te82+ in the Structure of Te8[Bi4Cl14]
Key words: catena-Octatellurium(2+), Main Group Element Clusters, Chalcogen Polycations
J. Beck and A. Stankowski
453  Full Text
Preparation and Structure of Cyclic Gallium(III) and Gallium(II) 2-Amino-ethyl-amides
Key words: Gallium(III) and Gallium(II) Amides, Gallium Amino Complexes, Gallium Coordination
E. S. Schmidt, A. Schier, N. W. Mitzel, and H. Schmidbaur
458  Full Text
New Metal-Rich Compounds NbIrSi, NbIrGe, and TaIrSi - Synthesis, Structure, and Magnetic Properties
Key words: Silicides, Germanides, Magnetic Properties
R. Mishra, R. Pöttgen, and G. Kotzyba
463  Full Text
Interaction in Molecular Crystals, 174. Crystal Growth and Structure Determination of Differently Methyl-substituted Tetraphenyl Imidodiphosphates (In German)
Key words: Imidodiphosphate Methyl-Substituted Tetraphenyl Esters, Spatial Overcrowding, Structure Correlation
H. Bock and E. Heigel
469  Full Text
Interaction in Molecular Crystals, 175. Crystal Growth and Structure Determination of {Cesium-tetraphenylimidodiphosphate} Aggregates with Differing Lipophilic Wrapping Due to Differently Methyl Substituted Phenyl Rings, and Relativistic DFT-Model Calculations of Cesium/Cesium Interactions (In German)
Key words: Cesium Tetraphenylimidodiphosphates, Methyl Substitution Effects, Polyion Aggregates, Crystal Structures
H. Bock, E. Heigel, and Z. Havlas
483  Full Text
Defluorination of Graphite Fluoride Applying Magnesium (In German)
Key words: Graphite Fluoride, Defluorination, Magnesium
E.-C. Koch
512  Full Text
Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Complex with Thiosemicarbazonato and Thiocyanate Ligands
Key words: Lead(II) Complex, 2-Acetylpyridine-4N-methylthiosemicarbazone
A. Castiñeiras, R. Domínguez, L. Bresolin, J. Bordinhão, A. J. Bortoluzzi, and M. Hörner
517  Full Text
Dependence of the Distortion of the Square Pyramids in N,N-Dimethylethylenediammonium Pentachloroantimonate(III) on the Geometry of Hydrogen Bonds
Key words: N,N-Dimethylethylenediammonium Cation, Chloroantimonate(III)
M. Bujak and J. Zaleski
521  Full Text
Synthesis and Solid-Phase Application of a 9-Xanthenyl Handle
Key words: Polymer Support, Solid-Phase Synthesis, Xanthene
C. Somlai, P. Hegyes, R. Fenyö, G. K. Toth, B. Penke, and W. Voelter
526  Full Text
a-Dicarbonylmonophenylhydrazones as Nucleophiles and Neighbouring Groups (In German)
Key words: C-Aminomethylation, Mercury(II)-EDTA Dehydrogenation, Intramolecular
H. Möhrle and G. Keller
533  Full Text
Synthesis and Properties of a-Aminocarbohydroximic Esters (In German)
Key words: a-Aminocarboximidates,Meerwein 's Salt, a-Aminothiocarboxylic O-Esters, a-Aminocarbohydroximic Esters, Synthetic Methods
W. Thimann and D. Geffken
547  Full Text
A New Synthesis of Two Naturally Occurring Dihydrobenzo[b]furan-Type Neolignans of Potential Biological Activity
Key words: Benzofurans, Neolignan, Heck Reaction
L. Juhász, Z. Dinya, S. Antus, and T. E. Gunda
554  Full Text
N u m b e r  7
A Word of Thanks to Professor Heinz P. Fritz on the Occation of his Retirement as Editor
A. Klemm
Original Communications
Radical Labeled Metallocenes (M = Fe, Co). Metallocenylene Bridged Bis(3-imidazolin-1-oxyls) (In German)
Key words: 3-Imidazoline-1-oxyl, Ferrocene, Cobaltocinium
H. Dialer, K. Polborn, and W. Beck
563  Full Text
Ab initio Calculations and Qualitative Valence Bond Considerations for H2N-NO2 (Nitramide) and H2N-NO (Nitrosamine)
Key words: Nitramide, Nitrosamine, Valence Bond Structures
J. Geith, T. M. Klapötke, R. D. Harcourt, and P. P. Wolynec
571  Full Text
Synthesis and Structure of Potassium Tetrakis(triisopropylsilylphosphanyl)indate (In German)
Key words: Indates, Indium, Phosphanides
M. Westerhausen, S. Weinrich, and H. Piotrowski
576  Full Text
Transition Metal Complexes with Sulphur Ligands, Part 151. Ligand Enforced Configurations and Low-Spin States of [FeNS4] Cores in [FeII(L)('pyS4')] Complexes with s and s-p Ligands (L = N2H4, pyridine, PMe3, PnPr3; 'pyS4'2- = 2,6-bis(2-mercaptophenylthiomethyl)pyridine(2-))
Key words: Iron Sulphur Complexes, Nitrogenase
D. Sellmann, N. Blum, and F. W. Heinemann
581  Full Text
The Stannides RERhSn (RE = Ho - Yb) and ScTSn (T = Pd, Pt) - Structure Refinements and 119Sn Mössbauer Spectroscopy
Key words: Stannides, Crystal Structure, Mössbauer Spectroscopy
R. Mishra, R. Pöttgen, R.-D. Hoffmann, H. Trill, B. D. Mosel, H. Piotrowski, and M. F. Zumdick
589  Full Text
Synthesis, Structure, and Magnetic Properties of EuAgCd and YbAgCd
Key words: Cadmium, Crystal Structure, Magnetic Properties
T. Fickenscher, G. Kotzyba, R.-D. Hoffmann, and R. Pöttgen
598  Full Text
Ba16Nb5N19 - A Nitridoniobate(V) Containing Isolated [NbN4]7- and [Nb2N7]11- Units
Key words: Nitridometalate, Nitridoniobate
P. Höhn and R. Kniep
604  Full Text
Solvothermal Syntheses, Crystal Structures and Properties of Thiomolybdates with Complex Transition Metal Cations
Key words: Thiomolybdates, Solvothermal Synthesis
J. Ellermeier and W. Bensch
611  Full Text
Crystal and Electronic Structure of LaAlSi2 (In German)
Key words: Silicides, Lanthanum, Aluminium
C. Kranenberg, D. Johrendt, A. Mewis, and W. Kockelmann
620  Full Text
Collidinium and Imidazolium Salts of Fluorine-Containing Anions. The Crystal Structure of [CollH]2[AsF6][As2F11] (Coll = 2,4,6-Trimethylpyridine) (In German)
Key words: Hydrogen Fluoride, Imidazoles, Pyridines
N. Kuhn, S. Fuchs, R. Minkwitz, and T. Berends
626  Full Text
Hexakis(dimethylaminoxy)disiloxane: Insertion of an Oxygen Atom into the Si-Si Bond of a Disilane by Dimethylaminoxy Lithium
Key words: Silicon, Disilane, Siloxane
N. W. Mitzel and U. Losehand
630  Full Text
Supersilyltrielanes R*nEHal3-n (E = Triel, R* = SitBu3): Syntheses, Characterization, Reactions, Structures (In German)
Key words: Silicon, Trieles, Supersilyl
N. Wiberg, K. Amelunxen, T. Blank, H.-W. Lerner, K. Polborn, H. Nöth, R. Littger, M. Rackl, M. Schmidt-Amelunxen, H. Schwenk-Kircher, and M. Warchold
634  Full Text
Silyltrielanes R'nEHal3-n} (E = Al, Ga, In; R' = SitBu2Ph): Syntheses, Characterization, Structures (In German)
Key words: Silicon, Aluminium, Gallium
N. Wiberg, T. Blank, H.-W. Lerner, H. Nöth, T. Habereder, and D. Fenske
652  Full Text
Reactions of Amino-imino-boranes with Transition Metal Halides and Substituted Transition Metal Halides
Key words: Adducts of Aminoimino Boranes, Metallated Diaminoboranes, Titanium
B. Böck, H. Nöth, and U. Wietelmann
659  Full Text
Synthesis and Structure of Di-and Triferriostibonium Salts of the Type [Fp2SbPh2]2FeX4 and [Fp3SbR]2FeX4 (Fp = CpFe(CO)2, R = Ph, Cl; X = Cl, Br, I)
I.-P. Lorenz, R. Schneider, H. Nöth, K. Polborn, and J. Breunig
Key words: Ferriostibonium Salts, Organometallated Antimony, Silyl Method
671  Full Text
Polysulfonylamines CXXXVIII. 1,1-Di(organosulfonyl)-3,3-diorganylureas: Synthesis of Eight Representatives and Crystal Structure of the Prototype (MeSO2)2N-C(O)-NMe2 (In German)
Key words: Sulfonylureas Amide Single Bond,Rotational Barrier
J. Dalluhn, H.-H. Pröhl, A. Blaschette, and P. G. Jones
680  Full Text
Synthesis and Bioactivities of Naturally Occurring Anthraquinones: Isochrysophanol,Isozyganein, w-Hydroxyisochrysophanol and Morindaparvin
Key words: Anthraquinones, Antibacterial Activity of Anthraquinones, Cytotoxicity of Anthraquinones
J. H. Zaidi, F. Naeem, R. Iqbal, M. I. Choudhary, K. M. Khan, S. Perveen, S. T. A. Shah, S. Hayat, and W. Voelter
689  Full Text
N u m b e r  8
Original Communications
Multianvil High-Pressure Synthesis and Crystal Structure of b-YbBO3
Key words: Multianvil, High-Pressure Synthesis, Borates
H. Huppertz
697  Full Text
2,3-Dihydro-2-methoxyethylimino-1,3-dimethylimidazole - a Novel Hemilabile Coordinating Chelate Ligand (In German)
Key words: Imidazoles, Rhodium, Palladium
N. Kuhn, M. Grathwohl, C. Nachtigal, and M. Steimann
704  Full Text
Soluble Pyridine Complexes of the Ternary Gallium(III) Chalcogenide Halides (GaEX)3, with E = S, Se and X = Cl, Br
Key words: Pyridine Complexes, Ternary Gallium(III) Chalcogenide Halides
S. D. Nogai, A. Schier, and H. Schmidbaur
711  Full Text
Antiferromagnetic Coupling in a (m}-Hydroxo)(m}-pyrazolato)dicopper(II) Complex. Synthesis, Crystal Structure, Magnetic Properties, and Theoretical Studies
Key words: Binuclear Copper(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling
H. Kara, Y. Elerman, and K. Prout
719  Full Text
Synthesis of a Large Water-Soluble Gold Cluster (Au32-36) and its Properties as a Potential Label in Electron Microscopy
Key words: Water-Soluble Gold Cluster, Protein Labelling
W. Jahn
728  Full Text
Coordination of the Anion of 2,4-Dicyano Glutaconic Acid Diethyl Ester to tripodIron(II)-Fragments. Formation of Helical Structures (In German)
Key words: 2,4-Dicyano Glutaconic Acid Diethyl Ester Anion, Cyano Bridges, Helix
V. Jacob, G. Huttner, E. Kaifer, and P. Kircher
735  Full Text
Structural Characterization of Rh(III) Complexes Containing the Polypyridyl Ligands and Some Properties of their Derivatives
Key words: Rhodium, Polypyridyl
M. Y. Kim, W. K. Seok, H. N. Lee, S. H. Han, Y. Dong, and H. Yun
747  Full Text
Preparation and Crystal Structures of (Hg3)(PO4)Cl, (Hg3)(AsO4)Cl and (Hg3)(AsO4)Br - Mercury Compounds with the Triangular Hg34+ Cluster
Key words: Kuznetsovite, Mercury Cluster Hg34+, Merohedral Twinning
M. Weil
753  Full Text
Synthesis and Crystal Structures of Chlorometalates [M = V(III), Mo(V)] (In German)
Key words: Vanadium Compound, Molybdenum Compound
S. Chitsaz, E. Iravani, J. Pauls, and B. Neumüller
759  Full Text
Polysulfonylamines, CXL. N-Cycloalkyldimesylamines CnH2n-1N(SO2CH3)2: Syntheses (n = 3 - 6), Solid-State Molecular Structures (n = 4 - 6), and Role of Weak Hydrogen Bonds C-H···O in the Crystal Structures (In German)
Key words: N-Cycloalkyl Di(methanesulfonyl)amines Carbon-Nitrogen Bond Lengthening, Weak Hydrogen Bonds
W. Schaper, I. Lange, D. Henschel, O. Moers, A. Blaschette, and P. G. Jones
765  Full Text
Synthesis and Spectroscopic Studies of New Bis(N-1-hydroxy-2,6-di-tert-butyl-phenyl-salicylideneaminato)cobalt(II)Complexes and their Oxidation with PbO2
V. T. Kasumov, B. Karabulut, I. Kartal, and F. Köksal
778  Full Text
Guaianolide Sesquiterpene Lactones from Cichorium intybus (Asteraceae)
Key words: Guaianolide, Cichorium intybus, Chicory
Y. Deng, L. Scott, D. Swanson, J. K. Snyder, N. Sari, and H. Dogan
787  Full Text
Chloroisosulochrin, Chloroisosulochrin Dehydrate, and Pestheic Acid, Plant Growth Regulators, Produced by Pestalotiopsis theae
Key words: Chloroisosulochrin, Pestheic Acid, Pestalotiopsis theae
A. Shimada, I. Takahashi, T. Kawano, and Y. Kimura
797  Full Text
Synthesis and Antiviral Activity of 2'-Deoxy-2'-fluoro-L-arabinofuranosyl 1,2,3-Triazole Derivatives
Key words: Triazole Nucleosides, Anti-Viral Activity, Glycosyl Azides
S. Ölgen and C. K. Chu
804  Full Text
Synthesis of New Cyclopentadienyl-, Indenyl- and Fluorenylphosphanes by the Reaction of Carbanions of the Cyclopentadienyl Type with Alkyl(aryl)chloro-N,N-dialkylaminophosphanes
Key words: Cyclopentadienylphosphanes, Alkyl(aryl)chloro-N,N-dialkylaminophosphanes, (Amino)cyclopentadienylphosphanes
V. V. Kotov, E. V. Avtomonov, N. A. Ustynyuk, and D. A. Lemenovskii
812  Full Text
Three Reagents in One:Ammonium Permanganate in the Oxidation of Benzyl Alcohol
Key words: Ammonium Permanganate, Oxidation
L. Kótai, B. Kazinczy, Á. Keszler, S. Holly, I. Gács, and K. K. Banerji
823  Full Text
4',x-Seco and 4', x-4',5'-Diseco C-Nucleosides from 2-Hydrazino-(3H)-thieno[2,3- d]pyrimidin-4-ones
Key words: Thieno [2,3-d]pyrimidinone, Triazolo[3,4-a]thieno [2,3-d] pyrimidinone, Sugar Hydrazones
A. A. Hamed, H. F. Bader a, and E.-S. H. El-Ashry
826  Full Text
Phytol and Glycerol Derivatives from the Marine Green Alga Codium iyengarii of the Karachi Coast (Arabian Sea)
Key words: Codium iyengarii, Chlorophyceae Codiosides
M. S. Ali, M. Saleem, V. U. Ahmad, and S. Shameel
837  Full Text
Dihydroquinol and Quinol Derivatives from Ajuga parviflora
Key words: Ajuga parviflora, Labiatae, Dihydroquinol and Quinol Derivatives
E. Akbar, H. R. Nawaz, and A. Malik
842  Full Text
N u m b e r  9
Original Communications Methylated Ammonium and Hydrazinium Salts of 5,5'-Azotetrazolate
Key words: Ammonium, Azotetrazolate, Hydrazinium
A. Hammerl, G. Holl, M. Kaiser, T. M. Klapötke, P. Mayer, H. Piotrowski, and M. Vogt
847  Full Text
New Hydrazinium Salts of 5,5'-Azotetrazolate
Key words: Azotetrazolate, High Nitrogen Materials, Hydrazinium
A. Hammerl, G. Holl, M. Kaiser, T. M. Klapötke, P. Mayer, H. Nöth, H. Piotrowski, and M. Suter
857  Full Text
A Curious Case of Partial Spontaneous Resolution on Crystallization of a Racemate. The Crystal and Molecular Structures of N-Acetyl-DL-alanine Methylester and N-Acetyl-L-alanine Methylester
Key words: Chirality, Racemate, Amino Acids
G. Müller and M. Lutz
871  Full Text
Group 12 Metal Complexes of 2-Formylpyrrole- (4PL1) and 2-Acetylpyrrole-N(4)-phenylthiosemicarbazone (4Pl2), as Examples form Different Donor Modes. Crystal and Molecular Structures of [Hg(4PL1-H)Br]2 and [Zn(4PL2)2Br2] · 2 EtOH
Key words: Pyrrole, Thiosemicarbazones, Group 12 Metal Complex
R. Carballo, A. Castiñeiras, and T. Pérez
881  Full Text
Secondary Bonding Interactions in Some Halopyridinium and Dihalopyridinium Halides
Key words: Pyridinium, Halides, Hydrogen Bonds
M. Freytag and P. G. Jones
889  Full Text
Magnetic Properties and Crystal Structure of a Dinuclear Iron(III) Complex
Key words: Binuclear Iron(III) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling
A. Elmali, Y. Elerman, and I. Svoboda
897  Full Text
Synthesis and Coordination Chemistry of Novel Binucleating Macrocyclic Ligands with Amine-thioether and Amine-thiophenolate Donor Functions
Key words: Macrocyclic Ligands, Nitrogen, Sulfur
M. H. Klingele, G. Steinfeld, and B. Kersting
901  Full Text
Thermical and Calorical Behaviour of Solid LaAl3Br12 and Chemical Transport of LaBr3 with AlBr3 (In German)
Key words: Lanthanum Alumimium Bromide, Calorimetry, Enthalpy
H. Oppermann, H. Dao Quoc, and M. Zhang-Preße
908  Full Text
Thermochemical Investigations of Systems SE2O3-SeO2. II. Samarium Selenium Oxides on the Line Sm2O3-SeO2 (In German)
Key words: Samarium Selenium Oxides, Thermal Decomposition, Phase Diagram
H. Oppermann und M. Zhang-Preße
917  Full Text
Synthesis and Crystal Structure of [Bis(N-oxo-2-acetylpyridine 4N-Methylthiosemicarbazone)zinc(II)] Monohydrate
Key words: Polymeric Zinc(II) Complex, N-Oxo-2-acetylpyridine 4N-Methylthiosemicarbazone
A. Castiñeiras, R. Domínguez, J. Bordinhão, J. S. d. Oliveira, A. J. Bortoluzzi, and M. Hörner
927  Full Text
Spectroscopic and Magnetostructural Evidence for the Formation of [Cu0.5Co0.5(H2Tea)X] Mixed-Crystal Compounds from Zerovalent Cu and Co Salts in the Presence of Triethanolamine (H3Tea - Triethanolamine; X = SCN, Cl)
Key words: Mixed Crystals, Zerovalent Copper, Cobalt(II) Salts
V. G. Makhankova, O. Yu. Vassilyeva, V. N. Kokozay, B. W. Skelton, G. A. V. Albada, and J. Reedijk
931  Full Text
Preparation and Structure of Lithium Bis[cis-ethene-1,2-di(tbutylamido)]gallate(III) Tetrahydrofuran
Key words: Gallium(III) Amide, Gallium Amido Complex, Lithium Gallate
E. S. Schmidt, N. W. Mitzel, and H. Schmidbaur
937  Full Text
Dinuclear and Trinuclear Organometallic Complexes (ReS4)[MCl(C5Me5)], M = Rh, Ir, and (m-WS4)[IrCl(C5Me5)]2 (In German)
Key words: Iridium Compounds, Rhodium Compounds, Tetrathiometallates
M. Wanner, I. Hartenbach, J. Fiedler, T. Schleid, and W. Kaim
940  Full Text
29Si-29Si and 29Si-13C Indirect Nuclear Spin-Spin Coupling, and Isotope-Induced Chemical Shifts 1D12/13C(29Si) and 1D28/29Si(13C), Determined for Silenes Stabilized by Intramolecular N-Si Coordination
Key words: Silicon, Silenes
B. Wrackmeyer and H. Oehme
947  Full Text
Organophosphorus Compounds, Part 146. Imidovanadium(V)Complexes as Reaction Partners for Kinetically Stabilized Phosphaalkynes.Synthesis and Reactivity of 3-Aza-1,2,4,6-tetraphospha-quadricyclanes
Key words: Cyclooligomerization of Phosphaalkynes, Imidovanadium(V) Complexes, 3-Aza-1,2,4,6-tetraphospha-quadricyclanes
C. Peters, F. Tabellion, A. Nachbauer, U. Fischbeck, F. Preuss, and M. Regitz
951  Full Text
Pyrazino-methyl-ethylenedithiotetrathiafulvalene, Precursor of t-Phase Conductors
Key words: Tetrathiafulvalenes, Cation Radical Salts, Organic Conductors
G. C. Papavassiliou, A. Terzis, and C. P. Raptopoulou
963  Full Text
N u m b e r  10
Original Communications
Synthesis and Crystal Structure of Tricesium Undecaphosphide-Ammonia(1/3) Cs3P11 · 3 NH3 (In German)
Key words: Polyphosphides, Liquid Ammonia, Tricesium-undecaphosphide-ammonia(1/3) Cs3P11 · 3 NH3
D. Knettel, M. Reil, and N. Korber
965  Full Text
Magnetic Properties and Crystal Structure of a 3,5-Dimethylpyrazolate-Bridged Binuclear Copper(II) Complex
Key words: Binuclear Copper(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling
Y. Elerman and A. Elmali
970  Full Text
Enantioselective Catalysis, 139. A Chiral Cyclic Amidine Containing a Pyridine Substituent - Synthesis, Coordination Chemistry, Catalysis
Key words: Amidine, Chirality, Cyclopropanation
H. Brunner, R. J. Maier, and M. Zabel
975  Full Text
Key words: Beryllium Chemistry, Beryllium Carboxylates, Quantum Chemical Calculations
R. J. F. Berger, M. A. Schmidt, J. Jusélius, D. Sundholm, P. Sirsch, and H. Schmidbaur
979  Full Text
Three Types of the Samarium(III) Sulfide Selenide Sm2S2-xSe1+x (0.1 £ x < 0.2) (In German)
Key words: Samarium, Sulfides, Selenides
F. Lissner, F. A. Weber, and T. Schleid
990  Full Text
Investigations on the Thermal Decomposition of Coordination Polymers Based on Copper(I) Halides and 2-Methylpyrazine
Key words: Copper(I) Halides, 2-Methylpyrazine, Coordination Polymers
C. Näther, I. Jeß, and H. Studzinski
997  Full Text
Crystal Structure and Tautomerism of 1-[N-(4-Iodophenyl)]aminomethylidene-2(1H)naphthalenone
Key words: Photochromism, Thermochromism, Keto-Enol Tautomerism
H. Ünver, M. Kabak, D. M. Zengin, and T. N. Durlu
1003  Full Text
N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy
Key words: Tin, Lead, Amides
B. Wrackmeyer, A. Pedall, and J. Weidinger
1009  Full Text
Synthesis and Properties of 2-Cyanimino-1,3-dimethylimidazoline [1]} (In German)
Key words: Imidazoles, Nitriles, Molybdenum
N. Kuhn, M. Grathwohl, M. Steimann, R. Boese, and N. L. Madhavi Nalam
1015  Full Text
Synthesis and Crystal Structure of (dmaaH)2(dmaH)2[P12S12N12(NH)2] · 4 dmaa, dmaa = N,N-Dimethylacetamide, dma = Dimethylamine, an Anhydrous Example of the P12N14 Cage
Key words: Phosphorus, Cage Compounds
S. Roth and W. Schnick
1020  Full Text
Syntheses, Crystal Structures and Magnetic Behaviour of [Li(12-crown-4)2][Li(12-crown-4)OH2]2[Nb6Cl18], [Li(15-crown-5)2(OH2)]3[Nb6Cl18], and [(18-crown-6)2(O2H5)]3[Nb6Cl18] (In German)
Key words: Niobium Cluster, Chloride, Crown Ether
M. Ströbele and H.-J. Meyer
1025  Full Text
Investigation of the Thionation Reaction of Cyclic Imides
Key words: Imides, Monothioimides, Dithioimides
A. Orzeszko, J. K. Maurin, and D. Melon-Ksyta
1035  Full Text
Polysulfonylamines CXLII. A Supramolecular Monomer-Dimer Pair: Strongand Weak Hydrogen Bondingin the Crystal Structures of Pyridinium Dimesylamide and 4,4'-Bipyridinediium Bis(dimesylamide)
Key words: Di(methanesulfonyl)amide, Hydrogen Bonding, Supramolecular Chemistry
O. Moers, I. Lange, K. Wijaya, A. Blaschette, and P. G. Jones
1041  Full Text
Polysulfonylamines CXLIII. Role of Weak Hydrogen Bonds (C-H···O) in the Crystal Structures of 2,6-Dimethylpyridinium,1-Hydroxypyridinium and Imidazolium Dimesylamide
Key words: Di(methanesulfonyl)amide, Weak Hydrogen Bonding, Very Short Heteronuclear Hydrogen Bond
O. Moers, K. Wijaya, T. Hamann, A.Blaschette, and P. G. Jones
1052  Full Text
Synthesis and Structural Studies of 5,11,17,23-Tetrahydroxyresorc[4]arenes
Key words: Hydroxyresorc[4]arenes, Hydrogen Bonding
T. Gerkensmeier, C. Agena, W. Iwanek, R. Fröhlich, S. Kotila, C. Näther, and J. Mattay
1063  Full Text
Enaminones as Building Blocks In Heterocyclic Synthesis: A New One Pot Synthesis of Polyfunctional Substituted Pyridines
Key words: Michael Addition, Acyl- and Aroylpyridines, Dihydropyridines
S. M. Agamy, M. M. Abdel-Khalik, M. H. Mohamed, and M. H. Elnagdi
1074  Full Text
Remangilone D, a Ne Bisnoroleanane Triterpene,and a Ne Flavone from Physena madagascariensis
Key words: Physena madagascariensis, Triterpene, Flavone
Y. Deng, M. Tianasoa-Ramamonjy, and J. K. Snyder
1079  Full Text
Metal Complexes of Biologically Important Ligands, CXXXIX. A Ferrocenylene Bridged Pseudohexapeptide Fe[C5H4CH2OGlyBalOMe(Val-Boc)]2
Key words: Ferrocene, Peptide
H. Dialer, W. Steglich, and W. Beck
1084  Full Text
N u m b e r  11
Original Communications
Structure Determination for the Crystalline Phase of Triphenyl Phosphite by Means of Multi-Dimensional Solid-State NMR and X-Ray Diffraction
Key words: Triphenyl Phosphite, Structure Determination, Solid-State NMR
J. Senker and J. Lüdecke
1089  Full Text
Amido-tert-butylimidovanadium(V) Compounds. Synthesis, Reactions and 51V NMR Spectroscopic Studies (In German)
Key words: Amido-tert-butylimido-vanadium(V) Compounds, 51V NMR Spectra
F. Preuss, M. Vogel, U. Fischbeck, J. Perner, G. Overhoff, E. Fuchslocher, F. Tabellion, B. Geiger, and G. Wolmershäuser
1100  Full Text
peri-Interactions in Naphthalenes, 5. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations
Key words: peri-Naphthalenes, Steric Effects
G. Dyker, M. Hagel, G. Henkel, M. Köckerling, C. Näther, S. Petersen, and G. P. Schiemenz
1109  Full Text
[Co(NH3)6]ClCO3 - a Hexaamminecobalt(III) Complex with an 'Ideal' Carbonate Group (In German)
Key words: Hexa(ammine)cobalt(III)-Carbonate Complex, Vibrational Spectroscopy, Thermal Analysis
M. Dahm and A. Adam
1117  Full Text
Crystal Structure and Magnetic Properties of an Oxygen-Bridged Trinuclear Copper(II) Complex
Key words: Trinuclear Copper(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling
Y. Elerman, E. Kavlakoglu, A. Elmali, and E. Kendi
1123  Full Text
Importance of Orbital Complementarity in Spin Coupling through Two Different Bridging Groups. Synthesis, Crystal Structure, Magnetic Properties and Magneto-Structural Correlations in a Dicopper(II) Complex of Endogenous Alkoxo Bridging Ligand with Exogenous Pyrazolate
Key words: Binuclear Copper(II) Complex, Super-Exchange Interactions, Antiferromagnetic Coupling
Y. Elerman, H. Kara, and A. Elmali
1129  Full Text
Thermal Catalytic Hydrosilylation of Conjugated Dienes with Triethylsilane in the Presence of Tricarbonyl(o-xylene)Metal (Metal = Cr, Mo, W) Complexes
Key words: Hydrosilylation, Tungsten, Carbonyl
C. Kayran and P. Rouzi
1138  Full Text
Preparation, Properties, and Crystal Structure of Quaternary Silicide Carbides RCr2Si2C (R = Y, La - Nd, Sm, Gd - Ho)
Key words: Quaternary Silicide Carbides
M. W. Pohlkamp and W. Jeitschko
1143  Full Text
CsCu3Dy2S5 and CsCu3Er2S5: Two Isotypic Quaternary Sulfides of the Lanthanides with Channel Structures (In German)
Key words: Copper, Lanthanides, Sulfides
P. Lauxmann and T. Schleid
1149  Full Text
Donor-Acceptor Complexes between Simple Phosphines. First Structural Data for an Almost Forgotten Class of Compounds
Key words: Hypervalence, Phosphines, Lewis Acid-Base Adducts
G. Müller, H.-J. Matheus, and M. Winkler
1155  Full Text
Donor-Acceptor Complexes between Organoamines and Phosphorus Tribromide
Key words: Hypervalence, Phosphines, Lewis Acid-Base Adducts
G. Müller, J. Brand, and S. E. Jetter
1163  Full Text
Orthoamides, LVI. A New Method of Wide Scope for the Preparation of Aryl Formates
Key words: Aryl Formates, Formylation, Hydroxyarenes
G. Ziegler and W. Kantlehner
1172  Full Text
Orthoamides, LVII. Can Aromatic Aldehydes be Prepared from Aryl Formates via the Fries Rearrangement? (In German)
Key words: Aromatic Hydroxyaldehydes, Fries Rearrangement, Formylation
G. Ziegler, E. Haug, W. Frey, and W. Kantlehner
1178  Full Text
Polysulfonylamines, CXLVII. The First N,N-Disulfonylated Thioureas: Synthesis of (RSO2)2N-C(S)-NMe2 (R = Me, 4-Me-C6H4) and Crystal Structure of the Ditosyl Compound (In German)
Key words: Sulfonylthioureas, Thioamide Single Bond, Weak Hydrogen Bonding
J. Dalluhn, H.-H. Pröhl, O. Moers, A. Blaschette, and P. G. Jones
1188  Full Text
Some Reactions of Ynehydrazines with Isocyanates: [2+2]- and [4+2]Cycloadditions, (Hydrazinoethynyl)metallation (In German)
Key words: Cycloadditions, Cyclic Betaines, 1,3-Oxazin-4-ones
G. Himbert and O. Gerulat
1196  Full Text
Structural Influence of Hydrogen Bonding and p-Stacking in trans-Diazido-tetra-kis(pyrazole)nickel(II) and trans-Diazido-tetrakis(3-methylpyrazole)nickel(II)
Key words: Nickel Complexes, p-Stacking, Hydrogen Bonding
C. Zhang, C. Janiak, and H. Brombacher
1205  Full Text
7-Azoniafluorenone Derivatives by Electrostatically Activated SNAr-Reactions (In German)
Key words: 7-Azoniafluorenone, SNAr-Reactions, Electrostatic Effects
R. Weiss, F. Pühlhofer, and F. Hampel
1209  Full Text
Palladium(II) and Platinum(II) Complexes of N-3-Pyridinylmethanesulfonamide
Key words: IR Spectra, Palladium(II)and Platinum(II) Complexes, N-3-Pyridinylmethanesulfonamide
N. I. Dodoff
1217  Full Text
Facile Approach to ersatile Chiral Intermediates for Fused Cyclopentanoid Natural Products
Key words: Chiral Intermediates, Fused cyclopentanoids
F. Zulfiqar and A. Malik
1227  Full Text
Nucleophilic Aromatic Substitution at 2-Fluoroimidazolium Ions: Synthesis and Crystal Structure of a Dicationic 2,2-Biimidazolyl Derivative (In German)
Key words: Imidazoles, Enetetramine
N. Kuhn, G. Weyers, D. Bläser, and R. Boese
1235  Full Text
Interpenetrating Cluster Chains in the Structure of K0.77Nb6Cl15 (In German)
Key words: Niobium, Chloride, Cluster
A. Nägele, C. Day, A. Lachgar, and H.-J. Meyer
1238  Full Text
Synthesis and Structure of RE2Rh2Cd (RE = La, Ce, Pr, Nd, Sm)
Key words: Cadmium, Solid State Synthesis, Mixed Valence
F. Stadler, T. Fickenscher, and R. Pöttgen
1241  Full Text
N u m b e r  12
Original Communications
New Oxogermanates(IV) of the Heavy Alkaline Metals. Preparation and Crystal Structure (In German)
Key words: Germanates, Oxogermanates, Alumogermanates
C. Hoch und C. Röhr
1245  Full Text
Thiolate Complexes of Gold(I) Based on a Tris(phosphine) Support
Key words: Gold(I) Complexes, Tri(tertiary phosphine) Complexes, Thiolate Complexes
J. D. E. T. Wilton-Ely, S. Hofreiter, N. W. Mitzel, and H. Schmidbaur
1257  Full Text
New Coordination Compounds Derived from Nitrone Ligands: Copper(II) Complexes with 8-Hydroxyquinoline-2-carbaldehyde- and Pyridine-2-carbaldehyde-N-methylnitrones
Key words: Nitrones, Copper
E. G. Petkova, K. V. Domasevitch, M. V. Gorichko, V. Y. Zub, and R. D. Lampeka
1264  Full Text
Metal Complexes of Biologically Important Ligands, CXL. Halfsandwich Complexes of Ruthenium(II), Rhodium(III), Iridium(III) and Palladium(II), Platinum(II) Complexes with N,O-Chelates of Fluorine and Thiophene Containing a-Amino Acids (In German)
Key words: 2-Fluorophenyl Glycine and Alanine, 2-Thienyl Glycine and Alanine, Ruthenium
D. Koch and W. Beck
1271  Full Text
Ternary Rare Earth and Uranium Nickel Arsenides Ln2NiAs2 \1(Ln} = Tb - Yb), LnNiAs (Ln = La - Nd, Sm, Gd, Dy - Yb), and UNiAs
Key words: Rare Earth Compounds, Arsenides, Displacive Phase Transition
W. Jeitschko, L.J. Terbüchte, and U. C. Rodewald
1281  Full Text
Borane Activators for Nickel Catalysts for Olefin Polymerization
Key words: Polymerization, Norbornene, Cocatalyst
P.-G. Lassahn, C. Janiak, and Jae-Seung Oh
1289  Full Text
Carbonyl(diphenylcyclopentadienyl)- and Carbonyl(tetraphenylcyclopentadienyl)rhodium(I) Complexes (In German)
Key words: (Diphenylcyclopentadienyl)rhodium Complexes, (Tetraphenylcyclopentadienyl)rhodium Complexes
H. Schumann and S. Stenz
1293  Full Text
Synthesis, Characterization and Molecular Structure of 2-Pyridyl-formamide N(4)-Dimethylthiosemicarbazone and Some Five-Coordinated Zinc(II) and Cadmium(II) Complexes
Key words: 2-Pyridyl-formamide, Thiosemicarbazones, Zinc
E. Bermejo, A. Castiñeiras, L. M. Fostiak, I. García, A. L. Llamas-Saiz, J. K. Swearingen, and D. X. West
1297  Full Text
Effect of a Thermal Treatment on the Activity of Carbon-Supported Pt, Pt+W and Pt+Mo Electrocatalysts for Methanol Oxidation Reactions
Key words: Methanol Oxidation, Infrared Reflectance Spectroscopy, Carbon-Supported Catalysts
G. Göka\ugaç, J.-M. Leger, and F. Hahn
1306  Full Text
The Synthesis and Crystal Structure of a Dinuclear {m-Pyrazolato-N,N'-Bridged Dinickel(II) Complex of 1,3-Bis(2-hydroxy-4-methoxybenzylideneamino)propan-2-ol
Key words: Dinuclear Nickel(II) Complex, Binucleating Ligand
A. Elmali, E. Kavlakoglu, and Y. Elerman
1315  Full Text
Improved Synthetic Route to Unsymmetrically Substituted Phosphinimino-phosphonium Salts. Crystal Structure of Tri-n-butyl-[tris(diethylamino)phosphinimino]phosphonium Chloride
Key words: Phosphonium Salt, Imine Salt
R. Bartsch, M. Freytag, S. Goller, P. G. Jones, and R. Schmutzler
1319  Full Text
Na2ZrSe3, a New Chalcogenometallate(IV) with a Layered Structure (In German)
Key words: Complex Chalcogenides, Selenides, Zirconium
N. A. Harringer, A. Kolb, and K. O. Klepp
1322  Full Text
Formation and Structure of Tris(diphenylstibino)amine (In German)
Key words: Tris(stibino)amine, Nitrogen Configuration
L. Balázs, H. J. Breunig, T. Krüger, and E. Lork
1325  Full Text
Synthesis and Structure of Oxo-Bridged, M(CO)5 Protected Hexagermanium Cage Compounds (In German)
Key words: Cage Compounds, Germanium-oxo Cages, Germanium-Transition Metal Bonds
G. Renner, G. Huttner, and P. Rutsch
1328  Full Text
The Gold Sulfates MAu(SO4)2 (M = Na, K, Rb)
Key words: Gold, Sulfate, Alkali Metals
M. S. Wickleder and O. Büchner
1340  Full Text
CD-Spectroscopic Investigations for the Determination of the Absolute Configuration of (4R,6S,7S)-Serricornin
Key words: Serricornin, CD Spectra, Absolute Configuration
J. Fleischhauer, S. Gabriel, A. Job, D. Enders, and A. Wollmer
1344  Full Text
Electrolysis of Tetrakis(4-N,N-dimethylaminophenyl)methane - Fragmentation of Tetraarylmethane under Oxidative Conditions
Key words: Cyclic Voltammetry, Redox Chemistry, Tetraarylmethanes
T. J. Zimmermann and T. J. J. Müller
1349  Full Text
The Chemical Evolution of a Nitrogenase Model,XXIV. Correlational Analysis of Effects of Organic Acids on in vitro MoFe-Protein Substrate Reduction Activities
Key words: Nitrogenase, Organic Acids, Mechanism of Action
G. N. Schrauzer and J. G. Palmer
1354  Full Text
Electrostatic Activation of SNAr-Reactivity by Sulfonylonio Substituents (In German)
Key words: Electrostatic Effects, Polycations
R. Weiss und F. Pühlhofer
1360  Full Text
Formation and Crystal Structure of Polymeric (MeTeCl3)n
Key words: Tellurium Chlorides, Polymeric (MeTeCl3)n
J. Pietikäinen, R. S. Laitinen, J. Konu, and J. Valkonen
1369  Full Text
N-Ferrocenyl Amines Bearing Boryl and Silyl Substituents at the Nitrogen Atom, Studied by 57Fe NMR Spectroscopy
Key words: Ferrocenes, Aminosilanes, Aminoboranes
B. Wrackmeyer, H. E. Maisel, and M. Herberhold
1373  Full Text
DFT Calculations of the Structures and IR Frequencies of the Anionic Fulminate Complexe [Co(CNO)6]3-, [Ni(CNO)4]2-, [Zn(CNO)4]2-, [Pt(CNO)4]2-, [Au(CNO)2]- and [Hg(CNO)4]2-
Key words: DFT Calculations, Fulminate Complexes, IR Spectra
W. Beck and T. M. Klapötke
1376  Full Text
Authors Index 1379